111Equation Chapter 1 Section 1 FUNDAMENTAL EQUATIONS

Nernst equation for O + ne

R:

E E0

RT aO
ln
nF aR

E E 0

*
O
*
R

(2.1.40)

RT C
ln
nF C

(2.1.44)
One-step, one electron kinetic relationships (Butler-Volmer approach):
kf k 0 exp f ( E E 0 )
(3.3.9)

k b k 0 exp (1 ) f ( E E 0 )

(3.3.10)

i FAk 0 CO (0, t )e f ( E E ) C R (0, t )e (1 ) f ( E E )

CO (0, t ) f CR (0, t ) (1 ) f
e

CR
CO

(3.3.11)

i i0

(Cathodic Tafel Equation)

RT
RT
ln i0
ln i
F
F

Marcus theory:
G f

(3.4.10)

(3.4.15)