1.

Jawab :
1. 2PbS + 3O2

2SO2 + 2P2O

PV = nRT
2 . 228 = n . 0,082 . 493
n=

456
40,426

= 11,28

2PbS + 3O2
M
R
S

2SO2 + 2P2O

11,28 10,18
10,18 10,18
1,10
n PbS
= n SO2
1,10

V SO 2
22,4

V SO2 = 1,10 x 22,4 = 24,64 L

2.

Jawab :
2. 2 NH3 + 2 O2
S
1,59
1,80
b 1,59
1,59
s
0,21
n=

m
Mr

NO + 3 H2O
0,795

m = 0,795 . 30,00614 = 23,85 gr

4.

Jawab :
4. Diketahui :

V = 1,5 x 103 m3 = 15.105 dm3 = 15.105 L

T = 298 K
P = 1 atm
XCO 2 = 0,4896
XCO = 0,0146
XH 2O = 0,3710
XSO 2 = 0,1185
XS 2 = 0,0003
XH 2 = 0,0047
XHCl = 0,0008 HCl
XH 2S = 0,0003

Ditanya :

V = ? (setiap gas yang dihasilkan)

Jawab : n =

PV
RT

1atm . 15.105 L
atm . L
0,082.
.298 K
mol . K

15.105
24,4658 mol

= 0,613.105
nCO2 = nt. XCO2
= 0,613,105 x 0,4896

= 0,3 . 105 mol

VCO2

nRT
P
5

0,3.10 mol . 0,0821

=

atm . L
. 198 K
K . mol

1atm

= 7,34.105 L (perhari)
= 7,34 .105 L x 365 = 26.791.104 L (pertahun
nCO2

= nt .XCO
= 0,613.105 x 0,0146
= 8,95.102 mol

VCO

n. RT
P
2

8,9.10 mol .0,0821

=

atm . L
. 298 K
K . mol

1 atm

= 21896,891 L (perhari)
H 2O

= nt . XH2O
= 0,613.105 x 0,3710
= 0,227 . 105 mol

VH2O =

n RT
P
0,227.105 mol . 0,0821
=

nSO2

atm . L
. 298 K
K . mol

1atm

= 5,554.105 L (perhari)
= 5,554.105 x 365 = 2027,21 .105 (pertahun)
= nt. XSO2
= 0,613 .105 x 0,1185
= 0,0726.105 mol

VSO2 =

n. R . T
P
5

0,0726.10 mol . 0,0821

=

atm . L
.298 K
k .mol

1 atm

= 1,776.105 L (perhari)
= 1,776.105 x 365 = 648,24.105 L (pertahun)
nS2

= nt x XS2
= 0,613.105 x 0,0003
= 18,39 mol

VS2

n. R . T
P

atm. L
.298 K
k . mol
1 atm

nH2

=
=
=
=
=

449,93 L (perhari)
449,93 L x 365 = 164.224,45 L (pertahun)
nt x XH2
0,613.105 . 0,0047
288,11 mol

VH2

18,39 mol . 0,0821

n. R . T
P
288,11 mol .0,0821

atm . L
.298 K
k . mol

1 atm

= 7048,84 L (perhari)
= 7048,83 L x 365 = 2.572.826,6 L (pertahun)
nHCl = nt x XHCl
= 0,613.105 . 0,0008
= 49,04 mol
VHCl =

n. R . T
P

atm . L
.298 K
k . mol
1 atm

49,04 mol . 0,0821

=
=
=
nH2S =
=
=
VH2S =

1199,8 L (perhari)
1199,8 L x 365 = 437.927 L (pertahun)
nt x XH2S
0,613.105 . 0,0003
18,39 mol

n. R . T
P
atm. L
.298 K
k . mol
1 atm

18,39 mol . 0,0821

=

= 449,93 L (perhari)
= 449,93 L x 365 = 164.224,45 L (pertahun)
5.

Jawab :
5. Dik :

T = 250 K
P = 1,0 x 10-3 atm
V=1L

Dit :

N?

Jawaban :

PV = NKT
N=

103 .1
250 . 1,38 x 1023

N = 2,9 x 1017

6.

Jawab :
6.

2 NO+ O2

2 NO2

P . V = n . R. T

n=

PV
RT

0,005 atm . 4000 L

atm L
0,082
298 K
mol K

2000
24,46 /mol

= 0,08176 mol
Mol total

= n NO + n O2
= 0,08176 mol + 0,08176 mol = 0,1634 mol

P tot . V tot

NO2

ntot . R .T
vtot

n. NO 2
n. NO 2

P NO2 = XNO2 .Ptotal

0,6663 atm

atm . L
..298 K
mol . K
6000 L

0,163mol .0.082
=

2.0,0817
2.0,0817

= 0663 atm

=1
= 1. 0,6663 atm =

= 0,6663 atm x 1,01325

atm

= 0,6751 bar

= 0,6663 atm x 101,325

kpa
atm

= 67,178 kpa

= 0,6663 atm x 14,7

7.

Jawab :
7. zat oksidasi
4 NH3 + 5 O2
oksidasi

4 NO-2 + 6 H2O

reduksi
2 NO2 + O2
oksidasi

2 NO2
reduksi

3 NO2 + H2O
oksidasi

2 HNO3 + NO
reduksi

Psi
atm

= 9,794 Psi

b. 4 NH3 + 5 O2
2 NO + O2
3 NO2 + H2O

4 NO + 6 H2O
2 NO 2
2 HNO3 + NO

4 NH3 + NO2 + 6 O2

238,095

mol NHO 3

3 x 104
63

= 952,38 kmol

1 mol HNO 3

476,19
2

Mol NH3 =

1
4

3NO + 2HNO3 + 5 H2O

= 476,19 kmol

= 238,095 kmol
Massa

= 17952,38
= 16190,46 kg

8.

Jawab :
8 . M1V1 M2V2
a. konsentrasi HNO3 = 0,00539 mol
M1.30 = 0,0502 x 3,22
M 1=

0,0502 x 3,22
30
0,16164
30

= 0,00539 mol

b. M1 x 50 = 0,0502 x 30

0,00539 x 50 = 0,0502 x 30
Mol berlebih

= (0,0502 x 30 ) (0,00539 x 50)

= 1,506 0,2695
= 1,2365 ml

Mol berlebih NaOH

=(

mol berlebih
1,2365
)
=
2V
80

= 0,01546 ml

9.

Jawab :
9. S + O2

SO2

m SO2 = 26 juta ton

n
mS

26 juta ton
64

= n . S . Mr
= 0,40625 . 32
= 13 jt ton

10.

= 0,40625 juta ton mol

Jawab :
10. 2 NH3 + H2SO4

(NH4)2SO4

m (NH4)2SO4 = 1 x 105 kg = 108 g

n=

gr
mr
108
132

7,57 x 105 mol

3 NH3
+
H2SO4
m 15,14
7,57 . 105
b 7,57 . 105 7,57 . 105
s 7,57 . 105
n=

(NH4)2SO4
7,57 . 105

gr
mr

15,14 . 105

gr
17

gr = 257,3 . 10 5 gr
m = 257,3 .10 2 kg
11. FeTiO3 + H2SO4
TiO2 + FeSO4 + H2O
3
8 x 10 Kg
3,67 x 103 Kg
Hasil =

3,67 x 103
x 100
8 x 103

= 45,88 %

12
.

Jawab : a. mis larutan = 100 ml

70
100

mL HNO3 =

x 100 mL

= 70 mL

1,41 =

m
V

m
70

m = 70 x 1,41
= 98,7 kg
b.n =

M=

a. H2SO4
mis = 100 mL

g
Mr
98,7
63
1,57
7 .102

= 1,57 mol

= 22,38 M

n
V

M=

18,3 =

n
0,1

n = 1,83 mol

x 10 x massa
Mr

b. M =

18,3 =

1,84 x 10 x gr
98
18,4 x gr
98

18,3 =

179,34 = 18,4 x gr
gr =

179,34
18,4

= 97,46 gr