@) Peer tutors: Arman Bolour (abolour@uci edu) Huong Nguyen (huonatn2@uciedu) Dr. Arasasingham - Chem 1B Midterm I & II Review Arman’s Section (Midterm I) 4) True or False... a) lonic compounds exist as hard crystalline solids at room temperature and have relatively high melting and boiling temperatures b) lonic compounds are brittle and not malleable ) Most ionic compounds do not conduct electricity in the solid state, but when dissolved in water or when heated to the molten state they do conduct electricity of their 2) Rank the molecules in order of increasing intermolecular strengths and list all intermolecular forces: Hl, HCl, KOH, HzO, CHsCIGaS, C(CHs)« 88 Ze Bz & 4 _Higu TMr ea: WEE BIC OF Small WH p- dIFERRENE! He Rane GaS JON IME - - Hacaqatiet a) ttc 2! £08 ¥ ange ethane (CH3CHs), propane (CH3CH2CHs), n-butane (CHsCH2CH2CHs), and iso-butane lané WO 2 Gl points. e Mo is]sCH) in order of increasing boil KANG < 1SEF butane SZ PTPOWL Sy - butane , Vt e-c™ . J 7 >on a oo \ fig f =U-ts Jk ome J ache) Se 6 TO 4 . ot alte ok d +O~ = ) { - - 4) What range of electronegativity would constitute the following types of compounds... ) a) NonpolariCompletely Covalent? ()< O .4 b) Polar Covalent? 0.4 — 2.0 32.0 c) lonic?ge BP HoMaAC WO SBE e Site 2 UO 2 maQdy 6) Where are the lattice points for these different structures... a) Simple Cubic (sc) = COVA § b) Body-Centered Cubic (bec) = COL WEN'S % CONTEC oF UIE ©) Face-Centered Cubic (fec) = (Carners x cenitur ot Coourface 7) What are the average # per unit cell of these different structures... a) Simple Cubic (sc) = | CHG b) Body-Centered Cubic (bec)=2 CG} @ ¢) Face-Centered Cubic (fec)=4- CH? /2 8) The relationship between the length of the edge of the cube and the radius of the atoms are given by the relationship... a) Simple Cubic (sc) = b) Body-Centered Cubic (bec) = = dr ©) Face-Centered Cubic (fee) = L= (& 7 dont conyer ) THA density of BaS at a certain temperature is 24.63 g/em®. CaldufateNhe length of an edacltktng it cell (in pm). me (60.306 2 ey de Ms 24.689, eS. Een Ve (4201 0 Megn = 2%\x\o2 . Nereis yee 24.6% Slows on any VENA 207 110 23nd dom CD (rg) 3 4 erecta Ee} on edger dt |= 3, ¥OGR KIS em a‘ fa i wesc problem, find the“atomic radius (in cm) of the unit cell, considering that it is a . O1245 om \, + &. 61a | Huong’s Section (Midterm II) 4) One cup containing 80 grams of water at 300 K is mixed into another cup containing 200 g of water at 450 k. What is the equilibrium temperature of the system? é he two liquids undergo thermal exchange; thus, the heat given off by one liquid will be equal to we) heat absorbed by the other. 1,74 mot. meat 2. ce HM (ose -350}-o0gf 150-14) 83 | 2005 ta A SOK YAGI K | C | 418 | 4.18 ino Ss3 How ie) work in joules is done of a system when a 1.15 atm extemal pressure causes a piston to decrease in volume from 6.55 liters to 3.16 liters? = We ~ POV -—s Wer. 82342) Pasa = 3, 4aGS- SV= 3.39 Nittrs =3.9 Lam Neynay - NW iaticg, 3 34q5: Joudks B\67 @SS BALWM rw 3) Agas at 25" ‘navi ised Rercnea in aston, doing 70044 of wrk aginst atmosoharcprosste The res eat of he Ges ncreaue by 052 and tis reperaine increased to 40°C. How much heat EIS Wee AOC \ \N= 1-5 | 7S004 A= 952.4 Ac= BY +N t ‘ ae RAK Wot NON " OMe Ob 241500 ,= $452) QS25 = BW, -18E3 ate the standard enthalpy change for this reaction: 2AN(5) +3.Ch(g) > 2 AIC (6) (112 Al (@)+ 6 HCI (aq) > 2 AICIs (aa) + 3 H2 (9) BC @) He (g) + Cle {@) > 2 HCI (9) aici) >aieited y e ) in 2 Al + GHC] AMS) BHT Ale - WAT eth eC Atte “14-8 4 . : . AT BQ~ AE Ave SCS) H=s55 yy 3 = AME Alls - 323 Ul ¢3Clr —> ZAICls Atye-2001-8 -