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Gas Abs
Gas Abs
MODULE 4: ABSORPTION
LECTURE NO. 4
(4.18)
Page 1 of 8
Gs, Y1
Gas out
Liquid in
Ls, X0
Gs,Y1
Ls, X1
N-1
N
Gs,YN
Ls, X1
Gas in
Gs, YN+1
Liquid out
Ls, XN
Figure 4.7: Schematic of tray tower.
(2)
(3)
Minimum liquid rate; actual liquid rate is 1.2 to 2 times the minimum liquid
rate.
(4)
algebraically.
Page 2 of 8
(4.19)
If the stage (plate) is ideal, (Xn, Yn) must lie on the equilibrium line, Y*=f(X)
Top plate is located at P(X0, Y1) and bottom plate is marked as Q(XN,
YN+1) in X-Y plane. A vertical line is drawn from Q point to D point in equilibrium
line at (XN, YN). From point D in equilibrium line, a horizontal line is extended up
to operating line at E (XN-1, YN). The region QDE stands for N-th plate (refer
Figure 4.8). We may get fraction of plates. In that situation, the next whole
number will be the actual number of ideal plates. If the overall stage efficiency is
known, the number of real plates can be obtained from Equation (4.18).
3.5
3.0
Q (XN,YN+1)
2.5
E (XN-1,YN)
2.0
Operating line
D (XN,YN)
1.5
Equilibrium line
N-1
1.0
N-2
0.5
P (X0,Y1)
0.0
0.0
0.2
0.4
0.6
0.8
1.0
Page 3 of 8
+1 1 = 0
(4.21)
+1 1 =
+1 1 = 0
+1 1 = 0
(4.22)
= =
where
(4.23)
(4.24)
Solution is = 1
(4.25)
1 +1 1 = 0
(4.26)
(4.27)
1 0
(4.28)
+ 2 = K1
1 0
1
(4.29)
Initial conditions:
N=0; Y0=X0
0 = 1
1 0
1
Page 4 of 8
1 =
0 0 1 + 0
1
1 =
0 1
0 1
(4.30)
1
1
1 0
(4.31)
When N=N+1;
+1 =
+1 =
0 1
1
0 1
1
+1
+
1
1 0
1
0
1
1
1 +1 = 0 1 +
1
0 1 =
1 +1
1
1
+1
1
0
0 1
1
0
1
0
+1 0
1 0
1 +
(4.32)
+1 0
1 0
+1 0
1 0
1
1
+
when 1
(4.33)
(4.34)
+1 1
(1 0 )
(4.35)
Page 5 of 8
0 +1 /
+1 /
1
1 +
when 1
(4.36)
(4.37)
+1 /)
Solution 4.2:
Basis: 1 hour
GN+1=30 kmol
yN+1=0.015
L0=90 kmol
Moles acetone in = 300.015 moles=0.45 moles
Moles nitrogen in = (30-0.45) moles=29.55 moles
Moles acetone leaving (95% absorbed) = 0.45(1-0.95) moles=0.0225 moles
Gs=29.55 moles
Ls=90 moles
=2.53 [as, Y=2.53X]
Joint initiative of IITs and IISc Funded by MHRD
Page 6 of 8
1 =
0.0225
= 7.61 104
29.55
+1 = 0.015
Rewriting Equation (4.19) (operating line) as
+1 1 = ( 0 )
29.55 0.015 7.61 104 = 90( 0)
XN=4.6810-3
(a) Solution by graphical method
Construction of operating line PQ:
P(X0, Y1)=P(0, 7.6110-4)
Q(XN, YN+1)=Q(4.6810-3, 0.015)
0.001
0.002
0.003
0.004
0.005
Page 7 of 8
=
=
ln
+1 0
1 +
1 0
ln
ln
0.0152.530
7.6110 4 2.530
1
1.204
1
1.204
ln 1.204
ln 20
0.204
1.204
+ 1.204
0.1856
1.43966
= 7.75
0.1856
Page 8 of 8