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2002 U. S. National Chemistry Olympiad: Local Section Exam
2002 U. S. National Chemistry Olympiad: Local Section Exam
NATIONAL
CHEMISTRY OLYMPIAD
LOCAL SECTION EXAM
Prepared by the American Chemical Society Olympiad Examinations Task Force
Not valid for use as an ACS Olympiad Local Section Exam after April 21, 2002. STOCK CODE OL02
Distributed by the ACS DivCHED Examinations Institute, Clemson University, Clemson, SC. All rights reserved. Printed in U.S.A.
amount of substance
ampere
atmosphere
atomic mass unit
atomic molar mass
Avogadro constant
Celsius temperature
centi- prefix
coulomb
electromotive force
energy of activation
enthalpy
entropy
CONSTANTS
m
m
M
mol
h
P
k
s
c
T
t
V
V
2
He
1.008
4.003
3
Li
4
Be
5
B
6
C
7
N
8
O
9
F
10
Ne
6.941
9.012
10.81
12.01
14.01
16.00
19.00
20.18
11
Na
12
Mg
13
Al
14
Si
15
P
16
S
17
Cl
18
Ar
22.99
24.31
26.98
28.09
30.97
32.07
35.45
39.95
19
K
20
Ca
21
Sc
22
Ti
23
V
24
Cr
25
Mn
26
Fe
27
Co
28
Ni
29
Cu
30
Zn
31
Ga
32
Ge
33
As
34
Se
35
Br
36
Kr
39.10
40.08
44.96
47.88
50.94
52.00
54.94
55.85
58.93
58.69
63.55
65.39
69.72
72.61
74.92
78.96
79.90
83.80
37
Rb
38
Sr
39
Y
40
Zr
41
Nb
42
Mo
43
Tc
44
Ru
45
Rh
46
Pd
47
Ag
48
Cd
49
In
50
Sn
51
Sb
52
Te
53
I
54
Xe
85.47
87.62
88.91
91.22
92.91
95.94
(98)
101.1
102.9
106.4
107.9
112.4
114.8
118.7
121.8
127.6
126.9
131.3
55
Cs
56
Ba
57
La
72
Hf
73
Ta
74
W
75
Re
76
Os
77
Ir
78
Pt
79
Au
80
Hg
81
Tl
82
Pb
83
Bi
84
Po
85
At
86
Rn
132.9
137.3
138.9
178.5
181.0
183.8
186.2
190.2
192.2
195.1
197.0
200.6
204.4
207.2
209.0
(209)
(210)
(222)
87
Fr
88
Ra
89
Ac
104
Rf
105
Db
106
Sg
107
Bh
108
Hs
109
Mt
110
111
112
114
(223)
226.0
227.0
(261)
(262)
(263)
(262)
(265)
(266)
(269)
(272)
(277)
(289)
Page 2
58
Ce
59
Pr
60
Nd
61
Pm
62
Sm
63
Eu
64
Gd
65
Tb
66
Dy
67
Ho
68
Er
69
Tm
70
Yb
71
Lu
140.1
140.9
144.2
(145)
150.4
152.0
157.3
158.9
162.5
164.9
167.3
168.9
173.0
175.0
90
Th
91
Pa
92
U
93
Np
94
Pu
95
Am
96
Cm
97
Bk
98
Cf
99
Es
100
Fm
101
Md
102
No
103
Lr
232.0
231.0
238.0
237.0
(244)
(243)
(247)
(247)
(251)
(252)
(257)
(258)
(259)
(260)
Not for use as a USNCO Local Section Exam after April 21, 2002.
DIRECTIONS
When you have selected your answer, blacken the corresponding space on the answer sheet with a soft, black #2 pencil. Make a
heavy, full mark, but no stray marks. If you decide to change an answer, erase the unwanted mark very carefully.
Make no marks in the test booklet. Do all calculations on scratch paper provided by your examiner.
There is only one correct answer to each question. Any questions for which more than one response has been blackened will not be
counted.
Your score is based solely on the number of questions you answer correctly. It is to your advantage to answer every question.
The best strategy is to arrive at your own answer to a question before looking at the choices. Otherwise, you may be misled by
plausible, but incorrect, responses.
1. Which element reacts most rapidly with water at 25 C to
produce a gas?
(A) aluminum
(B) carbon
(C) lithium
(D) phosphorus
(B) 2 only
(B) O2
(C) Cl2
(D) NO
(B) 2 only
(B) MnO2
(C) Mn2O3
(D) MnO3
(B) NO3
(C) Pb 2+
(D) Na +
Not for use as a USNCO Local Section Exam after April 21, 2002.
(B) 28 / 115
(C) 28 / 132
(D) 14 / 210
Page 3
(B) 8 L
(C) 10 L
(D) 15 L
42 mmHg
(A) 42 mmHg
(A) 20
Tube
2
Tube
3
Tube
4
(B) iodine
(C) mercury
(B) 2
(C) 3
(D) 4
(B) 18.5 mL
(C) 33.8 mL
(D) 84.4 mL
(B) 273 mL
(C) 278 mL
(D) 496 mL
Page 4
Values for H 2O
Cp
4.18 Jg1C1
H fusion 3.4 102 Jg1
(A) 240 J
(B) 850 J
(C) 1100 J
(D) 3700 J
Not for use as a USNCO Local Section Exam after April 21, 2002.
436
243
431
(A) 1110 kJ
(B) 248 kJ
(C) 183 kJ
(D) 248 kJ
(B) 1797 kJ
(C) 3234 kJ
(D) 5390 kJ
H of , kJmol1
[C2H5I], M
Rate, Ms1
0.010
0.010
0.020
0.010
0.020
0.030
1.2 105
2.4 105
7.2 105
84.7
393.5
285.8
(A) 764 kJ
(B) 1560 kJ
(C) 1664 kJ
(D) 3120 kJ
(A) no temperatures
Not for use as a USNCO Local Section Exam after April 21, 2002.
fast
slow
(A) 1 only
(B) 2 only
(C) either 1 or 2
Page 5
[ Hg]2 [O 2 ]
[HgO]2
(B) K =
(C) K = [ Hg][O 2 ]
[ Hg][O 2]
[HgO]
(D) K = [O 2 ]
38. Which salt gives the most acidic 0.1 M solution in water?
(A)
high
high
(B)
high
low
(C)
low
high
(D)
low
low
(B) H2O(l)
(C) OH(aq)
(D) H3PO4(aq)
Formic Acid
HCOOH
(A) 1.49
(B) 2.27
(C) 3.72
(D) 4.55
KA
1.9 104
(C) NH4Cl
(D) NH4NO2
84 gmol 1
6.8 106
(A) 0.22 gL 1
41.
(B) NaNO2
(A) NaCl
(A) VN
(B) VCl 3
(C) VOSO4
(D) VF5
(B) 3/1
(C) 6/1
Ga (aq) + 3e Ga (s)
0.529 V
Tl+(aq) + e Tl (s)
0.336 V
(A) 0.479 V
(B) 0.193 V
(C) 0.193 V
(D) 0.479 V
0.13 V
0.23 V
0.40 V
(A) 1 only
(B) 2 only
(A) 1 only
(B) 2 only
Page 6
Not for use as a USNCO Local Section Exam after April 21, 2002.
(B) Al and N
(C) Al and Se
(D) Al and O
53. In which species does the central atom obey the octet
rule?
(B) 14
(C) 15
(D) 16
(B) electronegativity
(A) XeF4
(B) SF4
(C) SiF4
(D) ClF4
(B) 2 only
(B) 3p4s3d
(C) 3d4s4p
(D) 4p4d4f
(A) aldehyde
(B) alkene
(C) ester
(D) ketone
(B) 4
(C) 6
(D) 8
49. Which has the highest ionization energy for the removal
of the second electron?
(A) F
(B) Ne
(C) Na
(D) Mg
(B) 3
(C) 4
(D) 5
(A) Be and B
(B) Al and Ga
(A) 5 sigma
(C) Co and Cu
(D) F and I
S C
(C)
C N
(B)
C N
(D)
Not for use as a USNCO Local Section Exam after April 21, 2002.
(B) P
(C) N and P
(D) N and S
END OF TEST
Page 7
Page 8
Not for use as a USNCO Local Section Exam after April 21, 2002.
Number
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
14.
15.
16.
17.
18.
19.
20.
Answer
C
B
A
D
C
B
A
A
C
D
A
B
C
C
A
B
D
C
B
A
Number
21.
22.
23.
24.
25.
26.
27.
28.
29.
30.
31.
32.
33.
34.
35.
36.
37.
38.
39.
40.
Answer
D
C
C
A
B
B
D
B
D
D
B
A
D
C
A
B
D
C
A
D
Number
41.
42.
43.
44.
45.
46.
47.
48.
49.
50.
51.
52.
53.
54.
55.
56.
57.
58.
59.
60.
Answer
A
B
A
C
D
C
A
B
C
B
D
D
C
A
D
A
C
B
D
A