18.52.

a)
nO 2=

n 02=

PV
RT

( 1.0 atm ) (.84 L)

=.034 mol 02
Latm
(.082
k)( 298 k)
mol

mole=.034 molO2 x

4 mole
=.14 mole
1 molO2

b)
1 atm
750 mmHgx
( 1.50 L )
(
760 mmHg )
nCL2=
=.0605 molCl 2
Latm
(.0821 mol k ) ( 298 k )
mole .121mol Cl 2 x

2 mole
=.5 e
1 molCl 2

c)
molSn=6.0 gSnx

1 molSn
=.051 molSn
118.7 gSn

mole=.051molSnx

2 mole
=.10 mole
1 molSn

18.53
4.50 Ax 1 hx

3600 s
1C
1 mole 1 molCu 63.55 gCu
x
x
x
x
=5.33 g Cu
1h
1 As 96500 C 2 mole
1 molCu

4.50 Ax 1 hx

3600 s
1C
1 mole 1 molBr 2 159.8 gBr 2
x
x
x
x
=13.4 gBr 2
1h
1 As 96500 C
2 mole
1 molBr 2

18.56
a)
2.00 gAgx

1 molAg
1 mole 96500 C
3C
x
x
=1.79 x 10
107.9 gAg 1 molAg 1 mole

( 1.79 x 103 C ) x 1 mole x 1molCu x 63.55 gCu =.589 gCu

96500 C

2 mole

1 molCu

b)

( 1.79 x 103 A . s ) x 1h x

1
=.133 A
3600 s 3.75 h