TRNG I HC CNG NGHIP TP H CH MINH

KHOA CNG NGH HA HC

TIU LUN: PHN TCH CNG NGHIP

TI : XC NH THNH PHN CaO V MgO
TRONG XI MNG

GVGD : ThS Trn Nguyn An Sa.

SVTH : L Th Ngc Bch.
Lp
: DHPT5.

NI DUNG
1

TNG QUAN V CaO V MgO

NGUYN TC

QUY TRNH

TNH TON KT QU

1. TNG QUAN V CaO V MgO.

Thnh phn ha hc: CaO: 63 - 66%; Al2O3: 4 - 8%;
SiO2: 21 - 24%; Fe2O3: 2 - 4%. Ngoi ra cn c mt s
oxyt khc nh MgO; SO3; K2O; Na2O; TiO2; Cr2O3;
P2O5,... Chng chim mt t l khng ln nhng t
nhiu u c hi cho xi mng

2. NGUYN TC.
St, nhm, titan v cc ion cng tr khc c tch khi
canxi v magie bng amoni hydroxit.
Chun canxi bng dung dch EDTA tiu chun pH >12
vi ch th fluorexon, im tng ng dung dch
chuyn t mu xanh chuyn sang mu hng.
Chun tng lng canxi v magie trong mu bng dung
dch EDTA tiu chun theo ch th eriocrom T en pH =
10,5. xc nh hm lng magie oxit theo hiu theo hiu s
th tch EDTA tiu th.

3. QUY TRNH.

3.1 Giai on loi st, nhm v titan.

3.2

Xc nh tng hm lng CaO v MgO.

3.3 Quy trnh xc nh hm lng CaO.

3.4 Quy trnh xc nh hm lng MgO.

3.1Giai on loi st, nhm v titan.

3.2

Xc nh tng hm lng CaO v MgO.

25 ml dd B
Thm 50 ml
nc ct,
chnh pH=10

Thm 10 ml dd m
pH=10 , 2 ml dd KCN
5%, ch th ETOO 1%

Dd t mu nho
chuyn sang xanh
chm

3.3 Quy

trnh

xc

nh

hm

S .

lng
Dd chun
EDTA 0,01M
(V1)

25 ml dd B

50 ml nc ct, 10 ml dd KOH
25%, 2 ml dd KCN 5%, ch th
fluorexon 1%
Dd chuyn
sang mu
hng
CaCO3

CaO

CaO + H2O = Ca(OH)2

CO2 + Q

+ Q.

CaO.

3.4 Quy

Dung
dch B

trnh

xc

nh

80 ml nc ct, 15ml dung dch m PH =

10.5

hm

lng

dung dch chun

EDTA
0.01%
(V2)

2ml dung dch Kalixyanua 5%, ch th ericrom

T en 1%

Mu ru nho
sang nc bin
MgCO3

CO2

+MgO

MgO.

4. Cng thc tnh CaO.

Hm lng CaO tnh bng phn trm theo cng thc:

0.00056 V2 k
%CaO
100
m
Trong :
K: l h s pha long
V1: th tch EDTA 0,001M tiu tn xc nh tng Ca v Mg ml
0,00056: khi lng CaO tng ng vi 1ml dd EDTA 0,01M,
m: khi lng mu tng ng vi th tch mu ly nh caxi
oxit, tnh bng g.

4. Cng thc tnh MgO.

Hm lng MgO tnh bng phn trm theo cng thc:

0,000403 V1 V2 k
% MgO
100
m
Trong :
0,000403: khi lng MgO tng ng vi 1ml

dd EDTA

0,01M, g.
V2: th tch dd EDTA 0,01M tiu tn chun
canxi, ml.
K: h s pha long.
m: khi lng mu th.

tng

Ti liu tham kho.

TCVN 141 : 2008
TCVN 141: 1998
Gio trnh phn tch cng nghip, TT CNHH,
HCN TP.HCM
Hong Minh Chu T Vng Nghi, C S Ha
Hc Phn Tch, NXB Khoa Hc V K Thut, 2002