/ 2015

---------------------------------------------------------------------------------------------------------------- 01

) : ( .
). (Airbag

.
: 1
E = 5V
C = 100 F
. R
C
:
-
E
t = 0 .
R
2 ) u C = f ( t ) i = g ( t
.
1 -

1 u C i .
2 .
)i ( A
3 ) ( .

) uC (V

4 ) . ( R
5 .

B
A

6 .
- :

.
1 :

d
k
= C
C =kd
k
d
k d
C .
=C

-2
(

) ( uC

0,1

) t ( ns

2 -

.
( .
N2 .
02
- :
R C t = 0

) u C ( t .

uC = E 1 e = RC

.
- 1 ) . u C ( t

R = 100

E
C

) uC (V

2 .
3 .
4 t =
. u C = 0,63E

0,5

) t ( ms

 - r . L . t = 0
) i ( t
i mA

18

)(L , r

R = 100
11

) t ( ms
1
2
3
4

.
I . r R E
.

di I
=
5 t = 0
dt

. RL

6 .
03
X 3 X 2 X 1 : R = 100 r
L . C
- .
L3 L2 L1 ) . LED (1
K t = 0 L1 . L2

L3 .
1 .
2 .

L1

X1

- X 3 ) ( D R = 100

L2

X2

. . t = 0

L3

X3

- 1
. X 3

2 . X 3

X3

3 u = Ae t + B
A B .

4 ) ( u R .

5
. a

1
t
Ee a

= u R

6 t = ln 2 D X 3 .
- 7 ) ( A ) ( B .
) (1 ) ) . ( 2 . ( 3

)( A
2

)(1

)( B

)(2

4 -

X3

) u (V

( .
( .

 - X 1 X 2
) . E ( 3
.

. 6
5 -

X2

X1

)( A

)( B
) u (V

) t ( ms

25

- 1 X 1 . X 2
2 X 1 . X 2

 04

S 2O3 :

) S 2O3 2( aq ) + 2 H 3O +( aq ) = S ( s ) + SO2 ( aq ) + H 2O ( aq
.
:
-

600 mL 100 mL :
500 mL 250 mL 100 mL 50 mL :
25 mL 20 mL 10 mL 5 mL :
500 mL 100 mL :


Na 2 S 2O3 ,5H 2O

- .
) : ( S1

) ( S1 V1 = 500 mL . C1 = 0,1 mol / L

) : ( S 2

) ( S 2 V2 = 50 mL C 2 = 0,05 mol / L ) . ( S1
- ) (1 ) . (2 ) 45 mL (1 ) ( S1 ) 45 mL (2

) (+ .
) ( S 2

t = 0 5 mL )

H 3O + , Cl . C = 1 mol / L

t = 32 s ) (+ ) (1 ) (2 ) (+
. t = 52 s
1 .
2 ) (+ ) (1 ) (2
3
( ) (1 ). (2
( .
( .
---------------------------------------------------------------------------------------------------------------- 05
Cl 2

Na + , OH

OH .

Cl 2 + 2OH = ClO + Cl + H 2O :
ClO

)(1

) ( Hypochlorite

2ClO = 2Cl + O2

)(2

ClO + Cl + 2 H 3O + = Cl 2 + 3H 2O :

)(3

.
:
. ) . ( chl. ) (12 chl. 12 L
Cl 2 1L .
) (12 chl.
.

)(chl.

ClO

. 48 chl.
2 > :
<
3 :
> <
4 .
(
(
250mL ). (12 chl.

12

20C

30C

40C
) t ( semaine

8
-------------------------------------------------------------------------------------------------------------- 06
I :

H 2O2 + 2 H 3O + + 2 I = 4 H 2O + I 2

)(1

, S 2O3 2

( 2K

. I 2
:

2S 2O3 2 + I 2 = S 4O6 2 + 2 I

)(2

= 50 mL -

V )

K , I . 0,1mol / L

V3 = 150 mL . C3 = 0,1mol / L . V = 1mL ) ( S . . C = 0, 2 mol / L t = 0 V2 = 2,5 mL . C 2 = 1mol / L

t = 20 s . 1mL ) ( S

. 1mL ) ( S .
1000 s t = 0 ) x = f ( t x .
1 .

) x ( mmol

- 2(
.
(
). (1
- 3(
) . ( S

(
) (1 .

4 ) (1 t ( s ) . t = 20 s
5 . t = 42 s .
6
7 .

100

 07
) ( S1

) ( H 2 O2 . V1 = 10 mL 200mL

) . ( S 2
V2 = 10 mL ) ( S 2 5mL
.
1 ) I 2 ( aq ) / I ( aq ) . H 2O2 ( aq ) / H 2O( l

2 C = 0,12 mol.L1
. VE = 13,85 mL . S 4 O6 2 / S 2 O32
( .
( ) ( S 2 ) . ( S1
3 ) ( xV x .
x ) ( S1

) [ H 2O2 ] ( mol.L1

4 V = 100 mL
.
] [ H 2 O2 .
(
]. [15 , 30 mn

(
. t = 0
( . t = 0
( .
.
1
VM = 22, 4 L. mol

0,1

) t ( mn

5
---------------------------------------------------------------------------------------------------------------- 08
:
K
. E = 6 VE
L r R = 200 . t = 0
(L
,
)r
1 2 1 . 2
R
B
C
-1 . uR

E
2
R+r

- 3 .
4 I 0
.
5 .

. uR = R

) u (V

) u (V

2 -

1
2

1 -
1

)t (s

0,002

)t (s

0,2
0,002

 09

, S 2O8

( 2K )

K , I

S2O82 + 2 I = I 2 + 2 SO4 2

:
3 3 : 1 -
) : (2 -

) I ( mol / L

) S2O82 ( mol / L

0,04

0,02

20C

) (A

0,02

0,01

20C

) (B

0,04
V2 = 100 mL

0,02
V1 = 100 mL

35C

1
.
2 C

[ I 2 ] = 8 103 mol / L

- 3
. t = 7,5 mn
V = 10 mL
100mL

) (C

2 Na + , S 2O32 C = 0,01 mol / L . VE = 8, 2 mL

(
(
www.guezouri.org
(
. S 4O6 2 / S 2O32

] [ I2

C V VE ] . [ I 2

0,008

0,006

0,004

0,002

20,0

13,3

7,5

3,3

60,0

36,7

21,7

8,3

390

230

110

35

) [ I 2 ] ( mol / L

) t ( mn

) t ( mn

) t ( mn

----------------------------------------------------------------------------------------------------------- 10
. :
E
E = 12VK
R2 = 220 R1 = 100 r LR1
) ( .
)(L , r
- . t = 0
-1 ) . ( R1

-2
(
( I 0 . r R1 E
- 3
- . t = 0
- 1 .

R2
)i ( A

di 1
2 + i = 0
dt

- 3 i = A e A .
- 4 .
( .
( . t = 2,5 ms
0,02

) t ( ms

2,5

 11

K , MnO4 . H 2C2O4

t = 0 V1 = 40 mL ) ( S1 C1 = 5 103 mol / L
V2 = 60 mL

) ( S2

/ Mn 2+

. C2 = 5 102 mol / L

( MnO

www.guezouri.org

) ( CO2 , H 2O / H 2C2O4

.
1 ) ( S1 ) . ( S 2
2 :
:

100 mL 10 mL : 10mL 5mL 1mL : - 500mL 100mL :

K , MnO4 C0 = 0,1mol / L

- H 2C2O4 C2 = 5 102 mol / L

( 100mL ) . ( S1

( n1 n2 .
( .
( MnO4 . x

(
3 :

2+

Mn .

160

140

120

100

90

80

70

60

40

20

)t (s

0,00

0,10

0,24

0,38

0,46

0,56

0,70

0,82

1,14

1,52

2,00

) MnO4 ( mmol / L

( ) 1 cm 10 s : MnO4 = f ( t

10 cm 2 mmol / L

( . t = 80 s
( .
--------------------------------------------------------------------------------------------------------------- 12
- 1 :

2 )( ) . (
3 X Po Y
---------------------------------------------------------------------------------------------------------------- 13
------133

t = 0 m0 = 103 g . 54 X e
- 1

133
54 X e

t = 5,25 jours

m = 5 104 g
- 2 10 % .
133

3 78 . 54 X e

 14
r = 20 . L = 0,2 H
. t = 0
1 .
2 ). i = f (t

3 )i = 0,12 (1 e500 t
:
( A
( V2
( V1
: t = 0,1 s
( A
( V2
( V1

E
K

)(L , r

V1

R0
V2