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Plasma Discharge Fundamentals
Plasma Discharge Fundamentals
OUTLINE
ORIGIN OF MINI-COURSE
45 hr graduate course at Berkeley =
12 hr short course in industry =
4 hr mini-course
-1-
Device sizes 30 cm 1 m
Driving frequencies from DC to rf (13.56 MHz) to microwaves
(2.45 GHz)
-2-
-3-
-4-
ANISOTROPIC ETCHING
Wet Etching
Plasma Etching
Ion Enhanced Plasma Etching
-5-
-6-
kTe (kelvins)
e
Quantity
Symbol
Value
Boltzmann constant
Elementary charge
Electron mass
Proton mass
Proton/electron mass ratio
Planck constant
k
e
m
M
M/m
h
h = h/2
c0
0
0
h2 /e2 m
a0 = 4
0
a20
11605 K
1.6022 1019 J
NA
R = kNA
6.0220 1023
8.3144 J/K-mol
1.6606 1027 kg
T0
298.15 K
1.0133 105 Pa
2.6868 1025 m3
133.32 Pa
2.4789 kJ/mol
4.1868 J
RT0
-7a-
-8-
-9-
NON-EQUILIBRIUM
Energy coupling between electrons and heavy particles is weak
Input
power
Electrons
weak
Walls
weak
Ions
weak
strong Walls
strong
Neutrals
strong Walls
in plasma bulk
Bombarding Ei Ee
at wafer surface
-10-
-12-
-12a-
-13-
POISSONS EQUATION
An electric eld can be generated by charges:
dA = Qencl
or
E
E=
0
0
S
E
Qencl
0
= ,
dx
0
Ex =
d
dx
yields
d2
dx2
0
This eld powers a capacitive discharge or the wafer bias power
of an inductive or ECR discharge
-14-
Vrf
FARADAYS LAW
An electric eld can be generated by a time-varying magnetic
eld:
E=
or
E dl =
t
C
B
t
A
Irf
B dA
E
Here B = magnetic induction vector
This eld powers the coil of an inductive discharge (top power)
Irf
~
E
-15-
AMPERES LAW
Both conduction currents and displacement currents generate
magnetic elds:
H = Jc + 0
E
= JT
t
JT = 0
In 1D:
JT x (x, t)
=0
x
so
JT x = JT x (t), independent of x
-16-
REVIEW OF PHASORS
Physical voltage (or current), a real sinusoidal function of time
V (t)
V0
V (t) = V0 cos(t + )
0
of time
V0
V = V0 ej = VR + jVI
Using ej = cos + j sin , we nd
VR = V0 cos ,
Note that
VI = V0 sin
V (t) = Re V e
jt
= V0 cos(t + )
= VR cos t VI sin t
Hence
V (t) V
(given )
-17-
VR
fe (v) = ne
m
2kTe
3/2
mv 2
exp
2kTe
vT e =
(kTe /m)1/2
Pressure p = nkT
For neutral gas at room temperature (300 K)
ng (cm3 ) 3.3 1016 p(Torr)
-18-
vx
1
ne
d3 v 12 mv 2 fe (v) = 32 kTe
Average speed
1
ve =
ne
d3 v vfe (v) =
8kTe
m
1/2
e
y
x
e =
dvx
dvy
dvz vz fe (v) =
0
1
ne ve
4
[m2 -s1 ]
-19-
FORCES ON PARTICLES
For a unit volume of electrons (or ions),
mne
due
= qne E pe mne m ue
dt
pe
pe (x + dx)
x x + dx
-20-
Drag
force
Neutrals
ue
kTe ne
e ne
x
ne
ne0
x
-21-
Fields,
Potentials
Maxwell's
Equations
Newton's
Laws
Charges,
Currents
-22-
DEBYE LENGTH De
The characteristic length scale of a plasma
Low voltage sheaths few Debye lengths thick
Lets consider how a sheath forms near a wall:
Electrons leave plasma before ions and charge wall negative
ne = ni = n0
Electrons
x
n ni = n0
ne
x
x
0
Assume electrons in thermal equilibrium and stationary ions
-23-
ni = n0
dx2
0 Te
Solution is
(x) = 0 ex/De ,
De =
0 Te
en0
1/2
In practical units
De (cm) = 740
Te in volts, n0 in cm3
Te /n0 ,
Example
At Te = 1 V and n0 = 1010 cm3 , De = 7.4 103 cm
= Sheath is 0.15 mm thick (Very thin!)
-24-
Charge/area +
en0 xe
Ions
+
Electrons
+
+
Charge/area
en0 xe
0 xe
E(x)
x
en0 xe (t)
0
pe =
e n0
0 m
1/2
n0 in cm3
-26-
-27-
-28-
etc
H
Total current J
e is mainly due to electrons
Conduction current Jc = ene u
Newtons law (electric eld and neutral drag) is
mm u
jm
ue = eE
e
Solve for u
e and evaluate Jc to obtain
p = 0 1
2
pe
( jm )
-29-
2
pe
2
Plasma
Sheath
0
p
0
J (continuous)
=
E
J
j0
=
E
J
jp
=
E
J
j0
PLASMA CONDUCTIVITY p
e2 ne
=
mm
-31-
1
)
Re (J E
2
[W/m3 ]
to nd pd in terms of E
Put J = (p + j0 )E
2
m
1 2
pd = |E| dc 2
2
2
+ m
= J/(
p + j0 ) to nd pd in terms of J.
Put E
For almost all rf discharges (pe )
pd =
1 2 1
|J|
2
dc
-32-
-33-
(ionization)
e + Ar e + Ar e + Ar + photon
e + Ar e + Ar
(elastic scattering)
(excitation)
e
e
Ar
Ar
-34-
-35-
Ar+
Ar+
Ar+ + Ar Ar+ + Ar
(elastic scattering)
Ar+ + Ar Ar + Ar+
(charge transfer)
Ar
Ar
Ar
Ar+
Ar
Ar+
1
ng i
Practical formula
i (cm) =
1
,
330 p
p in Torr
-36-
vi
i
(voltage units)
Eiz , Eex , and (3m/M )Te are energies lost by an electron due to
an ionization, excitation, and elastic scattering collision
2. Electron kinetic energy lost to walls
Ee = 2 Te
3. Ion kinetic energy lost to walls is mainly due to the dc potential
Vs across the sheath
Ei Vs
Total energy lost per electron-ion pair lost to walls
ET = Ec + Ee + Ei
-37-
-38-
uB
Plasma Sheath
Density
Wall
ns
Due to formation of a presheath, ions arrive at the plasmasheath edge with directed energy kTe /2
1
kTe
M u2i =
2
2
At the plasma-sheath edge (density ns ), electron-ion pairs are
lost at the Bohm velocity
ui = uB =
-39-
kTe
M
1/2
n0
wall
wall
ns
l/2
l/2
ns
uB
=
n0
l i
n0
wall
wall
ns
l/2
l/2
radial = hR n0 uB
0.86
hR
,
1/2
(3 + l/2i )
0.8
1/2
(4 + R/i )
-42-
Pabs
Plasma
ne = ni = n0
l
Particle balance
Production due to ionization = loss to the walls
Kiz ng n0 R2 l = (2R2 hl n0 + 2RlhR n0 )uB
Solve to obtain
Kiz (Te )
1
=
uB (Te )
ng de
where
de =
1
Rl
2 Rhl + lhR
-43-
-44-
i
e
ns
+ Vs
i = n s u B ,
e =
ns ve eVs /Te
4
M
2m
-45-
Vs 0.4 Vrf
Plasma
Vs +
+ Vs
Low voltage
sheath 5.2 Te
Vrf
Vs 0.8 Vrf
Plasma
Vs +
2e
M
1/2 3/2
Vs
s2
Pabs
Ae uB eET
where
Ae = 2R2 hl + 2RlhR
is an eective area for particle loss
Density n0 is proportional to the absorbed power Pabs
Density n0 depends on pressure p through hl , hR , and Te
-47-
-48-
EXAMPLE 1
Let R = 0.15 m, l = 0.3 m, ng = 3.3 1019 m3 (p = 1 mTorr
at 300 K), and Pabs = 800 W
Assume low voltage sheaths at all surfaces
Find i = 0.03 m. Then hl hR 0.3 and de 0.17 m
From the Te versus ng de gure, Te 3.5 V
From the Ec versus Te gure, Ec 42 V. Adding Ee = 2Te 7 V
and Ei 5.2Te 18 V yields ET = 67 V
Find uB 2.9 103 m/s and nd Ae 0.13 m2
Power balance yields n0 2.0 1017 m3
Ion current density Jil = ehl n0 uB 2.9 mA/cm2
Ion bombarding energy Ei 18 V
-49-
EXAMPLE 2
Apply a strong dc magnetic eld along the cylinder axis
= particle loss to radial wall is inhibited
For no radial loss, de = l/2hl 0.5 m
From the Te versus ng de gure, Te 3.3 V
From the Ec versus Te gure, Ec 46 V. Adding Ee = 2Te
6.6 V and Ei 5.2Te 17 V yields ET = 70 V
Find uB 2.8 103 m/s and nd Ae = 2R2 hl 0.043 m2
Power balance yields n0 5.8 1017 m3
Ion current density Jil = ehl n0 uB 7.8 mA/cm2
Ion bombarding energy Ei 17 V
= Signicant increase in plasma density n0
-50-
-50a-
INDUCTIVE DISCHARGES
-93-
MOTIVATION
Independent control of plasma density and ion energy
Simplicity of concept
RF rather than microwave powered
No source magnetic elds
-94-
Planar coil
-95-
EARLY HISTORY
First inductive discharge by Hittorf (1884)
-96-
Plasma
z
Coil
Window
p =
c
1
Im(p1/2 )
m
e2 0 ne
-97-
1/2
12 cm
TRANSFORMER MODEL
For simplicity consider long cylindrical discharge
N turn coil
b
Irf
Ip
Plasma
-98-
where
dc
e2 nes
=
mm
= Rp =
2R
dc lp
Plasma inductance Lp
Lp =
Using magnetic ux = R2 0 Ip /l
0 R2
= Lp =
l
-99-
L12 = L21
0 R2
= Lp =
l
-100-
Zs = Rs + jLs
2R
Rs = N 2
dc lp
0 R2 N 2
Ls =
l
b2
1
R2
1 2
I Rs
2 rf
-101-
EXAMPLE
Assume plasma radius R = 10 cm, coil radius b = 15 cm, length
l = 20 cm, N = 3 turns, gas density ng = 1.7 1014 cm3
(5 mTorr argon at 300 K), = 85 106 s1 (13.56 MHz),
absorbed power Pabs = 600 W, and low voltage sheaths
At 5 mTorr, i 0.6 cm, hl hR 0.19, and de 17.9 cm
Particle balance (Te versus ng de gure) yields Te 2.6 V
Collisional energy losses (Ec versus Te gure) are Ec 58 V
Adding Ee + Ei = 7.2 Te yields total energy losses ET 77 V
uB 2.5 105 cm/s and Ae 350 cm2
Power balance yields ne 5.6 1011 cm3 and nse 1.0
1011 cm3
Use nse to nd skin depth p 1.7 cm; estimate m = Kel ng
(Kel versus Te gure) to nd m 1.4 107 s1
Use m and nse to nd dc 113 1 -m1
Evaluate impedance elements Rs 14.7 and Ls 2.2 H;
|Zs | Ls 190
Power balance yields Irf 9.0A; from impedance Vrf 1720 V
-102-
Irf
N turn coil
p
Ip
Plasma
Primary
inductance
Coupling
inductance
Plasma
inductance
on axis
max, at r 12 Rwall
0,
at r = Rwall
-104-
INDUCTIVE DISCHARGES
POWER BALANCE
-105-
dc p
ne
Rs
ne
p plasma size
ne
-106-
1
ne
-107-
+
Vrf
Ip
Plasma
z
Cap Mode
Pabs = 12 I12 Rs
Ind Mode
-108-
ne
-109-
SOURCE EFFICIENCY
The source coil has some winding resistance Rcoil
Rcoil is in series with the plasma resistance Rs
Power transfer eciency is
=
Rs
Rs + Rcoil
Rs
ne
1
ne
p plasma size
ne
-112a-
CONCLUSIONS
-111-