Trung tm luyn thi Y - Dc

n thi i hc nm 2014 - 2015

KIM TRA KT THC CHNG AMIN - AMINO AXIT - PEPTIT - POLIME

H v tn:...........................................................................im:...................................
Cu 1: S amin c cha vng benzen c cng thc phn t C7H9N khi phn ng vi HNO2 nhit thng ng vai
tr cht kh l:
A. 3.
B. 4.
C. 5.
D. 6.
Cu 2: Cao su buna - N c to ra do phn ng ng trng hp gia butaien - 1,3 v acrilonitrin. t chy hon ton
mt lng cao su buna - N vi lng khng kh va (cha 20% O2 v 80% N2 v th tch), sau a hn hp sau
phn ng v 136,5 0C thu c hn hp kh v hi Y cha 14,407% CO2 v th tch. T l s mt xch butaien - 1,3 v
acrilonitrin l?
A. 1 : 2.
B. 2 :3.
C. 3 : 2.
D. 2 : 1.
Cu 3: Cho cc dung dch: C6H5NH3Cl (phenylamoni clorua), NH2CH2CH2CH(NH2)COOH, ClNH3CH2
COOH, HOOCCH2CH2CH(NH2)COOH, NH2CH2COONa. S lng cc dung dch c pH < 7 l:
A. 2.
B. 4.
C. 5.
D. 3.
Cu 4: Sp xp tnh baz tng theo th t sau:
A. C6H5NH2 , (C6H5)2NH, CH3NH2, C2H5NH2, (C2H5)2NH.
B. (CH3)2NH , C6H5NH2, C2H5NH2, (C2H5)2NH, (C6H5)2NH.
C. (C6H5)2NH , C6H5NH2, CH3NH2, C2H5NH2, (C2H5)2NH.
D. C2H5NH2 , CH3NH2, C6H5NH2, (CH3)2NH, (C6H5)2NH, (C2H5)2NH.
Cu 5: Cho cc cht sau: C2H5OH, C6H5OH, C2H5NH2, dung dch C6H5NH3Cl, dung dch NaOH, CH3COOH,
dung dch HCl long. Cho tng cp cht tc dng vi nhau c xc tc, s cp cht xy ra phn ng l:
A. 10.
B. 9.
C. 11.
D. 8.
+CH3 I(1:1)
+HNO2
+CuO,t 0
Cu 6: Cho s phn ng: NH3
X Y Z
Bit Z c kh nng tham gia phn ng trng gng. Hai cht Y v Z ln lt l:
A. C2H5OH, CH3CHO .
B. C2H5OH, HCHO.
C. CH3OH, HCHO.
D. CH3OH, HCOOH.
Cu 7: Pht biu no sau sau l ng:
A. Anilin tc dng vi axit nitr khi un nng thu c mui iazoni.
B. Benzen lm mt mu nc brom nhit thng.
C. Etylamin phn ng vi axit nitr nhit thng, sinh ra bt kh.
D. Cc ancol a chc u phn ng vi Cu(OH)2 to dung dch mu xanh lam.
Cu 8: Alanin c th phn ng c vi bao nhiu cht trong cc cht cho sau y: Ba(OH)2; CH3OH;
H2N-CH2-COOH; HCl; Cu; CH3NH2; C2H5OH; Na2SO4; H2SO4.
A. 4.
B. 5.
C. 6.
D. 7.
Cu 9: Cho hai hp cht hu c X, Y c cng cng thc phn t l C3H7NO2. Khi phn ng vi dung dch NaOH,
X to ra H2NCH2COONa v cht hu c Z; cn Y to ra CH2=CHCOONa v kh T. Cc cht Z v T ln lt l:
C. CH3OH v NH3.
D. CH3NH2 v NH3.
A. CH3OH v CH3NH2. B. C2H5OH v N2.
Cu 10: Cho tng cht H2NCH2COOH, CH3COOH, CH3COOCH3 ln lt tc dng vi dung dch NaOH (t0)
v vi dung dch HCl (t0). S phn ng xy ra l:
A. 3.
B. 6.
C. 4.
D. 5.
Cu 11: Thu phn hon ton 1 mol pentapeptit A th thu c 3 mol glyxin ; 1 mol alanin v 1mol valin. Khi thu
phn khng hon ton A th trong hn hp sn phm thy c cc ipeptit Ala-Gly ; Gly-Ala v tripeptit Gly-Gly-Val.
Amino axit u N, amino axit u C pentapeptit A ln lt l
A. Gly, Val.
B. Ala, Val.
C. Gly, Gly.
D. Ala, Gly.
Cu 12: Cho cc cht: (I) metyl axetat; (II) amoni axetat; (III) metyl amino axetat; (IV) etyl amoni nitrat; (V) axit glutamic;
(VI) axit gluconic; (VII) natri axetat. S cht va tc dng vi HCl, va tc dng vi NaOH (xc tc y ) l
A. 2.
B. 3.
C. 5.
D. 4.
Cu 13: Peptit: HOOCCH(CH3)NHCOCH2NHCOCH2NH2 c tn l
A. Glyxinalaninglyxin. B. Glyxylglyxylalanin. C. Alaninglyxinglyxin. D. Alanylglyxylglyxin.
Cu 14: Cho 0,125 mol -amino axit A tc dng vi 200 ml dung dch HCl 1M thu c dung dch X. Dung dch X tc
dng va vi 300 ml dung dch NaOH 1,5M thu c dung dch Y. C cn dung dch Y thu c 35,575 gam rn khan.
E l tetrapeptit A - B - A - B (B l -amino axit no cha 1 nhm -NH2 v 1 nhm -COOH). t chy hon ton 8,92 gam E
bng lng oxi va . Sn phm chy gm CO2, H2O v N2 trong tng khi lng ca CO2 v H2O l 21,24 gam. B l.
A. Glyxin
B. Valin
C. Alanin
D. - amino butanoic
Cu 15. Trong cc phn ng sau, phn ng no l phn ng khu mch polime?
OH
A. Poli(vinyl axetat) + nH2O

poli(vinyl ancol) + nCH3COOH.

B. Cao su thin nhin + HCl
cao su hiroclo ha.
300 C
C. Polistiren
nStiren.

150 C
D. Nha rezol
nha rezit + H2O
-

Bin son v ging dy: Ngc - Ha - 0982.163.448

Face: NGOC XUAN hoc TI LIU HA HC THY NGC

Trung tm luyn thi Y - Dc

n thi i hc nm 2014 - 2015

Cu 16: Cho 2,1 gam hn hp X gm 2 amin no, n chc, k tip nhau trong dy ng ng phn ng ht vi dung dch
HCl (d), thu c 3,925 gam hn hp mui. Cng thc ca 2 amin trong hn hp X l
A. C3H7NH2 v C4H9NH2.
B. CH3NH2 v C2H5NH2.
C. CH3NH2 v (CH3)3N.
D. C2H5NH2 v C3H7NH2.
Cu 17: Hiro ho cao su Buna thu c mt polime c cha 11,765% hiro v khi lng, trung bnh mt phn t H2
phn ng c vi k mt xch trong mch cao su. Gi tr ca k l
A. 2.
B. 5.
C. 3.
D. 4.
Cu 18: Cho cc polime: PE, PVC, polibutaien, poliisopren, amiloz, amilopectin, xenluloz, cao su lu ho. Dy
gm cc polime c cu trc mch thng l:
A. PE, polibutaien, poliisopren, amiloz, xenluloz, cao su lu ho.
B. PE, PVC, polibutaien, poliisopren, xenluloz, cao su lu ho.
C. PE, PVC, polibutaien, poliisopren, amiloz, xenluloz.
D. PE, PVC, polibutaien, poliisopren, amiloz, amilopectin, xenluloz.
Cu 19: Trung ho hon ton 8,88 gam mt amin X (bc mt, mch cacbon khng phn nhnh) bng axit HCl, to ra
17,64 gam mui. t chy hon ton 0,1 mol amin X thu c tng khi lng CO2 v H2O l?
A. 22,2.
B. 33,3
C. 44,4
D. 88,8
Cu 20. T nilon6,6 c iu ch bng phn ng trng ngng
B. HOOC-(CH2)4-COOH v HO-(CH2)4-OH.
A. HOOC-(CH2)2-CH(NH2)-COOH.
C. HOOC-(CH2)4-COOH v H2N-(CH2)6-NH2. D. H2N-(CH2)5-COOH.
Cu 21: t chy ht m gam hn hp amin X gm hai amin no, n chc, mch h thu c a gam nc v V lit CO 2
(ktc). Mi lin h gia m, a, V l
A. m =

17a 5V
+
27
42

B. m =

7a 5V
+
27 42

C. m =

17a V
+
27 42

D. m =

17a 5V
+
27 32

Cu 22: Amino axit mch khng phn nhnh X cha a nhm -COOH v b nhm -NH2. Khi cho 1mol X tc dng ht vi
axit HCl thu c 169,5 gam mui. Cho 1 mol X tc dng ht vi dung dch NaOH thu c 177 gam mui. Cng thc
phn t ca X l
A. C4H7NO4
B. C3H7NO2
C. C4H6N2O2
D. C5H7NO2
Cu 23. Nha rezit (nha bakelit) c iu ch bng cch
A. un nng nha rezol 1500C to mng khng gian.
B. un nng nha novolac 1500C to mng khng gian.
C. un nng nha novolac vi lu hunh 11500C to mng khng gian.
D. un nng nha rezol vi lu hunh 1500C to mng khng gian.
Cu 24: X l mt -amino axit cha 1 nhm COOH v 1 nhm NH2. Cho 8,9 gam X tc dng vi 200 ml dung dch
HCl 1 M thu c dung dch Y. phn ng ht vi cc cht trong dung dch Y cn dng 300 ml dung dch NaOH 1 M.
Cng thc ng ca X l:
A. CH3CH(NH2)COOH.
B. CH3C(CH3)(NH2)COOH.
C. CH3CH2CH(NH2)COOH.
D. CH3CH(CH3)CH(NH2)COOH.
Cu 25. Cho mt s hp cht sau: (1) etilen, (2) vinyl clorua, (3) axit aipic, (4) phenol, (5) acrilonitrin,
(6) buta1,3ien. Nhng cht c th tham gia phn ng trng hp l:
A. (1), (2), (5), (6).
B. (1), (2), (3), (4).
C. (1), (4), (5), (6).
D. (2), (3), (4), (5).
Cu 26. Este X c iu ch t mt ancol Y v mt amino axit Z. T khi hi ca X so vi H2 l 44,5. Cho 17,8 gam X
phn ng ht vi 250ml dung dch NaOH 1M thu c dung dch T. C cn dung dch T thu c m gam cht rn khan.
Gi tr ca m l
A. 19,4
B. 21,4
C. 24,2
D. 27,0
Cu 27. Nhm cc vt liu c ch to t polime trng ngng l:
A. Cao su, nilon-6,6, t nitron.
B. T axetat, nilon -6,6, PVC.
C. Nilon - 6; t lapsan, caproamit.
D. Nilon-6,6; t lapsan, capron.
Cu 28: Hn hp M gm anken X v hai amin no, n chc, mch h Y, Z (MY < MZ). t chy hon ton mt lng M
cn dng 21 lt O2 sinh ra 11,2 lt CO2 (cc th tch kh u o ktc). Cng thc ca Y l
A. CH3NH2.
B. CH3CH2CH2NH2.
C. C2H5NH2.
D. CH3CH2NHCH3
Cu 29: Poli(vinyl clorua) (PVC) c iu ch t kh thin nhin (cha 95% th tch kh metan) theo s chuyn ha
v hiu sut ca mi giai on nh sau :
%
%
%
Metan 15
Axetilen 95
Vinyl clorua 90
PVC

3
Mun tng hp 1 tn PVC th cn bao nhiu m kh thin nhin (o ktc) ?
A. 5,883.
B. 5589,462.
C. 5589,083.
D. 5883,246.
Cu 30: T 3 -amino axit Ala, Gly, Val c th to thnh ti a my tripeptit m trong thnh phn cu to ch cha 2
gc -amino axit khc nhau?
A. 8.
B. 18.
C. 27.
D. 24.
.........................................HT.........................................
Bin son v ging dy: Ngc - Ha - 0982.163.448

Face: NGOC XUAN hoc TI LIU HA HC THY NGC