StereochemistryQuiz

SSCK 2613 (Semester2012D013-1)

Course:

Name:

t.

Assign R or S for theseperspectivedrawings below:

OH

CHO

]..*,CH3

(o)

.rr\.tr.t,

"rc'c{1r",

(R)
H

COOH

ds)
(s) "o-.}-{1"
cHr
u.C
(3 marks)
2.

Give the nameof the compoundsbelow accordingtoElZ system.

t*
HrCrl
ZTCH2CHt

cr-fi,,rc:ca. cHzoH

G I - e- %

-3 rctot'yo,,"&c"fb,'d-2' en- t- 6l .
(l mark)

3.

Convert the Fischerprojection below to perspectivedrawing and assignR/S.

H:C

cH2oH

"tfe)

tro{n7r
(l mark)

(ii)

3.

Assign R/S to eachasymmetric carbon in the structures

below and convert to Fischer
projection.

+s)

Br.

trlb_oH (3F)

---

)_.--LcHrcH,

H:Ct"7u-ut
HOH

n.

arc
b,r.o,g#,--l* NFf,
22
l\CR)

CHO

cl-

|.,,,,NH2
,zY-

2cH2cH2Br
f\cH
t\ , o
0\

(2 marks)
3'

Show the asymmetric carbons using asteriskand convert

to Fischer structure. Assign
R/S.

9Ho
cH3cH2cHoHCH2CHrcHCHrCnzNHz
fi--;ftLL

(,t+
tCl4z

l5,l\G)

(3 marks)
{ii}