log pO2(g)

10

Pb-O -S Phase Stability Diagram at 850.000 C

Pb2O3

PbSO4
PbO

-5

-10
Pb

-15
-60

-50

-40

PbS

-30

-20

-10

File: C:\HSC5\Lpp\PbOS850.ips

10

20
log pS2(g)

Pb-O -S Phase Stability Diagram at 850.000 C

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X=
Y=
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8
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Temperature 1123.150
Species
Pb
O
Pb
1.000 0.000 0.000
PbO 1.000 1.000 0.000
Pb2O3
2.000 3.000
Pb3O4
3.000 4.000
PbS 1.000 0.000 1.000
PbSO4
1.000 4.000
S2(g) 0.000 0.000 2.000
O2(g) 0.000 2.000 0.000

K
S
DeltaG, kcal/mol
0.000
-25.606
0.000 -43.725
0.000 -68.447
-15.569
1.000 -118.751
0.000
0.000

REACTIONS at T = 1123.150
G / cal
1.000 Pb + 0.500 O2(g) -> PbO
-25605.700
2.000 Pb + 1.500 O2(g) -> Pb2O3
-43725.000
3.000 Pb + 2.000 O2(g) -> Pb3O4
-68446.800
1.000 Pb + 0.500 S2(g) -> PbS
-15568.700
1.000 Pb + 0.500 S2(g) + 2.000 O2(g) -> PbSO4
-118751.300
2.000 PbO + 0.500 O2(g) -> Pb2O3
7486.400
3.000 PbO + 0.500 O2(g) -> Pb3O4
8370.300
1.000 PbO + 0.500 S2(g) -> 0.500 O2(g) + PbS
10037.000
1.000 PbO + 0.500 S2(g) + 1.500 O2(g) -> PbSO4
-93145.600
1.500 Pb2O3 -> 0.250 O2(g) + Pb3O4
-2859.300
0.500 Pb2O3 + 0.500 S2(g) -> 0.750 O2(g) + PbS
6293.800

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0.500 Pb2O3 + 0.500 S2(g) + 1.250 O2(g) -> PbSO4

-96888.800
0.333 Pb3O4 + 0.500 S2(g) -> 0.667 O2(g) + PbS
7246.900
0.333 Pb3O4 + 0.500 S2(g) + 1.333 O2(g) -> PbSO4
-95935.700
1.000 PbS + 2.000 O2(g) -> PbSO4

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COORDINATES OF TRIPLE POINTS

Phases Present
Log pS2(g) Log pO2(g)
Pb - PbO - PbSO4
-6.354
-9.964
Pb - PbS - PbSO4
-6.058
-10.038
PbO - Pb2O3 - PbSO4
-44.986
2.913

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LINES BETWEEN TRIPLE POINTS AND AXIS

Log pS2(g) Log pO2(g) Log pS2(g) Log pO2(g)
Pb - PbSO4 -6.354
-9.964
-6.058
-10.038
PbO - PbSO4 -6.354
-9.964
-44.986
2.913
Pb-PbO
-60.000
-9.964
-6.354
-9.964
Pb-PbS
-6.058
-15.000
-6.058
-10.038
PbS-PbSO4 40.000
-10.038
-6.058
-10.038
PbO-Pb2O3 -60.000
2.913 -44.986
2.913
Pb2O3-PbSO4
-60.000
8.919 -44.986
2.913

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-103182.600