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AIPMT Sample Paper-6 (2009-Sample Paper)
AIPMT Sample Paper-6 (2009-Sample Paper)
com
1.
X !"
Z A1
Y !"
AB 4
ZB 1
!"
AB 4
ZB 1
are:
(1) #, $, %
(3) %, $, #
Sol:
A
Z
X !"
(2) $, #, %
(4) $, %, #
A
ZA 1
Y : $,
A
Z A1
Y !"
AB 4
ZB 1
B : %,
A B 4
Z B 1
B !"
A B 4
Z B1
B:#
( $, %, #)
&
2.
A thin circular ring of mass M and radius R is rotating in a horizontal plane about
an axis vertical to its plane with a constant angular velocity '. If two objects each
of mass m be attached gently to the opposite ends of a diameter of the ring, the
ring will then rotate with an angular velocity:
(1)
(3)
Sol:
'M
(2) ' M A 2m
M A 2m
'M
(4) ' M B 2m
M A m
M A 2m
I
I
1
2
' =
M
M A 2m
'.
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4.
Sol:
5.
The number of photo electrons emitted for light of a frequency ( (higher than the
threshold frequency (0) is proportional to:
(1) +a
(2) 3+
(3) +a
(4) +a
Speed v = '
a
2
a B x , x =
2
a B
a
= '
4
=
2T
& v = '
6.
Sol:
3a
4
2+ a 3
T
+a 3
T
&
(1) , 2 B i 2 r 2 B ,1 B i1 r 1 = 0
(2)
(3) ,1 B
(4) ,1 B
i A i
1
R A i r = 0
1
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B , B i A i
2
i A i
1
R A i r = 0
2
R B i r = 0
1
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Sol:
,1 ) (i1 + i2)R ) i1 r1 = 0.
&
7.
(1) 10 kg
Sol:
F = 6i B 8 j
F =
(2) 20 kg
A 10k ,
(3) 10
(4) 2
2 kg
10 kg
36 A 64 A 100 = 10 2 N
)2
a = 1 ms
& m =
10 2
= 10 2 kg
1
&
8.
The logic symbols for OR, NOT and NAND gates are respectively:
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9.
Sol:
If F is the force acting on a particle having position vector r and - be the torque
of this force about the origin, then:
(1)
(2)
r - = 0 and F - = 0
(3)
r - = 0 and F - 0
(4)
r - 0 and F - = 0
- = r F . r - = 0
F- = 0
&
10.
The two ends of a rod of length L and a uniform cross-sectional area A are kept at
two temperatures T1 and T2 (T1 > T2). The rate of heat transfer, dQ through the
dt
rod in a steady state is given by:
(1) dQ
(3) dQ
dt
dt
Sol:
k T B T
1
(2) dQ
= kLA T B T
(4) dQ
dt
LA
kA T B T
1
dt
kL T B T
1
kA T B T
dQ
1
2
=
dt
L
A p-n photodiode is fabricated from a semiconductor with a band gap of 2.5 eV. It
can detect a signal of wavelength:
(1) 4000 nm
Sol:
&
11.
max
hc
E
(2) 6000 nm
6.6 10
B 34
(3) 4000
3 10
2.5 1.6 10
B 19
(4) 6000
5000
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12.
(1)
(2)
(3)
(4)
Sol:
Pressure =
MLT
L
B2
= ML
B1
B2
. a = 1, b = ) 1, c = ) 2.
&
13.
(1) 100
(2) 150
Sol: 1IE = 1IB + 1 IC
$ =
1I
1I
(4) 75
C
B
)3
1IC = 5 2 10
A
)6
1IB = 100 2 10
$=
(3) 50
5
100
1000 = 50
&
14.
Sol:
The mass of a lift is 2000 kg. When the tension in the supporting cable is 28000 N,
then its acceleration is:
8000
2000
= 4 ms
B2
3
&
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15.
Four identical thin rods each of mass M and length l, form a square frame.
Moment of inertia of this frame about an axis through the centre of the square
and perpendicular to its plane is :
(1) 2
Sol:
mL
12
Ml
(2) 13
mL
4 mL
12
Total M.I. = 4 2 mL
3
Ml
mL
(3) 1
Ml
(4)
Each of the two strings of length 51.6 cm and 49.1 cm are tensioned separately by
20 N force. Mass per unit length of both the strings is same and equal to 1 g/m.
When both the strings vibrate simultaneously the number of beats is:
(1) 7
Sol:
Ml
&
16.
f1 =
(2) 8
1
2l
T
1
T
=
m
l Bl
1
l l
1
, f2 =
20
10
2
B3
1
2l
(3) 3
T
,f )f = 1
m 2 1 2
T l1 B l 2
m l l
1
51.6 B 49.1 10
(4) 5
51.6 49.1
2.5 10
50 50
1
10
17.
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18.
Figure
The
shows a plot of photo current versus anode potential for a photo
sensitive surface for three different radiations. Which one of the following is a
statement?
correct
(1)
(2)
(3)
(4)
19.
curves (a) and (b) represent incident radiations of same frequency but of
different intensities.
curves (b) and (c) represent incident radiations of different frequencies and
different intensities.
curves (b) and (c) represent incident radiations of same frequency having
same intensity.
curves (a) and (b) represent incident radiations of different frequencies and
different intensities.
&
Figure
The
shows elliptical orbit of a planet
about the sum S. The shaded area
SCD is twice the shaded area SAB. If 1 is the time for the planet of move from C
to D and
Sol:
(1) t1 = 4t2
(2) t1 = 2t2
(3) t1 = t2
(4) t1 > t2
A
t
, t1 = t2 4
A
A
, A1 = 2A2
& t1 = 2t2
&
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20.
2
A black body at 2275C radiates heat at the rate of 7 Cals/cm s. At a temperature
of 7275C, the rate of heat radiated in the same units will be:
(1) 50
Sol:
(2) 112
(3) 80
(4) 60
E = 6T4,
4
E
E
1000
500
= 16
T1 = 500 K
T2 = 1000 K
& E2 = 16 2 7 = 112 cal/cm2 s.
&
21.
The driver of a car travelling with speed 30 m/sec towards a hill sounds a horn of
frequency 600 Hz. If the velocity of sound in air is 330 m/s, the frequency of
reflected sound as heard by driver is:
(1) 555.5 Hz
(2) 720 Hz
(3) 500 Hz
(4) 550 Hz
Sol:
f7 =
v A 30
v A 30
360
v
f, f 8 =
f7 =
f =
600
v B 30
v
v B 30
300
= 720 Hz
&
22.
A wire of resistance 12 ohms per meter is bent to form a complete circle of radius
10 cm. The resistance between its two diametrically opposite points, A and B as
shown in the
is:
Figure,
(1) 3 9
(2) 6 + 9
(3) 6 9
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(4) 0.6 + 9
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Sol:
2+R !" 12 9
& R =
23.
6 6
12
=39
&
emf
Sol:
24.
Sol:
(1)
(2)
(3)
(4)
As the loop leaves the magnetic field, area in magnetic field decreases for all
loops, so induced emf does not remain constant. (Any of four loops)
&
(1)
(2)
(3)
(4)
G = 60 9, Ig = 1.0 A, I = 5 A.
Ig G= (I ) Ig) S,
S =
I G
g
I B I
=
g
1
5 B1
60 = 15 9
putting 15 9 in parallel.
&
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25.
R A
Lw B
(1)
, R
Lw B
, R
2
1
Lw B
Cw
R A
Cw
,
Cw
Lw B
(4)
2
2
(2)
Sol:
1
Cw
(3)
2
2
, R
R =
2
2
R A 'L B
26.
emf , is:
&
1
'C
Three concentric spherical shells have radii a, b and c (a < b < c) and have surface
charge densities 6, ) 6 and 6 respectively. If VA, VB and VC denote the potentials
of the three shells, then for c = a + b, we have:
VC = VB : VA
VC : VB : VA
Sol:
(1)
(3) VC = VB = VA
(2)
(4) VC = VA : VB
c = a + b.
v
6
,
6b
,
B 6b
6Q
4+ ,
6
,
c B b Ba
6 4+a
b B a
c B
6c
,
6c
6c
1
4+ ,
6 4+ b
c
1
4+ ,
6 4+a
,
6
,
c B
&
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c B b B a
VA = VC : VB
b Ba
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27.
An engine pumps water continuously through a hose. Water leaves the hose with
a velocity and
is the mass per unit length of the water jet. What is the rate at
which kinetic energy is imparted to water?
(1) mv2
Sol:
(2) 2
mv
(3) 2
2 2
(4) 2
m v
1
2
t
2
mv v =
= mv .
3
1
mv
2
&
28.
mv
)1
)4
Sol:
(1) 12 J
(2) 6 J
(3) 2 J
(4) 0.6 J
1
2
2 10 6 10
2
B4
= 6 J
&
29.
(1)
(2)
(3)
(4)
directly proportional to z1 z2
inversely proportional to z1
directly proportional to mass M1
directly proportional to M1 2 M2
&
30.
(1) 3 2 1016
(2) 9 2 1015
(3) 3 2 1019
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(4) 9 2 1017
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Sol:
)9
/ = 667 2 10
Nhc
P =
N =
9 10
B3
6.6 10
=
)3
m, P = 9 2 10
667 10
B 34
3 10
9 6.67 10
3 6.6 10
B9
8
B 10
B 26
16
3 10 sec
&
31.
(1)
(2)
(3)
(4)
Sol:
A = 2 cm,
'
k
= 128 ms
B1
, 5/ = 4, / =
4
m
5
2+
/
2+ 5
4
31.4
= 7.85
4
32.
(1)
(2)
(3)
(4)
Sol:
acceleration = ) k(x + a)
acceleration = k(x + a)
acceleration = kx
2
acceleration = ) k0x + k1x
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33.
Sol:
emf
V + ir = E
V = VA ) VB
E ) ir
=V
=i
= B r, i = 0, v = E
34.
If a diamagnetic substance is brought near the north or the south pole of a bar
magnet, it is:
(1)
(2)
(3)
(4)
35.
Sol:
)1
(1) 40 ms)1
(2) 25 ms)1
(3) 10 ms)1
(4) 20 ms)1
&
36.
Sodium has body centred packing. Distance between two nearest atoms is 3.7 .
The lattice parameter is:
(1) 4.3
(2) 3.0
(3) 8.6
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(4) 6.8
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Sol:
3.7 =
a =
2 3.7
3
= 4.3
&
37.
The internal energy change in a system that has absorbed 2 Kcals of heat and
done 500 J of work is:
(1) 6400 J
Sol:
(2) 5400 J
(3) 7900 J
(4) 8900 J
Q = 1U + W
1U = Q ) W = 2 2 4.2 2 1000 ) 500 = 8400 ) 500
= 7900 J
&
38.
(1) 3C,
Sol:
(2)
C
3
(3) 3C, 3V
, 3V
(4)
C
3
Q = CV
Veff = V + V + V = 3 V
1
C
eff
1
C
1
C
1
C
. C
eff
C
3
C
, 3V
3
&
39.
An explosion blows a rock into three parts. Two parts go off at right angles to each
)1
and 2 kg
second part moving with a velocity of 8 ms . If the third part flies off with a
)1
(1) 7 kg
(2) 17 kg
(3) 3 kg
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(4) 5 kg
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Sol:
Mv cos ; = 12
Mv sin ; = 16
tan ; =
M =
16
12
12 5
4 3
4
3
=
60
= 5 kg
12
&
40.
A particle starts its motion from rest under the action of a constant force. If the
distance covered in first 10 seconds is S1 and that covered in the first 20 seconds
is S2, then:
(1) S2 = 3S1
Sol:
s =
1
(2) S2 = 4S1
&
(4) S2 = 2S1
2
2
1
1
a t ,s =
a t
1
2
2
2
2
2
(3) S2 = S1
t
=
10
20
1
4
s2 = 4 s1
&
41.
Sol:
(1) 30 J
(2) 40 J
mv B mgh =
(3) 10 J
(4) 20 J
1 400 B 1 18 10
= 200 ) 180 = 20 J
&
42.
A conducting circular loop is placed in a uniform magnetic field 0.04 T with its
plane perpendicular to the magnetic field. The radius of the loop starts shrinking
at 2 mm/s. The induced emf in the loop when the radius is 2 cm is:
(1) 4.8 + 0V
(2) 0.8 + 0V
(3) 1.6 + 0V
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(4) 3.2 + 0V
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Sol:
e =B B
d
dt
+r
dr
= B B + 2r
dt
)2
)3
2 2 2 10
)7
= ) 0.04 2 25.12 2 10
)7
= 100.48 2 10
)7
= 32 + 2 10
)6
= 3.2 + 2 10
&
43.
B1
, is:
(1) 4 N is z direction
(3) 8 N in z direction
(2) 8 N is y direction
(4) 8 N in ) z direction
)6
C [2 2 2 2 106] = ) 8 N z-axis
F = q V B = ) 2 2 10
&
44.
R =
(2) 2 i
B j A k
m R A m R
1
m A m
1
(3) B i
B j B 2k
(4) B 2 i
A j A k
(1)
E = i 2xy A j x A y
(2)
E = i z A j xyz A k z
(3)
E = i 2xy B z
(4)
E = i 2xy A z
3
3
A 2k
1
B 8 i B 4 j A 4 k =B 2 i B j A k
4
&
45.
(1) B 2 i
Sol:
Sol:
V = 3.2 + 0 V
A k 3xz B y
2
2
A j xu A k 3z
2
A j x A k 3xz
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Sol:
E =B
=V
= B
=r
=V
=x
i B
2 xy A z
=V
=y
j B
=V
=z
i A j x A k 3 xz
&
46.
)8
The mean free path of electrons in a metal is 4 2 10 m. The electric field which
can given on an average 2 eV energy to an electron in the metal will be in units of
V/m:
(2) 8 2 10)11
(1) 5 2 10)11
Sol:
E=
V
d
2
4 10
(3) 5 2 107
8
B8
= 0.5 10 = 5 10 Vm
(4) 8 2 107
B1
&
47.
Sol:
The ionization energy of the electron in the hydrogen atom in its ground state is
13.6 eV. The atoms are excited to higher energy levels to emit radiations of 6
wavelengths. Maximum wavelength of emitted radiation corresponds to the
transition between:
(1) n = 3 to n = 1 states
(2) n = 2 to n = 1 states
(3) n = 4 to n = 3 states
(4) n = 3 to n = 2 states
n n B1
2
= 6
n2 ) n ) 12 = 0
(n ) 4) (n + 3) = 0 or n = 4
&
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48.
Under the influence of a uniform magnetic field, a charged particle moves with
constant speed V in a circle of radius R. The time period of rotation of the particle:
(1)
(2)
(3)
(4)
Sol:
T=
49.
= 2.5
N
cos
C
2+ 10
rad
m
t B + 10
B2
rad
s
x ;
Sol:
(1)
(2)
(3)
(4)
moving along x direction with frequency 106 Hz and wave length 100 m.
6
= k = + 10
B2
B1
, / = 200 m
&
50.
Sol:
A block of mass M is attached to the lower end of a vertical spring. The spring is
hung from a ceiling and has force constant value k. The mass is released from rest
with the spring initially unstretched. The maximum extension produced in the
length of the spring will be:
(1) 2 Mg/k
(2) 4 Mg/k
(3) Mg/2k
(4) Mg/k
ka = mg
a=
mg
k
&
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51.
BIOLOGY
correct pairing
"
The epithelial tissue present on the inner surface of bronchioles and fallopian
tubes is:
(1) Glandular
53.
(2) Ciliated
(3) Squamous
(4) Cuboidal
" Correct choice : (2)
(1) Inheritance
trait
Sol:
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54.
55.
56.
Sol:
(1) Soybean
(2) Sunnhemp
(3) Tobacco
(4) Tulip
Soyabean and Sunnhemp have monocarpellary pistil and tulip has trimerous
flower and perianth.
57.
(2) Ctenophores
(4) Coelenterates (Cnidarians)
" Correct choice : (1)
Which one of the following is commonly used in transfer of foreign DNA into crop
plants ?
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(3) Menstruation
(4) Ovulation
60.
Which one is the wrong pairing for the disease and its causal organism ?
Puccinia graminis
! Ustilago nuda
! Meloidogyne sp
! Alternaria solani
!
"
61.
What is
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65.
66.
(1) Sorosis
67.
(2) Syconus
(3) Caryopsis
(4) Hesperidium
" Correct choice : (2)
The cell junctions called tight, adhering and gap junctions are found in:
68.
What will happen if the stretch receptors of the urinary bladder wall are totally
removed ?
69.
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70.
The most popularly known blood grouping is the ABO grouping. It is named ABO
and not ABC, because O in it refers to having:
72.
(1) IAA
(2) GA
(3) IBA
(4) NAA
" Correct choice : (4)
73.
74.
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75.
permanently
(1) administering adenosine deaminase activators.
(2) introducing bone marrow cells producing ADA into cells at early embryonic
stages.
ADA cDNA.
"
76.
(1) caused by substitution of valine by glutamic acid in the beta globin chain of
haemoglobin
Which of the following plant species you would select for the production of
bioethanol ?
(3) Jatropha
(4) Brassica
" Correct choice : (3)
When breast feeding is replaced by less nutritive food low in proteins and calories;
the infants below the age of one year are likely to suffer from:
(1) Rickets
(2) Pongamia
(2) Kwashiorkor
(3) Pellagra
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(4) Marasmus
" Correct choice : (2)
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80.
A young infant may be feeding entirely on mothers milk which is white in colour
but the stools which the infant passes out is quite yellowish. What is this yellow
colour due to ?
81.
82.
83.
Sol:
(1) Mango
(2) Wheat
(3) Tea
(1) Oscillatoria
(3) Chlorobium
(4) Teak
" Correct choice : (2)
(2) Rhodospirillum
(4) Chromatium
" Correct choice : (1)
84.
(1) C-Karyokinesis
(3) A-Cytokinesis
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85.
of food in humans ?
(2) Chylomicrons
87.
88.
seminal vesicle
prostate
bulbourethral
gland
seminal vesicle
bulbourethral
gland
prostate
(3) ureter
seminal vesicle
prostate
bulbourethral
gland
(4) ureter
prostate
seminal vesicle
bulbourethral
gland
"
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89.
What is
90.
91.
92.
93.
(1) Pinus
(2) Cycas
(3) Papaya
(4) Marchantia
" Correct choice : (1)
(2) Tonsil
(3) Thymus
(4) Thyroid
" Correct choice : (3)
"
94.
dicotyledonous
root
is
distinguished
from
the
Plasmodesmata are :
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96.
Removal of introns and joining the exons in a defined order in a transcription unit
is called:
(1) Tailing
97.
(2) Cerebrum
(4) Medulla Oblongata
" Correct choice : (3)
Which part of human brain is concerned with the regulation of body temperature?
(1) Cerebellum
(3) Hypothalamus
99.
(4) Splicing
" Correct choice : (4)
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103.
A country with a high rate of population growth took measures to reduce it. The
below shows age-sex pyramids of populations A and B twenty years apart.
Select the
interpretation about them:
Figure
correct
Interpretations:
105.
106.
(1) Dianthus
(1) Polytrichum
(3) Wheat
(2) Lemon
(3) Marigold
(4) Argemone
" Correct choice : (2)
(2) Ustilago
(4) Funaria
"
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107.
(1) compulsory
(2) permission to use only pure diesel with a maximum of 500 ppm sulphur as
fuel for vehicles.
(3) use of non-polluting Compressed Natural Gas (CNG) only as fuel by all buses
and trucks.
(4) compulsory mixing of 20% ethyl alcohol with petrol and 20% biodiesel with
diesel.
"
108.
(1) Heterospory
(3) Free-living gametophyte
109.
The annular and spirally thickened conducting elements generally develop in the
protoxylem when the root or stem is:
(1) elongating
(2) widening
(3) differentiating
(4) maturing
" Correct choice : (4)
110.
The
111.
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112.
A health disorder that results from the deficiency of thyroxine in adults and
characterised by (i) a low metabolic rate, (ii) increase in body weight and
(iii) tendency to retain water in tissues is:
113.
114.
115.
116.
117.
(1) Porphyra
(2) Fucus
(3) Gracillaria
(4) Chara
" Correct choice : (2)
wrongly matched ?
(2) Fruit juice ! pectinase
(4) Detergents ! lipase
" Correct choice : (1)
(1) Ginkgo
(2) Marchantia
(3) Cedrus
(4) Equisetum
" Correct choice : (4)
alphabets is the correct
118.
Uric acid is the chief nitrogenous component of the excretory products of:
119.
(1) Earthworm
(2) Cockroach
(1) Transpiration
(3) Fighting against infection
(3) Frog
(4) Man
" Correct choice : (2)
(2) Guttation
(4) Protection against grazing
" Correct choice : (1)
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120.
121.
DDT residues are rapidly passed through food chain causing biomagnification
because DDT is:
122.
123.
Select the
124.
(1) Offset
(2) Rhizome
(3) Sucker
(4) Runner
" Correct choice : (3)
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126.
correct
The
sequence of spermatogenetic stages leading to the formation of
sperms in a mature human testis is:
127.
128.
129.
(1) Nausea
(2) Cough
(3) Headache
(4) Allergy
" Correct choice : (4)
(1) Forests
(2) Livestock
(4) Grasslands
" Correct choice : (1)
Which one of the following is the most likely root cause why menstruation is not
taking place in regularly cycling human female ?
130.
131.
Palisade parenchyma is
132.
absent in leaves of :
(2) Soybean
(3) Gram
(4) Sorghum
" Correct choice : (4)
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133.
correct
Items
Group
135.
Sol:
"
(2) Irradiation
(4) Tissue culture
(Biston betularia)
(1) appearance of the darker coloured individuals due to very poor sunlight
(2) protective mimicry
(3) inheritance of darker colour character acquired due to the darker environment
(4) natural selection whereby the darker forms were selected
This is a phenomenon of industrial melanism. The moths rested during day time
when their predators (birds) are active. During industrial revolution, the
surrounding areas were covered with soot and hence dark forms got camouflaged.
This offered protection to dark forms when coal was used. Later when electricity
was source of energy the environment became lighter (absence of soot) and more
of the paler forms of moth were sighted.
"
136.
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137.
Which one of the following pairs of food components in humans reaches the
stomach totally undigested?
A change in the amount of yolk and its distribution in the egg will affect:
139.
140.
141.
142.
Sol:
"
"
(3) Azolla
(4) Glomus
" Correct choice : (2)
Whose experiments cracked the DNA and discovered unequivocally that a genetic
code is a triplet?
143.
Which one of the following types of organisms occupy more than one trophic level
in a pond ecosystem ?
(1) Fish
(2) Zooplankton
(3) Frog
(4) Phytoplankton
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144.
(1) Insecticide
(2) Agent for production of dairy products
(3) Source of industrial enzyme
(4) Indicator of water pollution
"
146.
(1) coffee
(2) lily
(3) castor
(4) cotton
" Correct choice : (3)
147.
148.
(1) Mesophytes
(2) Epiphytes
(3) Hydrophytes
(4) Xerophytes
" Correct choice : (3)
(2) Duplication
(4) Insertion
"
149.
septum of 14th
and 15th
segments.
th
"
150.
The kind of tissue that forms the supportive structure in our pinna (external ears)
is also found in:
(1) nails
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(4) vertebrae
" Correct choice : (3)
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151.
(3)
Sol:
(2)
(4)
152.
Sol:
2B
(2)
(3)
(4)
PO 34 B (P = + 5)
SO 24 B (S = + 6)
Cr 2 O 27 B (Cr = + 6)
! Correct choice : (4)
153.
Lithium metal crystallises in a body centred cubic crystal. If the length of the side
of the unit cell of lithium is 351 pm, the atomic radius of the lithium will be:
151.8 pm
75.5 pm
300.5 pm
240.8 pm
(1)
Sol:
(2)
(3)
(4)
a 3=4r
r = a 3 = 351 1.732 = 151.98 pm
4
4
! Correct choice : (1)
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154.
(3)
(4)
Sol:
RX + Mg $% RMgX
RX + KOH $% ROH + KX
155.
Sol:
In the case of alkali metals, the covalent character decreases in the order:
MF > MCl > MBr > MI
MF > MCl > MI > MBr
MI > MBr > MCl > MF
MCl > MI > MBr > MF
MI > MBr > MCl > MF. As the size of the anion decreases covalency decreases
(1)
(2)
(3)
(4)
Which one of the elements with the following outer orbital configurations may
exhibit the largest number of oxidation states?
(1)
Sol:
3d54s1
(2)
3d54s2
(3)
3d24s2
(4)
3d34s2
The configuration 3d5 4s2 can have various oxidation states upto + 7.
! Correct choice : (2)
157.
Sol:
(2)
(3)
(4)
Given:
(i) Cu2+ + 2e" $% Cu, Eo = 0.337 V
(ii) Cu2+ + e" $% Cu+, Eo = 0.153 V
Electrode potential, Eo for the reaction, Cu+ + e" $% Cu, will be:
0.90 V
0.30 V
0.38 V
0.52 V
(1)
(2)
(3)
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(4)
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Sol:
Cu2+ + 2e" $% Cu; &Go = " nEo F = " 2 ' F ' 0.337 = " 0.674 F
Cu+ $% Cu2+ + e" ; &Go = " nEo F = " 1 ' F ' " 0.153 = 0.153 F
Cu+ + e" $% Cu ;
&G
159.
(3)
Sol:
d H2
would be:
dt
(2)
(4)
3
2
d NH 3
= 2 ' 10"4 mol L"1 s"1 , the
dt
160.
(1)
(2)
(3)
CH3CH2OH
(4)
Sol:
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161.
The energy absorbed by each molecule (A2) of a substance is 4.4 ' 10"19 J and
bond energy per molecule is 4.0 ' 10"19 J. The kinetic energy of the molecule per
atom will be:
(1)
(3)
Sol:
(2)
B 19
K.E per atom = 4.4 10
(4)
Amongst the elements with following electronic configurations, which one of them
may have the highest ionization energy?
(1)
(3)
Sol:
Ne [3s23p2]
Ne [3s23p1]
(2)
(4)
Ar [3d104s24p3 ]
Ne [3s23p3]
Smallest atom having half filled p-sub shell has highest I0 value
! Correct choice : (4)
163.
In the reaction
BrO 3B aq A 5 Br Baq A 6H A % 3 Br 2 l A 3 H2 O l . The rate of appearance of
bromine (Br2) is related to rate of disappearance of bromide ions as following:
(1)
B
d Br 2
= B 5 d Br
dt
3 dt
(2)
d Br 2 5 d Br B
=
dt
3 dt
(3)
d Br 2 3 d Br B
=
dt
5 dt
(4)
B
d Br 2
= B 3 d Br
dt
5 dt
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Sol:
B
1 d Br 2 = B 1 d Br
3 dt
5 dt
B
d Br 2
3 d Br
=B
dt
5 dt
Sol:
(2)
&T
kf
(3)
(4)
0.00732 = 2
1.86 0.002
! Correct choice : (4)
165.
(2)
(3)
(4)
(2)
not
(4)
The segment of DNA which acts as the instrumental manual for the synthesis of
the protein is:
ribose
gene
nucleoside
nucleotide
(1)
(2)
(3)
(4)
Sol:
(2)
(3)
(4)
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169.
Half life period of a first-order reaction is 1386 seconds. The specific rate constant
of the reaction is:
(1)
(3)
Sol:
(2)
(4)
170.
(2)
(3)
(4)
Al2O3 is reduced by electrolysis at low potentials and high currents. If 4.0 ' 104 amperes
of current is passed through molten Al2O3 for 6 hours, what mass of aluminium is
produced? (Assume 100% current efficiency. At. mass of Al = 27 g mol"1)
(1)
Sol:
(2)
(3)
(4)
172.
Chlorobenzene
(2)
Benzylchloride
(3)
Xylene
(4)
Toluene
Sol:
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173.
(1)
(2)
(3)
(4)
Sol:
The dissociation constants for acetic acid and HCN at 25)C are 1.5 ' 10"5 and
4.5 ' 10"10 respectively. The equilibrium constant for the equilibrium
CN" + CH3COOH
(1)
Sol:
(3)
(4)
CH3COOH
HCN; 1
Ka
H+ + CN"
! Ka for CN
"
1
4.5 10B 10
+ CH3COOH
CH3COO" + HCN is
1.5 10B 5 = 1
4.5 10B 10 3
175.
Sol:
Propionic acid with Br2|P yields a dibromo product. Its structure would be:
(1)
(2)
(3)
(4)
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176.
The values of &H and &S for the reaction, C(graphite) + CO2 (g) $% 2CO(g) are
170 kJ and 170 JK"1, respectively. This reaction will be spontaneous at
910 K
1110 K
510 K
710 K
&G = &H " T & S
(1)
Sol:
(2)
(3)
(4)
Copper crystallises in a face-centred cubic lattice with a unit cell length of 361 pm.
What is the radius of copper atom in pm?
157
181
108
128
(1)
Sol:
a 2=4r
r = a 1.414
4
(2)
(3)
(4)
178.
Sol:
(1)
(2)
(3)
(4)
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179.
2 HCOOH
(3)
(2)
(4)
2 CO2
Sol:
Sol:
According to MO theory which of the following lists ranks the nitrogen species in
terms of increasing bond order?
(1)
(2)
(3)
(4)
Bond order N2 = 3
N2B = 2.5
N22 B = 2.0
! Correct choice : (1)
181.
Sol:
(2)
TiF26 B and Cu 2 Cl 2
(3)
(4)
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182.
(1)
Sol:
(3)
(4)
(CH3)3 B
The IUPAC name of the compound having the formula CH , C " CH = CH2 is:
1-butyn-3-ene
but-1-yne-3-ene
1-butene-3-yne
3-butene-1-yne
(1)
(2)
(3)
(4)
(1)
(2)
(3)
(4)
Sol:
(3)
[CO (en)3]3+
does not
(4)
186.
(2)
(3)
(4)
Terylene
Nylon 66
[NH(CH2)6 NH CO (CH2)4 " CO " ]2
Teflon
(CF2 " CF2 ")n
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not
correctly
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Sol:
Correct representation is
! Correct choice : (1)
187.
Sol:
(2)
(3)
(4)
10"
'
at 298 K.
(2)
Benzoic acid
(3)
Benzene
(4)
Toluene
Sol:
M
The equivalent conductance of 32 solution of a weak monobasic acid is 8.0 mhos cm2
and at infinite dilution is 400 mhos cm2. The dissociation constant of this acid is:
1.25 ' 10"(6
6.25 ' 10"(4
1.25 ' 10"(4
1.25 ' 10"(5
8.0 = 2 ' 10" 2
* =
=
400
D
(1)
Sol:
2
Ka = C*
1B*
(2)
C* 2 = 1
32
(3)
10
(4)
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190.
(1)
(2)
(3)
(4)
191.
Sol:
will be:
"1
"1
" 243.6 kJ mol
" 120.0 kJ mol
553.0 kJ mol" 1
1523.6 kJ mol" 1
[(4 ' 410.5) + 606.1 + 431.3)] " [(6 ' 410.5) + 336.49)] = " 120.0 kJ mol" 1
(1)
(2)
(3)
(4)
192.
Sol:
(2)
(3)
(4)
193.
(2)
(3)
(4)
F2
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194.
In which of the following molecules / ions BF3, NO B , NH B and H2O, the central
2
2
2
atom is sp hybridized?
(1)
NH2B and H 2 O
(2)
NO 2B and H 2 O
(3)
BF3 and NO 2B
(4)
NO 2B and NH 2B
! Correct choice : (3)
195.
Sol:
(2)
(3)
(4)
Sol:
(1)
(2)
(3)
(4)
197.
What is the [OH"] in the final solution prepared by mixing 20.0 mL of 0.050 M
HCl with 30.0 mL of 0.10 M Ba(OH)2?
0.40 M
0.0050 M
0.12 M
No. of m. equivalent of HCl = 20 ' 0.05 = 1.0
(1)
Sol:
(2)
(3)
(4)
0.10 M
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198.
(1)
(2)
(3)
(4)
199.
(b)
Sol:
200.
(1)
(2)
(3)
(4)
(2)
(3)
insulin
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