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Fugacity Calculation Example
Fugacity Calculation Example
Fugacity Calculation Example
Estimate the fugacity of gaseous propane at 2.4 MPa. and 344 K using the following p-v-T
data for propane at 160F.
Pressure
Specific
Volume
MN/m2
m3/kg
---
0.1724
0.3447
0.3691
0.181
Ideal
Specific
Volume
m3/kg
--0.3776
0.1888
x 103
m3/kg
7.88
1.0342
0.05512
0.06293
7.81
1.2066
0.04598
0.05394
7.96
1.379
0.03903
0.0472
8.17
9.14
m 3 MN
x 2 x106 = 19248.5 J/kg
kg m
ln(f/p) = -1/RT dp = -19248.5/(8314 x 344.4) x 44 = -0.2956
[44 is RMM of propane needed since R is in kJ/mol/K]
f/p = 0.7441
f = 0.7441 x 2.4 = 1.7856 MPa
m3/kg
MN/m2
4.25
0.1724
0.7327
8.15
0.1723
1.4043
7.84
0.3448
2.7032
7.855
0.3447
2.7076
7.885
0.1724
1.3593
8.065
0.1724
1.3904
8.655
1.0342
8.9510
19.2485
7.8
0.0944
0.02697
Area =
Ave. x
p x 103
8.5
0.08652
0.01783
0.6895
2.4
Average
x 103