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2005 U. S. National Chemistry Olympiad: Local Section Exam
2005 U. S. National Chemistry Olympiad: Local Section Exam
2005 U. S. National Chemistry Olympiad: Local Section Exam
NATIONAL
CHEMISTRY OLYMPIAD
LOCAL SECTION EXAM
Prepared by the American Chemical Society Olympiad Examinations Task Force
ampere
atmosphere
atomic mass unit
atomic molar mass
Avogadro constant
Celsius temperature
centi prefix
coulomb
electromotive force
energy of activation
enthalpy
entropy
equilibrium constant
CONSTANTS
m
M
M
mol
h
P
k
Rf
s
T
t
V
EQUATIONS
E = Eo
1
1A
1
H
1.008
3
Li
RT
ln Q
nF
k E 1 1
ln 2 = a
k1 R T1 T2
H 1
ln K =
+ constant
R T
13
3A
5
B
14
4A
6
C
15
5A
7
N
16
6A
8
O
17
7A
9
F
18
8A
2
He
4.003
10
Ne
6.941
9.012
10.81
12.01
14.01
16.00
19.00
20.18
11
Na
12
Mg
13
Al
14
Si
15
P
16
S
17
Cl
18
Ar
22.99
24.31
19
K
20
Ca
3
3B
21
Sc
4
4B
22
Ti
5
5B
23
V
6
6B
24
Cr
7
7B
25
Mn
8
8B
26
Fe
9
8B
27
Co
10
8B
28
Ni
11
1B
29
Cu
12
2B
30
Zn
58.69
63.55
65.39
69.72
72.61
74.92
78.96
79.90
83.80
46
Pd
47
Ag
48
Cd
49
In
50
Sn
51
Sb
52
Te
53
I
54
Xe
26.98
28.09
30.97
32.07
35.45
39.95
31
Ga
32
Ge
33
As
34
Se
35
Br
36
Kr
39.10
40.08
44.96
47.88
50.94
52.00
54.94
55.85
58.93
37
Rb
38
Sr
39
Y
40
Zr
41
Nb
42
Mo
43
Tc
(98)
44
Ru
101.1
45
Rh
102.9
106.4
107.9
112.4
114.8
118.7
121.8
127.6
126.9
131.3
75
Re
76
Os
77
Ir
78
Pt
79
Au
80
Hg
81
Tl
82
Pb
83
Bi
84
Po
85
At
86
Rn
85.47
87.62
88.91
91.22
92.91
95.94
55
Cs
56
Ba
57
La
72
Hf
73
Ta
74
W
132.9
137.3
138.9
178.5
180.9
183.8
186.2
190.2
192.2
195.1
197.0
200.6
87
Fr
88
Ra
89
Ac
104
Rf
105
Db
106
Sg
107
Bh
108
Hs
109
Mt
110
111
112
114
(269)
(272)
(277)
(2??)
(223)
(226)
(227)
58
Ce
59
Pr
(262)
60
Nd
(263)
61
Pm
(262)
62
Sm
(265)
63
Eu
(266)
64
Gd
65
Tb
66
Dy
67
Ho
173.0
175.0
101
Md
102
No
103
Lr
144.2
(145)
150.4
152.0
157.3
158.9
162.5
164.9
167.3
91
Pa
92
U
93
Np
94
Pu
95
Am
96
Cm
97
Bk
98
Cf
99
Es
100
Fm
(237)
(244)
(243)
(247)
(247)
(251)
(252)
(257)
(258)
70
Yb
(209)
168.9
140.9
238.0
209.0
69
Tm
90
Th
231.0
207.2
68
Er
140.1
232.0
Page 2
(261)
204.4
(259)
(210)
(222)
71
Lu
(262)
Not for use as a USNCO Local Section Exam after March 28, 2005
DIRECTIONS
When you have selected your answer to each question, blacken the corresponding space on the answer sheet using a soft, #2
pencil. Make a heavy, full mark, but no stray marks. If you decide to change an answer, erase the unwanted mark very carefully.
There is only one correct answer to each question. Any questions for which more than one response has been blackened will not
be counted.
Your score is based solely on the number of questions you answer correctly. It is to your advantage to answer every question.
(B)
(C)
(D)
(B) at 112 C
(A) 4 molecules
(B) 5 molecules
(C) 6 molecules
(D) 8 molecules
(B) 35.5
(C) 55.8
(D) 71.0
Not for use as a USNCO Local Section Exam after March 28, 2005
Page 3
(B) 30.0%
(C) 50.0 %
(D) 70.0 %
(B) 5.04
(C) 15.2
(D) 26.2
(B) 33.6 mL
(C) 37.2 mL
(D) 67.1 mL
(A) He = H 2 = N 2 = CO 2
(C)
2 B 2(g)
(D) 5 B(s) +
(B) 31
(C) 54
(D) 56
(B) 485
(C) 500
(D) 515
(B) SiC.
(C) CsCl.
(D) C 10H22.
I. vapor pressure
II. surface tension
(A) I only
(B) II only
Page 4
20. C 2H6(g)
+
2 H2(g)
2 H2(g)
r B5H9(g)
r B5H9(g)
2 O2(g)
(B) 1383.7 kJ
(C) 1471.7 kJ
(D) 1559.7 kJ
(B) 24.0 C
(C) 26.5 C
(D) 53.1 C
(B) 121 kJ
(C) 484 kJ
(D) 2710 kJ
Not for use as a USNCO Local Section Exam after March 28, 2005
(A) I only
(B) II only
27. What are the units of the rate constant for a second order
reaction when the rate is expressed in mol. L-1. s-1?
(A) s-1
(B) L. mol -1
(C) L. mol -1. s-1
(B)
[OH ]
2
Rate = k [ (CH 3 ) 3 CBr ] [OH ]
(C)
K=
2[SO 2 ]
3[O 2 ]
(B)
K=
2[ ZnO][SO 2 ]
3[ ZnS][O 2 ]
(D)
K=
[SO 2 ] 2
[O 2 ] 3
K=
[ ZnO] 2 [SO 2 ] 2
[ ZnS] 2 [O 2 ] 3
(A) 1.41
(B) 2.82
(C) 5.65
(D) 11.18
(B) 3.110-2
(C) 5.310-6
(D) 3.910-7
(B) 3.010-6
(C) 6.010-6
(D) 3.810-3
Not for use as a USNCO Local Section Exam after March 28, 2005
Page 5
BaCO3
BaSO4
CaCO3
CaSO4
Ksp
2.610-9
1.110-10
4.910-9
7.110-9
(D) Br2
(B) 2/1
(C) 3/1
(D) 5/1
(B) 0.091 V
(C) 0.091 V
(D) 0.427 V
(B) II only
(B) 2, 1, 1,
(C) 3, 3, 1, 1 2
(D) 4, 3, 2,
44. How
many unpaired electrons are ina gaseous iron atom
in its ground state?
(A) 6
(B) 4
(C) 2
(D) 0
45. Evidence for the electron arrangement in atoms has been
obtained primarily from the study of
(A) isotopes.
(B) radioactivity.
(C) stoichiometry.
46. Which statement about the radii of atoms and their ions
is correct?
(A) Cations are smaller than their atoms, anions are
larger.
(B) Cations and anions are both smaller than their
atoms.
(C) Cations and anions are both larger than their atoms.
(D) Cations are larger than their atoms, anions are
smaller.
47. When the atoms; Li, Be, B, Na, are arranged in order of
increasing atomic radius which is the correct order?
(A) Li, Be, B, Na
(B)
(C)
(D) +
Page 6
(B) NCl3
(C) PCl4+
(D) SF 4
Not for use as a USNCO Local Section Exam after March 28, 2005
I.
II.
Which of the structures
represent possible resonance forms of this ion?
(A) I only
(B) II only
(B) N2, F 2, O2
(D) F 2, O2, N2
(B) C2H4
(C) C2H6
(A) 2-isopropyl-1-butene
(B) 2,3-dimethyl-2-hexene
(C) 2-methyl-3-isopropyl-1-butene
(D) 2,3,4-trimethyl-1-pentene
59. What is the
hybridization of carbon
atoms 1, 2, and 3,
respectively in the
structure?
(D) C 3H4
(A) condensed.
(B) denatured.
(C) hydrolyzed.
(D) polymerized.
END OF TEST
(B) butanone
(C) 1-chlorobutane
(B) CH3CHO
(C) CH3COOH
(D) CH3COOCH3
(B) two
(C) three
(D) four
Not for use as a USNCO Local Section Exam after March 28, 2005
Page 7
Number
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
14.
15.
16.
17.
18.
19.
20.
21.
22.
23.
24.
25.
26.
27.
28.
29.
30.
Answer
D
B
A
A
B
D
C
D
C
D
C
A
D
A
B
B
A
D
D
D
A
B
B
A
B
C
C
D
D
A
Number
31.
32.
33.
34.
35.
36.
37.
38.
39.
40.
41.
42.
43.
44.
45.
46.
47.
48.
49.
50.
51.
52.
53.
54.
55.
56.
57.
58.
59.
60.
Not for use as a USNCO Local Section Exam after March 28, 2004
Answer
B
B
B
B
C
D
C
B
D
A
A
C
C
B
D
A
D
B
D
C
A
B
D
A
D
B
C
D
D
B