Energy Balance

Compressor

25C, 1
atm

167C, 3
atm

210 mol/h
O2

210 mol/h
O2

Component - Oxygen and Nitrogen

O2 ( g ) N 2 (g)at 31 , 1 atm

Reference State:

^
H

Substance

^
H out

n out
(kJ/mol)

O2

(mol/h)
210

N2

790

^
H2

(mol/h)
210

^
H1

(kJ/mol)

^
H3
^
H4

790

H 1 H 2 is 0 since the condition at standard.

The specific enthalpy of

167

^ O P+ CpO dt
H 3=V
2

25

167

0.0245 ( 300100 ) + 29.10 103 +1.158 105 T 0.6076 108 T 2+1.311 1012 T 3 dt
25

1.158 10 T 0.6076 10 T 1.311 10

4.9+ 29.10 10 T +

+
2
3
4
3

12

4 167

25

4.9+ [ ( 4.8597+0.16150.0094+0.0003 )( 0.7275+0.00360.00003+1.28 107 ) ]

4.9+ [ 5.01210.7311 ]
9.181

kJ
mol

167

^ N P+ Cp N dt
H 4 =V
2

25

167

0.0245 ( 300100 ) + 29 103 +0.2199 105 T + 0.5723 108 T 22.871 1012 T 3 dt

25

0.2199 105 T 2 0.5723 108 T 3 2.871 1012 T 4

4.9+ 29 10 T +
+

2
3
4
3

167

25

4
5
7
4.9+ [ ( 4.843+0.0307+ 0.00895.58 10 )( 0.7275+0.00007+2.98 10 2.80 10 ) ]

4.9+ [ 4.88200.7276 ]
9.054

kJ
mol
out

^ i n i ^
H= n i H
Hi
i

210

mol
kJ
mol
kJ
9.181
+ 790
9.054
0
h
mol
h
mol

9080.67

)(

kJ
h