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Coeus - VN g3.D NG C Bao Bì Kim Lo I TXTT V I TP
Coeus - VN g3.D NG C Bao Bì Kim Lo I TXTT V I TP
Coeus - VN g3.D NG C Bao Bì Kim Lo I TXTT V I TP
H NI - 2011
Li ni u
QCVN 12-3:2011/BYT do Ban son tho Quy chun k thut
quc gia v bao b v cc vt liu tip xc trc tip vi thc
phm bin son, Cc An ton v sinh thc phm trnh duyt
v c ban hnh theo Thng t s 34/2011/TT-BYT ngy 30
thng 8 nm 2011 ca B trng B Y t.
Cadimi
Ch
Phenol
Formaldehyd
Cn kh
Nc[3]
Nc[3]
Nc[3]
Nc
250C trong 1 gi
Heptan[1] , [6]
Nc[3] , [7]
Gii hn ti a
0,2 g/ml
0,1 g/ml
0,4 g/ml
5 g/ml [8]
m tnh [8]
30 g/ml [8]
250C trong 2 gi
Pentan
Ethanol 20%
Ghi ch
[1]
Bao b, dng c kim loi dng cha ng cht bo, du n v thc phm cha cht bo.
Bao b, dng c kim loi dng cha ng ung c cn.
[3]
Bao b, dng c kim loi dng cha ng thc phm c pH ln hn 5.
[4]
Bao b, dng c kim loi dng cha ng thc phm c pH nh hn hoc bng 5.
[5]
0
0
Bao b, dng c kim loi s dng nhit ln hn 100 C iu kin ngm 95 C trong 30 pht.
[6]
Hm lng cn kh khng qu 90 g/ml trong trng hp mu l hp c ph bn trong mt
lp ph c nguyn liu chnh l cc loi du t nhin hoc cht bo v hm lng ca km oxyd trong
lp ph ln hn 3%.
[7]
S lng mt cht ha tan trong cloroform (gii hn n 30g/ml hoc t hn) c xc nh khi mt
[6]
mu c th c s dng tng t nh v s lng vt qu 30g/ml.
[8]
Khng p dng i vi cc bao b, dng c kim loi khng ph 1 lp nha tng hp tip xc trc tip
vi thc phm.
[9]
Dung dch ra gii c c c 5 ln, mc d nng trong dung dch ra gii
khng qu 25g/ml.
[2]
Ph lc
PHNG PHP TH THI NHIM
1. Chun b dung dch th:
- Ra sch mu bng nc ct, x l mu th thi nhim theo hng dn c
th sau:
i vi mu c th ng cht lng, cho dung dch ngm thi vo trong lng
mu.
i vi mu khng th cha ng cht lng, ngm mu ngp trong dung dch
ngm thi theo t l 2 ml/cm2 din tch b mt mu th.
- S dng dung dch ngm thi v iu kin ngm thi theo hng dn ti mc II.
Quy nh k thut.
2.
Xc nh hm lng ch v cadmi
2.1 Chun b dung dch chun
2.1.1 Cadmi
- Dung dch cadmi chun gc:
Cn 100 mg cadmi, ha tan trong 50 ml acid nitric 10%, c trn bp cch thy. Sau
thm acid nitric 0,1 mol/l ha tan v nh mc n 100 ml. Dung dch
chun cadmi gc ny c nng 1 mg/ml.
- Dung dch cadmi chun lm vic:
Ly chnh xc 2 ml dung dch cadmi chun gc, v thm dung dch lm dung dch
ngm thi, nh mc n 100 ml. Nng dung dch cadmi chun lm vic 0,1
g/ml.
2.1.2 Ch
- Dung dch chun ch gc:
Ha tan 159,8 mg ch (II) nitrat trong 10 ml acid nitric 10%, v thm nc ct nh
mc n 100 ml. Dung dch chun ch gc ny c nng 1 mg/ml.
- Dung dch chun ch lm vic:
Ly chnh xc 8 ml dung dch ch chun gc, thm dung dch lm dung dch ngm
thi v nh mc n 100 ml. Dung dch ch chun lm vic c nng 0,4
g/ml.
2.2 Tin hnh
Xc nh ch v cadmi trong dung dch th bng phng php quang ph hp th
nguyn t hoc quang ph pht x plasma.
3. Xc nh Arsen
3.1 Chun b dung dch chun gc:
- Chun b dung dch chun gc:
Nghin mn arsen trioxyd, sy kh trong 4 gi 105C, cn 0,10g, thm 5ml dung
dch NaOH (1 5) v ha tan. Trung ha dung dch ny bng acid sulfuric (1
20), thm 10 ml acid sulfuric d (1 20), thm nc va un si v ngui, nh
mc n 1.000 ml. Nng dung dch chun lm vic l 0,1 g /ml.
-Chun b dung dch chun lm vic :
Ly 10 ml dung dch arsen chun gc, thm 10 ml acid sulfuric (1 20), thm
nc va un si v ngui, nh mc n 1.000 ml. Nng dung dch
chun lm vic l 0.1 g /ml.
6
Ch chun b dung dch chun lm vic ngay trc khi s dng v lu tr trong mt
bnh kn.
3.2 Dung dch hp th arsen ha tan 0,5 g bc N,N diethyldithylocarbamat n
va 100ml bo qun dung dch ny trong l thy tinh mu nt nhm ch mt
3.3 Bnh phn ng
- Ly 200-300 ml dung dch th (nu s dng heptan l dung dch ngm thi, th
chuyn 200-300 ml dung dch th vo mt bnh hnh qu l, c chn khng n cn
mt vi ml, chuyn phn dch c vo mt chn bch kim, thch anh, hoc cc thy
tinh chu nhit ( gia nhit ti 1050C v cn b) sau trng bnh ct hai ln, mi
ln vi khong 5 ml heptan v gp dch ra vo dch c c. Cho bay hi trn b
cch thy n khi bc hi ht dung dch v cn li cn cng. Sy kh cn trong 2
gi 1050C, ngui trong bnh ht m, cn chn v cn xc nh khi lng cn
(s chnh lch khi lng chn v cn vi khi lng b).
- Tin hnh ng thi mu trng, trong thay th tch dung dch th bng th tch
nc ct tng ng.
- S dng cng thc sau tnh lng cn:
Cn kh (g/ml) = [(a-b) x1.000] / th tch dung dch th (ml)
Trong :
a (mg) = s chnh lch khi lng gia chn c cn v b trong th nghim vi
dung dch th.
b (mg) = s chnh lch khi lng gia chn c cn v b trong th nghim vi
mu trng
Ngoi ra, nu dng nc lm dung dch ngm thi m lng cn kh ln hn 30
g/ml th kt qu phi theo phng php th sau y:
- Thm 30 ml cloroform vo phn cn kh thu c, gia nhit, lc v sau cn
cht lng thu c sau lc trong mt chn thch anh, bch kim, hoc thy tinh chu
nhit bit khi lng. Hn na, ra cn kh va lc hai ln, s dng 10 ml
chloroform mi ln, gia nhit, lc, a cht lng c lc vo b bay hi cch thy.
Sau khi lm ngui, cn chn v cn xc nh khi lng cn (s chnh lch khi
lng chn v cn vi khi lng b). Tin hnh ng thi mu trng, trong thay
th tch dung dch th bng th tch nc ct tng ng.
- S dng cng thc sau tnh lng cht tan trong chloroform
Lng cht tan trong chloroform (g/ml) = [(a-b) x1,000] / th tch dung dch th
ban u(ml)
b (mg) = mu trng
7.
Epiclorohydrin
Thit b o
Kh mang
8.
Vinyl chlorid
8.1 Chun b dung dch vinyl chlorid chun
- Ly khong 190 ml ethanol vo bnh nh mc 200 ml, y bnh bng nt cao su
silicon v cn khi lng. Lm lnh bnh nh mc bng methanol bng kh v tim
vo 200 mg vinyl clorid c ho lng. Tim ethanol c lm lnh bng
methanol bng kh vo bnh, nh mc n 200 ml. Tip tc lm lnh bnh bng
methanol bng kh. Ly 1 ml dung dch trn, v thm ethanol c lm lnh bng
methanol bng kh, nh mc n 100 ml v bo qun trong methanol bng kh.
Dung dch thu c c nng 10 g/ ml. Ethanol (99,5) dng trong th nghim
khng c cha nhng cht c nh hng n cc cht dng trong php th.
8.2 Tin hnh
- Rt 50 l dung dch chun vinyl clorua vo bnh thy tinh c nt y c 2,5 ml
N, N dimethylacetamid, v y np ngay. Lm tng t vi mu th. Sau , un
nng bnh cha dung dch mu v bnh cha dung dch chun trong 1 gi, duy tr
nhit 90C, thnh thong lc u bnh. Tip theo, ly 0,5 ml hi trong mi bnh,
chy sc k kh theo hng dn c m t di y, sau so snh thi gian lu
ca pc trong sc k ca dung dch th v dung dch chun Vinyl chlorid.
Ct sc k
Nhit ct
10