CNG HO X HI CH NGHA VIT NAM

QCVN 4 - 15: 2010/BYT

QUY CHUN K THUT QUC GIA

V PH GIA THC PHM - CHT X L BT
National technical regulation on Food Additive Flour treatment agents

H NI - 2010

QCVN 4 - 15: 2010/BYT

Li ni u
QCVN 4-15:2010/BYT do Ban son tho quy chun k thut
quc gia v Ph gia thc phm v cht h tr ch bin bin
son, Cc An ton v sinh thc phm trnh duyt v c ban
hnh theo Thng t s 44/2010/TT-BYT ngy 22 thng 12
nm 2010 ca B trng B Y t.

QCVN 4 - 15: 2010/BYT

QUY CHUN K THUT QUC GIA

V PH GIA THC PHM - CHT X L BT
National technical regulation on Food Additive Flour treatment agents

I. QUY NH CHUNG
1. Phm vi iu chnh
Quy chun k thut quc gia (sau y gi tt l Quy chun) ny quy nh cc yu cu
k thut v qun l v cht lng, v sinh an ton i vi cc cht x l bt c s dng
vi mc ch lm ph gia thc phm.
2. i tng p dng
Quy chun ny p dng i vi:
2.1. T chc, c nhn nhp khu, xut khu, sn xut, bun bn v s dng cc
cht x l bt lm ph gia thc phm (sau y gi tt l t chc, c nhn).
2.2. C quan qun l nh nc c lin quan.
3. Gii thch t ng v ch vit tt:
3.1. Cht x l bt: l ph gia thc phm c b sung vo bt nhm ci thin
cht lng nng hoc mu cho thc phm.
3.2. JECFA monograph 1 - Vol. 4 (JECFA monographs 1 - Combined
compendium of food addiditive specifications; Joint FAO/WHO expert committee on
food additives; Volume 4 - Analytical methods, test procedures and laboratory
solutions used by and referenced in the food additive specifications; FAO, 2006): Cc
yu cu k thut i vi ph gia thc phm, Tp 4 Cc phng php phn tch, quy
trnh th nghim, dung dch th nghim c s dng (hoc tham chiu) trong yu
cu k thut i vi ph gia thc phm; JECFA bin son; FAO ban hnh nm 2006.
3.3. M s C.A.S (Chemical Abstracts Service): M s ng k ha cht ca
Hip hi Ha cht Hoa K.
3.4. TS (test solution): Dung dch thuc th.
3.5. ADI (Acceptable daily intake): Lng n vo hng ngy chp nhn c.
3.6. INS (International numbering system): H thng m s quc t v ph gia
thc phm.

QCVN 4 - 15: 2010/BYT

II. YU CU K THUT, PHNG PHP TH V LY MU
1. Yu cu k thut v phng php th i vi azodicarbonamid s dng lm
cht x l bt c quy nh ti ph lc ban hnh km theo Quy chun ny.

2. Cc yu cu k thut quy nh trong Quy chun ny c th theo JECFA

monograph 1 - Vol. 4, ngoi tr mt s php th ring c m t trong ph lc. Cc
phng php th c hng dn trong Quy chun ny khng bt buc phi p
dng, c th s dng cc phng php th khc c gi tr tng ng.

3. Ly mu theo hng dn ti Thng t 16/2009/TT-BKHCN ngy 02 thng 6

nm 2009 ca B Khoa hc v Cng ngh v hng dn kim tra nh nc v cht
lng hng ha lu thng trn th trng v cc quy nh khc ca php lut c lin
quan.
III. YU CU QUN L
1. Cng b hp quy
1.1. Cc cht x l bt phi c cng b ph hp vi cc quy nh ti Quy
chun ny.
1.2. Phng thc, trnh t, th tc cng b hp quy c thc hin theo Quy
nh v chng nhn hp chun, chng nhn hp quy v cng b hp chun, cng
b hp quy ban hnh km theo Quyt nh s 24/2007/Q-BKHCN ngy 28 thng 9
nm 2007 ca B trng B Khoa hc v Cng ngh v cc quy nh ca php lut.
2. Kim tra i vi cht x l bt
Vic kim tra cht lng, v sinh an ton i vi cc cht x l bt phi thc
hin theo cc quy nh ca php lut.
IV. TRCH NHIM CA T CHC, C NHN
1. T chc, c nhn phi cng b hp quy ph hp vi cc quy nh k
thut ti Quy chun ny, ng k bn cng b hp quy ti Cc An ton v sinh thc
phm v bo m cht lng, v sinh an ton theo ng ni dung cng b.
2. T chc, c nhn ch c nhp khu, xut khu, sn xut, bun bn v s dng
cc cht x l bt sau khi hon tt ng k bn cng b hp quy v bo m cht lng,
v sinh an ton, ghi nhn ph hp vi cc quy nh ca php lut.

QCVN 4 - 15: 2010/BYT

V. T CHC THC HIN
1. Giao Cc An ton v sinh thc phm ch tr, phi hp vi cc c quan chc
nng c lin quan hng dn trin khai v t chc vic thc hin Quy chun ny.
2. Cn c vo yu cu qun l, Cc An ton v sinh thc phm c trch nhim
kin ngh B Y t sa i, b sung Quy chun ny.
3. Trng hp hng dn ca quc t v phng php th v cc quy nh
ca php lut vin dn trong Quy chun ny c sa i, b sung hoc thay th th
p dng theo vn bn mi.

QCVN 4 - 15: 2010/BYT

Ph lc
YU CU K THUT V PHNG PHP TH
I VI AZODICARBONAMID
1. Tn khc, ch s

Azobisformamide;
INS 927a

2. nh ngha
Tn ha hc

Azodicarbonamid, diamid ca acid azodicarboxylic

M s C.A.S.

123-77-3

Cng thc ha hc

C2H4N4O2

Cng thc cu to

Khi lng phn t

116,08

3. Cm quan

Bt tinh th mu vng n cam, khng mi

4. Chc nng

Cht x l bt

5. Yu cu k thut
5.1. nh tnh
tan

Khng tan trong nc, khng tan trong ethanol; t tan trong
dimethyl sulfoxid

nng chy

Phn hu hon ton nhit ln hn 1800C

Oxy ho
CO2

Phi c phn ng oxy ha c trng (gii phng iod t dung

dch KI trong mi trng acid H2SO4 10 %)
Phi c phn ng c trng ca carbon dioxyd.

5.2. tinh khit

Gim khi lng khi
sy kh

Khng c qu 0,5% (nhit sy 500C trong 2 gi, p sut

chn khng).

QCVN 4 - 15: 2010/BYT

pH

Khng c nh hn 5,0 (to hn dch theo t l 1 : 50 bng

cch cho 2 g mu vo 100 ml nc v khuy mnh bng my
khuy trong 5 pht).

Tro sulfat

Khng c qu 0,15% (Ly 1,5 g mu, th theo phng

php I)

Ch

Khng c qu 2,0 mg/kg.

5.3. Hm lng

Khng c nh hn 98,6% ; hm lng nitrogen tnh theo

cht kh khng c nh hn 47,2% v khng c qu
48,7%

6. Phng php th
6.1. nh tnh
CO2

un nng 10 mg mu trong mt chn s. Dng a thu tinh

ly mt git dung dch Ba(OH)2 h ln trn mu th, git thuc
th tr nn c trng.

6.2. tinh khit

Ch

- Th theo JECFA monograph 1 - Vol.4.

- Xc nh bng k thut quang ph hp th nguyn t thch
hp cho hm lng quy nh. La chn c mu th v
phng php chun b mu da trn nguyn tc ca phng
php m t trong JECFA monograph 1 - Vol.4 phn cc
phng php phn tch cng c.

6.3. nh lng
nh lng azodicarbonamid bng phng php chun :
Cn chnh xc 225 mg mu (trc c sy kh trong
t sy chn khng nhit 500C trong 2 gi) cho vo bnh
tam gic thu tinh ti mu c nt y dung tch 250 ml. Thm
vo 23 ml dimethyl sulfoxid, ra hon ton mu xung pha
di bng dung mi, y np bnh v trng ming bnh bng 2
ml dung mi. Thnh thong lc cho u dung dch sau ni
lng nt y phn dung dch dnh trn chy vo trong
bnh v ra mu c ho tan trong dung dch. Thm 5 g
KI v 15 ml nc, ngay lp tc dng pipet cho 10 ml HCl 0,5
N vo trong bnh v y nt bnh tht nhanh. Lc u cho n
khi KI c ho tan v yn t 20 25 pht trong iu kin
khng c nh sng. Chun iod c gii phng bng dung
dch natri thiosulfat 0,1N cho n khi mt mu vng.
tip vi natri thiosulfat nu c mu vng xut hin trong 15
pht. Thc hin xc nh i vi mu trng vi dung dch c
cha 25 ml dimethyl sulfoxid, 5 g KI, 15 ml nc v 5 ml HCl
0,5N v hiu chnh nu cn thit. Mi ml dung dch Na2S2O3
0,1N tng ng vi 5,804 mg C2H4N4O2.
nh lng nitrogen bng phng php Kjeldahl:
Cn chnh xc 50 mg mu (trc c sy kh trong t
sy chn khng nhit 500C trong thi gian 2 gi) cho vo
7

QCVN 4 - 15: 2010/BYT

bnh Kjeldahl th tch 100 ml, thm vo 3 ml acid hydriodic
(nng ti thiu 57%), un trong thi gian 75 pht v b
sung thm nc nu cn duy tr ng th tch ban u.
Tng nhit giai on cui ca qu trnh un v tip tc un
cho n khi th tch trong bnh gim cn mt na. Lm ngui
nhit phng, thm vo 1,5 g K2SO4 v 3 ml nc. Thm
cn thn 4,5 ml H2SO4 m c v gia nhit cho n khi iod
khng bay ra na. ngui v ra thnh bnh bng nc, gia
nhit n khi ho than v li lm ngui nhit phng.
Thm 40 mg thu ngn (II) oxyd vo bnh cha than v gia
nhit cho n khi mu ca dung dch tr thnh mu vng nht,
lm ngui, ra thnh bnh bng mt vi ml nc v un hn
hp trong thi gian 3 gi. Lm ngui v thm vo 20 ml nc
khng cha amoniac, 16 ml dung dch NaOH 50%, 5 ml dung
dch Na2S2O3 44%. Lp bnh vi b phn chng ct v ct,
hng dch ct vo 10 ml dung dch acid boric 4%. Thm vi
git thuc th methyl - xanh methylen TS v chun
bng acid H2SO4 0,05N. Thc hin xc nh i vi mu
trng. Mi ml acid H2SO4 0,05N tng ng vi 0,7004 mg
nitrogen.