Estimation of HSP from an Equation of State

C7

Appendix

Conceptional Diagram of Computation of HSP from Equation of State

Figure C7-1 Conceptional Diagram of Computation of HSP from Equation of State

Panayiotou can use the EOS to calculate the three

solubility parameters for any one of a considerable
variety of solvents. Their dening equations are known
from Equations 2.5 and 2.6. Panayiotou also repeated
the work with pressure-volume-temperature (PVT) data
for high molecular weight polymers.

C. CALCULATED OUTCOMES VS.

ACCEPTED HSP VALUES
As with Figures C6-1 through C6-4 in Appendix C6, for
calculation of the three HSP values with correlations and the
Pythagorean theorem, corresponding gures can be drawn
for calculation of the three HSP via Panayiotous equation of
state method. They show a considerably improved reproduction of the experimentally derived (mostly) values from
the reference of Chapter 2, Endnote I, Dr. Hansen's published database.
The Hildebrand (TOTAL) Solubility Parameter in Figure
C7-2 is calculated from Equation C7-1 using Panayiotous

Figure C7-2 Prediction of the Hildebrand Solubility

Parameter

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