Appendix

632
Table C8-5 Primary Groups used in the Stefanis Panayiotou Group Contribution Method

d Polar

d Polar
LOW

dH
Bonding

Molar Volume cc/mole

Primary Group

MPa

Example Solvent

0.9328

1.6444

0.7107

0.7458

0.2990

24.2690

Propane

CH2

0.0089

0.3141

0.1361

0.3877

0.1161

16.6355

Butane

CH<

0.5982

0.6051

0.6477

0.2064

0.1386

9.3251

Isobutane, or IPA, or Chloroform

>C<

1.2911

2.0249

0.0113

2.6466

Neopentane, or Chloroform, or
Carbon tetrachloride

>CC<

0.3682

0.9957

1.9773

0.1212

9.4023

2,3-Dimethyl-2-butene

CHC<

0.4993

1.1018

1.2761

1.7171

0.0307

15.5740

2-Methyl-2-butene

CHCH

0.2242

0.5037

0.1503

0.1253

0.4819

25.2114

cis-2-Butene

CH2C<

0.3234

0.9052

0.6956

0.7191

0.1115

26.5972

Isobutene

CH2CC<

0.0325

1.2654

1.7087

38.0743

3-Methyl-1,2-butadiene

CH2CCH

1.3653

0.2453

0.7545

44.2955

1,2-Butadiene

CH2CH

0.9483

2.0170

0.2511

1.1783

1.3552

35.4382

Propylene

CF3

0.0921

2.1381

1.2997

0.0887

39.6435

Peruorohexane

CF2

0.9628

27.5403

Peruoromethylcyclohexane

0.3079

0.6557

12.1491

2-Fluoropropane

0.4895

33.3180

n-Butyl chloride

24.4583

t-Butyl chloride

>CF
F (except as above)

CH2Cl

0.3595

0.5013

0.4498

Peruoromethylcyclohexane

>CCl

2.8308

1.8196

0.1473

>CCl2

0.5034

0.1035

1.3220

>CHCl

0.4951

2.6796

1.3563

0.1300

27.0238

Isopropyl chloride

CHCl2

1.2342

1.6255

3.0669

0.5254

45.9340

1,1-Dichloropropane

CCl3

1.1060

2.5679

59.5423

Benzotrichloride, or Chloroform

Pentachlorocyclopropane

Estimation of HSP from Group Contribution Methods

CH3

d H Bonding
LOW

C8

d Disperse