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  • Final Thermo Code

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    This MATLAB code analyzes thermodynamic properties for a two-component system. It calculates activity coefficients and Gibbs energy for given mole fractions and pressures at 79.8°C. Curve fitting is used to predict values at 90°C. Graphs are generated comparing measured and predicted pressure-composition data at both temperatures.

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    final thermo code

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    This MATLAB code analyzes thermodynamic properties for a two-component system. It calculates activity coefficients and Gibbs energy for given mole fractions and pressures at 79.8°C. Curve fitting is used to predict values at 90°C. Graphs are generated comparing measured and predicted pressure-composition data at both temperatures.

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    © All Rights Reserved
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    31 views2 pages

    Final Thermo Code

    Uploaded by

    api-302257258
    This MATLAB code analyzes thermodynamic properties for a two-component system. It calculates activity coefficients and Gibbs energy for given mole fractions and pressures at 79.8°C. Curve fitting is used to predict values at 90°C. Graphs are generated comparing measured and predicted pressure-composition data at both temperatures.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Flag for inappropriate content
    Download as docx, pdf, or txt
    of 2

    Thermodynamics MATLAB Code

    clear;
    clc;
    T=79.80;
    X1=[0 0.0856 0.1558 0.3012 0.4114 0.4202 0.4287 0.5782 0.5556 0.7390
    0.8201 1]';
    Y1=[0 0.3542 0.3765 0.4060 0.4201 0.4234 0.4287 0.4376 0.4642 0.5649
    0.6428 1]';
    X2=(1-X1);
    Y2=(1-Y1);
    A1=8.37895;
    A2=8.07131;
    B1=1788.020;
    B2=1730.630;
    C1=227.438;
    C2=233.426;
    Psat1=(10^(A1-(B1/(T+C1))));
    Psat2=(10^(A2-(B2/(T+C2))));
    P=[352.6 530 539.6 547 548.1 548.5 549.7 545.7 541.7 506.6 479.2 374.6]';
    %calculating gammas and gibbs energy at each pressure and concentration
    for i=[1:12]
    gamma1(i)=((Y1(i)*P(i))/(X1(i)*Psat1));
    gamma2(i)=((Y2(i)*P(i))/(X2(i)*Psat2));
    Gibbs(i)=(X1(i)*log(gamma1(i))+X2(i)*log(gamma2(i)));
    %Two Parameter values from curve fitting
    A21=1.032;
    A12=2.375;
    end
    T2=90;
    newPsat1=(10^(A1-(B1/(T2+C1))));
    newPsat2=(10^(A2-(B2/(T2+C2))));
    newX1=[0:.01:1]';
    newX2=1-newX1;
    l=length(newX1);
    %calculating new gammas and predicted pressures at each respective mol frac
    for j=1:l
    new_gamma1(j)=exp((newX2(j)*newX2(j)*(A12+((2*(A21-A12))*newX1(j)))));

    new_gamma2(j)=exp((newX1(j)*newX1(j)*(A21+((2*(A12-A21))*newX2(j)))));
    PredP1(j)=((new_gamma1(j)*newX1(j)*Psat1)+
    (new_gamma2(j)*newX2(j)*Psat2));
    PredP2(j)=((new_gamma1(j)*newX1(j)*newPsat1)+
    (new_gamma2(j)*newX2(j)*newPsat2));
    newY1(j)=((new_gamma1(j)*newX1(j)*Psat1)/PredP1(j));
    newY12(j)=((new_gamma1(j)*newX1(j)*newPsat1)/PredP2(j));
    end
    %graphing predicted pxy diagram at 90 degC
    plot(newX1,PredP2,'b')
    hold on
    plot(newY12,PredP2,'c')
    ylabel('Pressure [mm Hg]')
    xlabel('X1 Y1 @90 degC')
    legend('Liquid', 'Vapor')
    title('P-XY at T=90 degC')
    %graphing pxy diagram at 79.8 degC
    figure
    plot(X1, P, '*', Y1, P, '*', newX1, PredP1, 'r', newY1, PredP1, 'g')
    ylabel('Pressure [mm Hg]')
    xlabel('X1 Y1 @79.8 degC')
    legend('Liquid', 'Vapor', 'Predicted Liquid', 'Predicted Vapor')
    title('P-XY at T=79.80 degC')

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