RECEIPT OF CHECK

0103832

12/5/2008

Date o~ Check

!:

12/3/2008

Check Number ~-:----~~--------

Amount Received $2,332.50

RECEIP1i GENERATED BY:

Sunshine McManus

COMMENTS modification

Media: AIR QUALITYI

Rcporc Dltelfime I I 12I5f2008 2:2647 PM '

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MAIN F~LE

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OIL USA, INC.

MERAUX REFINERY P. O. BOX 100 MERAUX LA 70075-0100

iUOO DEC

PrJ 1 06

·.i

LDE{J F'<ECEI~T

MURPHY

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HAND-DELIVERED

December 5, 2008

,

original to IDa

~8Py to iLi(o"tttll J~:u .:~

, f fl(tg;', '1

Ms. Cheryl Nolan

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Assistant Secretary

Office of Envifbnmental Services

Louisiana Depsrtment of Environmental Quality P.O. Box 431311

Baton Rouge, eA 70821-4313

RE: MurpJl Oil USA, Inc. -Meraux Refinery Merau~ SL Bernard Parish, Louisiana

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Part 70 Operatbig Permit Minor Modification Application

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Title ~,Pe,.mit No.: 2500-00001-V3

Agen£J! Interest No.: 1238 v' '

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Dear Ms. Nolan: '

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Murphy Oil USA, Inc. (MOUSA) is submitting this minor modification application to the Title

VlPart 70 Perihit No. 2S00-00001-V3, issued May 8, 2008. MOUA is submitting this minor modification application to reinstate Tank 80-9 and to replace three tanks by constructing and operating Tanks 1-3A, 80-SA, and 80-IOA at the Meraux Refinery, As MOUSA is not requesting an increase in CAP emission limits in this application, the application qualifies to receive minor lhodification procedures. 1

MOUSA is Jldertaking this project to replace previously existing tanks and to address postKatrina storag~ capacity shortages. The use of domed internal floating roofs on Tanks 80-9 and 80-IOA, as well as an internal floating roof on Tank 1-3A, will result in significant reductions in VOC emission~ versus the previously existing tanks. The construction of Tank 80-SA will enable tank farm changes to accommodate the future BenFree Unit, which must be built and operational by January, 2010 to satisfy the Mobile Source Air Toxics rule. The tanks will be constructed within the current boundaries of the Meraux Refinery and will be located at sites of previously existing tanks.!

.... Tank 1-3~ will replace Tank 1-3 at its existing location. (Tank 1-3 was built prior to 1958.) Tank 1.3A! will have a capacity of 1,000 barrels and will be in slop oil return service for oily waters recbvered from the onsite Wastewater Treatment Plant. Tank 1-3A will be equipped with an intl~rnal floating roof, whereas Tank 1-3 was a fixed roof tank. ,

LDEQ

1 Per paone conversation between Bryan Johnston (LDEQ) and Cheri Kwast on November 6, 2008, minor mo~ificalion procedures are appropriate if tanks are being added to an emissions CAP if the emissions CAP ~oes not increase. Public notice is not required for a minor modification, which includes an addition ofa ~our.~e 10 an emissions CM~J1jJmns do not change.

(504) 271-4141 USA. FAX (504) 278-5201

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Ms. Cheryl Nolan- Page 2

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December 5, 2008

... Tank 80·5A will replace Tank 80·5 at its previous location. (Tank 80·5 was demolished in 2001.) Ta~ 80·5A will have a capacity of 80,000 barrels and will be in heavy oil service.

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... Tank 80-9 is an existing tank that will be restored to the permit. Tank 80·9A has a capacity

of 80,000 ~rrels and will be permitted for gasoline, middle distillate, and naphtha service. MOUSA Jill' replace the external floating roof with a domed internal floating roof, which will reduc~!emissions. MOUSA allowed the tank to be removed from Title V Permit No. 2500.000011. V2, as the strategic plan at that time was to remove the tank.

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... Tank 80-10A will replace Tank 80·10 at its previous location. (Tank 80-10 was demolished

in 2006.).iiTank 80·10A will have a capacity of 80,000 barrels and will be permitted for gasoline, middle distillate, sour water, naphtha, and heavy oil service. Tank 80-1 OA will have a doJed internal floating roof.

MOUSA plans Ito begin construction of the new tanks immediately upon approval and, therefore, respectfully requests that the LDEQ process this application in the most expeditious manner possible. Purkuant to LAC 33:I.Chapter 18, MOUSA is submitting a certified "Request for Expedited Perkt Processing" form with this application. Pursuant to Louisiana Administrative

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Code (LAC) 33:III.223, Fee Number 0720, the applicable permit processing fee in the amount of

$2,332.50 is al~o being provided with this submittal. MOUSA has authorized the expenditure of the funds necJ!ssary to cover the additional cost incurred by LDEQ in association with this

d· d I' •

expe ite pernut request.

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Please contact Mr. Matthew Dobbins with MOUSA at (504) 271-4141 if you have any questions

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or comments regar mg t IS app ication.

Attachments

Refinery Manager Meraux Refinery

Sincerely,

MURPHY OIL USA, INC.

cc: Mr. Syed Quadri - LDEQ

I,

Mr. Jeff Robinson - EPA

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Ms. Cheryl Nolan - Page 3

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December 5,2008

Title V Permit Minor Modification Application

bee: Mr. Kent Veron - MOUSA Mr. Mfttt Dobbins - MOUSA

Ms. V~lerie Barth - Trinity Consultants

G;IAIRITITLE ¥\PERMIT APPLICATIONSIPERMIT V4\08120S.DEQ LETTER..DOC

)

.~

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STATE OF LOUISIANA

DE~ARTMENT OF ENVIRONMENTAL QUALITY

Office of Environmental Services' Environmental Assistance Division

Post!Office Box 4313 • Baton Rouge, LA 70821-4313 .

Custdmer Service: 225-219-LDEQ (5337) or Toll Free 1-866-896-LDEQ (5337)

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REQUEST FOR EXPEDITED PERMIT PROCESSING

This form is to bellsubmitted when an applicant requests consideration for expedited processing of permits, mocltications. licenses, registrations, or variances in accordance with LAC 33:I.Chapter 18. Submission of this form shall in no way constitute approval of the expedited permit request. The Office will notify the applicant in writing of the decision to expedite processing of the requested permit application. ALL n·J'FORMATION MUST BE PROVIDED. Please submit one form for each activity for which expeditf;!'d processing is requested.

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;~-.; .. : ..... ': ,',' ... ,' . ·jlL:~:· · .. ~<-;:;~~cr"~9:N}I-- F *;~!LiTvt~f.8~~~1[.IQN::.~~~:,:~:::~:::: '::,;~ .. :.' :-.;:'.)'. ··::::·~·.:.'n~'·;~!;··.;,:,~:~

Agepc}Arii~rEls't (AI)~#' :11238 ~;p.er~i~ ~:(ii'pe~~{~~4L . j~:!~.;:.~;; 2S00-00001-V3

:" ;',: X Ai(:' lI' \.': S~I)~vVast~:::',<~<· ;-;" ;N'~vV.Facllit\t{· .'. ~;'y~,' x~O·d,i~,e9iF~9.U!tY,

,t:{···, :.,Water 1[,: :.:~ :Ha~ardous·~\.yaste. }Typeof /Gener~L~e-rmit·.:·:) (:".:' :., _.Vi:irianb~;ri~;~p·>::);:

~r.JIedia . . .. "

;~)' ··'Other: 'IV:::~;ermlt ~·Lice!1se.:,::: ..... :~~:U ~ .. :, . Registt#.!'iqX,··(l\;.:

. 'Ii . ", ' ,''-:: '. .. Ren'~V;;ai w/~o~mcation.·:.. ·\:.\t,:·: ... ::.':"'>.:

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Matl_Dobbins@murphyoilcorp.com

" r , ~.~ :.

Meraux Refinery
Street P.O. Box 100
Cf~y Meraux I State I LA
Name Matt Dobbins
Phone .. ( S04 ) 271-4141
Cell Phone. ( 504) 278-5268 Mailing Address

Zlp .. ::1 70075

Technical Contact Avaitable

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After Normal Work Hours

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Fax

( 504) 278-5201

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~ .... ~

SECTION II - EXPEDITED PER~IT INFORMATION

~. ' .. , ".

1, How many new ~ermanentjobs will result from this permit aCtion?

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.2. Date requested f8r final permit decision I January 13, 2009

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X Yes' :'No·

Yes X No'<

3. Is construction a~tivity proposed in permit application? ..

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4. Does the applica~t' owe any outstanding fees to LDEQ?

If you answered ijYes" to No.4, above, attach explanation to this form.

'.

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'5. Is there a limit tol~he amount you are willing to pay to expedite the permit?

. Yes .. :: X:No.:<

form_7172_r01 12/13/06

Expedited Permit Request Page 1 of 2

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'Ifyou answered "Yes" to No.5, above, please read and complete the following:

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I understand that i~ such a maximum amount is requested, the number of overtime hours a department employee or contractor works processing the permit, modification, license, registration, or variance shall be · .,Iimited accordingly.I'/f further processing of the document is required, the department's continued review will .' . not be in accordance with 'the provisions of this Chapter, and the request will no longer be handled on an

: expedited basis. I Jnderstand tha/the department will charge'a fee for the expedited processing which was ..

performed. (LAC 33:1.1805). .

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· l wish to limit the ex'pedited permit fee to:

No limit

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Maintaining tank capacity availability by replacement of existing tanks tha are no longer in service with tanks with mora stringent emission controls.

.. ' ... ~

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'SECTION IV ":CERTIFiOATlo.~S.·.·

.i; .... -,. ".:.

'. " :",.' :,:" II' . .0' ...... : ',' . .-:. " . ., .' _- :,' ,.",_- .;;{.;:. ::.' '.

: Check:'th~~~J)propriate box regarding,pendlng.enforcement actions and-lawsuits. .•... ;.. . ...

"0 l~e~ify.{hat~ am' not subject to ~n;:'ki,~~i~9_:.~t~~e or fe~e"fJl enforcem~n~'ac~jo~sj ·i~cIUding.citi~e·n .. suitS -.

. broughtunderst(jle or federallaw. t ": .. '" .. .' . .: -:.'~ .

1/": . or" .... "'11' .. '.: ' •. ',' '. . ... , . ":'~:':, ;:'.-.~:;

( .':" 0 I am currimqy ~ubject. tO,pending state or federal e;iforceriient,actions, including citizen suits brought>

· :',' ,,'. <.' under state gr federal law. .' .' , ':' . .-. . " '::

• Ple'iia'se read and complete the following: , . , . :-"' ..

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· I, as the duly authorized responsible official, certify in accordance with LAC 33:1.1B03.C, that should additional information be requ~fed to complete the permit process, all requested information will be provided . within the

timeframes specified I by the department. ' .

I ut?dersta'nd that: 1 .

•. . If the requested information is not provided within the fimeframes specified, or if the limit I have indicated _as a maximudl amount to be paid for expedited processing is reached, the Department reserves the 'right to cease processing the permit, modification, license, registration, or variance 8S Em expeqitedpermit. .

. • If the depart~~nt ceases expediteipe'rmit processing, I will be billed (or·the expedjte:ci.pi~·c.essing that

occurred in accordance with LA C 33: I. 1805, B. . . '

• Failure to pay::the expedited permit processing fee by the due date specified on the invoice will constitut~,; a violation of these regulations and shall subject the applicant to relevant enforcement action under the' Louisiana En~!ronmental Quality Act including, but not limited to, revocation or suspension of the .permit, ,

modification, license, registration, or variance. .

• There is no gJlarantee that a final permit decision will be issued by the date I have requested.

• The submitta/lbf this request does not release me from liability for any vio/a/ions relaled to ihis activity or the Environmdntal Quality Act.

• A permit ma~l be required prior to any construction at the site, operation of the proposed' activity or commencement of discharges from this proposed activity, and I should refer to media-specific

regulations fO~1 t~ ipformation. /l .

Signature II./;t~ x:J1i17A~ Title Refinery Manager

IjLy~n G. Bourgeois (J

Printed Name

It? ~ 3 -0&

Date

form_7172_r01 12/13/06

Expedited Permit Request Page 2 of 2

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TITLE V MINOR MODIFICATION ApPLICATION MURPHY OIL USA, INC. • MERAUX REFINERY

Prepared by:

Valerie Barth • Principal Consultant Cheri Kwast • Consultant Carol Waszkowski • Technical Assistant

TRINITY CONSULT ANTS 4000 S, Sherwood Forest Boulevard Suite 503 Baton Rouge, Louisiana 70816 (225) 292-2661

December 2008

Project 081901.0063

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TriuityA CGnsultants

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TABLE OF CONTENTS

1. INTRODUCTION ,.. , 1

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1.1 REGULATORY CONSIDERATIONS 2

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1.1.1 REGULATORY ANAL YS[S 2

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1.2 . EMISSION RATE CALCULA TrONS 3

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2. ApPLICATION FOR ApPROVAL OF EMISSIONS

ApPENDlxA I

AREA MA~ & PLOT PLAN

ApPENDlXB

INSIGNIFICANT ACTIVITES AND GCXVIl ACTIVITIES

ApPENDIX c II

EMISSION CALCULATIONS

ApPENDIXD I

CERTIFICNfE OF GOOD STANDING

ApPENDIX E II

COMPLIANCE SCHEDULE AND ENFORCEMENT ACTION DOCUMENTATION

II Murphy Oil USA, lnc.

Trinity Consultants

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1. INTRODUCTION

Murphy Oil ust Inc. (MOUSA) own' and operates a petroleum refinery in Meraux, Louisiana. MOUSA is subihiuing this minor modification application in order to modify the facility's Title V permit accordin~ to the provisions in the Code of Federal Regulations (40 CFR Part 70) and as required by the Louisiana Department of Environmental Quality (LDEQ) Operating Permits Program, Chapter 5 of th~1 Administrative Code. Required data, certifications, and application forms are included in this ~pplication.

MOUSA receivL Title V Permit No. 2500-00001-V3 on May 8, 2008. MOUSA is submitting this minor modific~tion application to replace three tanks by constructing and operating Tanks 1-3A, 80-

II

5A, and 80-lOt at the Meraux Refinery. MOUSA is also requesting to reinstate Tank 80-9 in this

permit modifidtion. As there is no increase in CAP emission limits requested in this application, the

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application qualifies to be processed using minor modification procedures. I

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MOUSA is undertaking this project to replace existing tanks. The tanks will be constructed within

the current bou~daries of the Meraux Refinery and will be located at sites of existing tanks. Coverage under a Title ~I permit is required before construction can commence on these tanks. The tanks that

will be replaced are described more specifically below: .

... Tank 1-3AI~ilI replace Tank 1-3 at its existing location. (Tank 1-3 was built prior to 1958.) Tank 1-3A will have a capacity of 1,000 barrels and will be in slop oil return service for oily waters

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recovered from the onsite Wastewater Treatment Plant. Tank 1-3A will be equipped with an

internal flo~ting roof, whereas Tank 1-3 was a fixed roof tank. Therefore, MOUSA will realize a significant I~eduction in VOC emissions at this tank. Tank 1-3A will be subject to, and meet the emission cgntrol standards, ofNSPS Kb and MACT CC.

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.... Tank SO-SA will replace Tank 80-5 at its previous location. (Tank 80-5 was demolished in 2001.)

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Tank 80-SA will have a capacity of 80,000 barrels and will be in heavy oil service. Due to the

low vapor ~ressure of this material, Tank 80-5 will not be subject to NSPS Kb control standards, so it will o~ly be required to have a fixed roof.

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.... Tank 80-9 is an existing tank that will be incorporated into the permit. Tank 80-9 has a capacity

of 80,000 tiarrels and will be permitted for gasoline, middle distillate, and naphtha service. MOUSA J!ill replace the external floating roof with a domed internal floating roof. Tank 80-9 will be sutiject to, and meet the emission control standards, of MACT CC. MOUSA previously requested that the tank be removed in Title V Permit No. 2500-00001- V2, as the strategic plan at that time Jlas to remove the tank. The plans for this tank have now changed.

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.... Tank 80-1 OA will replace Tank 80- IO at its previous location. (Tank 80-10 was demolished in

2006.) Ta~ 80-1 OA will have a capacity of 80,000 barrels a1td will be permitted for gasoline, middle didlillate, sour water, naphtha, and heavy oil service .. Tank 80-1 OA will be subject to, and

- IJ .

I Per p~one conversation between Bryan Johnston (LDEQ) and Cheri Kwast on November 6,2008, minor modification proJkdures are appropriate if tanks are being added to an emissions CAP if the emissions CAP does not

increase. Public Hotice is not required lor a minor modification, which includes an addition of II source to an emissions CAP I if the capped emi~sions do not change.

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II Murphy Oil USA, Inc.

Trinity Consultants '

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meet the control standards of, NSPS Kb and MAC[ CC. Tank 80-IOA will have a domed . I fl II. f

mterna oatmg roo .

There is no increase proposed to the annual throughputs of the new tanks. Each lank will continue to have the same 11nnual throughput as the tank it will replace. Also, the tanks will comply with all federal and statg Spill Prevention, Control and Countermeasures (SPCC) rules.

1.1 REGULATORY CONSIDERATIONS

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1.1.1 REGULATORY ANALYSIS

Tabl~s I through 4 of Section 23 of the AAE contain the regulatory applicability analysis forT1nks 1-3A, 80-SA, 80-9, and 80-IOA. Federally applicable requirements as well as state!~egulations affecting the tanks are identified. This application only contains the regulatory applicability for the new equipment, as required.l

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The following list outlines the changes made to the regulatory applicability tables as they

are fgund in the facility's current Title V permit.

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... Tank 1-3 is being tom down and replaced with a new internal floating roof tank that

~ill be called Tank 1-3A. Tank J-3A must comply with NSPS Kb and MACT CC.

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Tank I -3A complies with MACT CC by complying with NSPS Kb as allowed.

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4 ~ank 80-5 was tom down and is being replaced with a new fixed roof tank that will be

JaIled Tank 80-SA. Tank SO-SA must comply with MACT CC as a Group 2 Tank.

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~ank SO-SA is exempt from NSPS Kb due to the low vapor pressure of the heavy oil it

J,ill store. Tank 80-SA will be subject to MACT cc.

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... ~ank 80-9 is being repaired and converted to a domed external floating roof tank. As

the costs associated with the repair of Tank 80-9 does not cause it to be considered r~constructed and the modification to the tank will not cause an increase in emissions

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(pnk 80-9 is being converted from an EFR to a DEFRlIFR), the modification to Tank

80-9 will not trigger NSPS Kb, but the tank must comply with MACT Cc.

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4 ~ank SO-10 was tom down and is being replaced a new domed external floating roof t~nk called Tank SO-IDA. Tank SO-IDA is subject to NSPS Kb and MACT CC.· Tank

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80-1 OA complies with MACT CC by complying with NSPS Kb as allowed.

2 Per phJ~e conversation between Syed Quadri (LDEQ) and Cheri Kwast (Trinity) on November 12,2008, only

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the regulatory applf,cability for the sources with changes in regulatory applicability need to be included in the application,

• ;;:.::'::<;J;'Y.Wl ""'''0"" ",I;"b;I;" "O~ '0' ,,'" '0 be ;"1 •• ",, m ,Ii, '1'1'''''';0' ; f '0 <h,"g~ 're bci'g

I) Murphy Oil USA, lnc.

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Trinity Consultants

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1.2 EMISSION RATE CALCULATIONS

Emission rate calculations for Tanks 1-3A, 80-SA, 80-9, and 80-1 OA have been included in Appendix C of this applicMtion. Since no changes are being requested for the tank emission CAPs, calculations

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of the CAP limits have not been included in this application.' To maintain consistency with the

current Title V ~ennil, calculation of the maximum emission rates have been included in Appendix C. Tank 80-10A is1lbeing added to the gasoline, middle distillate, naphtha, and heavy oil CAPs. Tank 80-1 OA will alsb operate in sour water service. Tank 80-9 is being added to the gasoline, middle distillate, and nMphtha CAPs. Tank 1-3A is being added to the slop oil CAP, and Tank 80-SA is being added to the he~vy oil CAP.

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3 Per pho~~ conversation between Syed Quadri (LDEQ) and Cheri Kwast (Trinity) on November 12,2008, calculations should ~Iot be included if CAP emissions are not changing.

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Murphy Oil US~, Inc.

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Trinity Consultants

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2. ApPLICATION FOR ApPROVAL OF EMISSIONS 1

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l__~~~~ __ M_urphY Oil ]' Inc.

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Trinity Consultants

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Department of Envnonmental Quality Office of Envirorllnental Services Air Permit~ Division

P.O. Bo~ 4313

Baton Rouge, L~ 70821-4313

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(225) 219-3181

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LOUISIANA

Application for Approval of Emissions of Air Pollutants from Part 70 Sources

1. II . PLEASE TYPE OR PRINT
Facility Informatien [LAC 33: 111.517 .D_1]
Facility Name or Process Unit Name (if any) I
Meraux Refinery II
Agency Interest Number (A.I. Number) Currently Effective Per
1238 II 2500-00001- V3
Company - Name Of Owner
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Murphy Oil U.S.A,I!nc.
Company - Name or Operator (if different from Owner)
II
Parent Company (if Company - Name of Owner given above is a division)
Murphy Oil Corpo4tion
Ownership: 11
Check the appropriate box.
I8l . II h' 1 . hi o regulated utility Om
corporation, partners ip, or so e propnetors ip
11 Dot
o state govenunent 0 federal govenunent
• 2 . Physical LoJltion and Process Description
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ILAC 33: 111.51 ':1.0.18, unless otherwise stated]
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What does this facility produce? Add more rows as necessary.
See introduction. II
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What modification)/changes are proposed in this application? Add more rows as necessa
See introduction. II .
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Nearest town (in the same parish as the facility): Parish(es) where facilit
Meraux, LA· 11 SI. Bernard
Distance To (mi): II - 239.4 Texas - 236.2 Arkansas - 31.9 M
Latitude of Facility Front Gate: 290eg 55 Min 48 Sec
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Longitude of Facility Front Gate: 890eg 2§Min ±lSec
Distance from neJ}est Class I Area 91.8 kilometers
Add physical addrJL and description of location of (he facility belo~. If the facility has n
directions. Add mJ~e rows as necessary.
MU!Ehy Oil U.S.A!~ Inc., Meraux Refinery
2500 E. SI. Bernard Hi~hwax
Meraux, LA 70075J
!8J Map attached (~equired per LAC 33:II1.517.D.I)
• [8] Description of ~rocesses and products attached (required per LAC 33: II1.517.0 .2)
[8] lntroduction/Description of the proposed project attached (required per LAC 33 :1II.517.
form_7195_rOO
06/06/07 [8J All Process Units

o Pro~ess Unit-specific Permit

mit Number(s)

unicipal government

her, specify

ry.

Y is located:

ississippi

-101.2 Alabama 80 Hundredths 70 Hundredths

o address, provide driving

0.5)

3. Confidentiality (LAC 33.I.Chapter 5]
• Are you requesting dbnfidentiality for any information except air· pollutant emission rates? 0 Yes [8J No
If 'yes, " list the se~tions for which confidentiality is requested below. Add rows as necessary. Confidentiality requests
require a submittal that is separate from this application. Information for which confidentiality is requested should not be
submitted with this Jpplication. Consult instructions.
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4. Type of APpJbation (LAC 33:III.517.D)
Complete the appropriate column (lor 2) that corresponds to the type of permit being sought. Check all that apply within
the appropriate colufun. I
Column 1 [I Column 2
o Part 70 General 11 [8J Part 70 Regular
o Renewal II o Renewal I
Select one, if applicable: Select one, if applicable: I
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o Entirely new facility o Entirely new facility
o Modification or ~Ixpansion of existing facility (may also o Significant modification or expansion of existing facility
include reconciliations) (may also include reconciliations) [LAC 33:11I.527]
OR T' III
econci iation on y [8J Minor modification or expansion of existing facility (may
o Individual emiss~bns unites) addition also include reconciliations) [LAC 33:111.525]
o Reconciliation only
NSR Analysis:
I
,
psoD NNSRD
• Does this submittal tdate or replace an application currently under review? 0 Yes [8] No I
. II
If yes, provide date that the prior application was submitted:
Select one if this apJ~ication is for an existing facility that does not have an air quality permit
o Previously Grandfathered (LAC 33:III.50 I.B.6)
o Previously Exempted (e.g., Small Source Exemption; Act 918)
o Previously Unpermitted
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5. Fee Information (LAC 33:III.517.D.17J
Fee Parameter: If the fee code is based on an operational parameter (such as number of employees or capital cost), enter that
q I
parameter here. Refinery crude throughput.
Industrial Category: Enter the Standard Industrial Classification (SIC) Codes that apply to the facility.
Primary SICC: 11 2911
Secondary SICC(s): N/A
Project Fee calculLion: Enter fee code, permit type, production capacity/throughput, and fee amount pursuant to LAC
33:III.Chapter 2. Add rows to this table as needed. Include with the application the amount in the Grand Total blank as the
permit application f~e.
FEE EXISTING INCREMENTAL SURCHARGES
CODE TYPE CAPACITY CAPACITY MULTIPLIER NSPS PSD AIR TOTAL
INCREASE TOXICS AMOUNT
0720 Minorll 125,000 N/A NJA [8J 0 0 $2,332.50
BBUday
• GRAND TOTAL $2,332.50

form 7195 rOO :
- -
06/06/07 more than 25 IOns/year of all nonattainment [!ollutants, change emissions by more than 10 tons/year of an individual toxic
• air [!ollutant, or change emissions by more than 100 tons/year of all other criteria (attainment) Qollutants, then the Qennit
fee is egual to the minimum minor modification fee for each fee [!rocess catego[Y involved. Per LAC 33:IIl.211.A, the
25% NSPS fee has been assessed.
Electronic Fund T~anSfer (EFT): If paying the penn it application fee using an Electronic Fund Transfer (EFT), ple~s
include the EIT Tra!nsaction Number, the Date that the EFT was made, and the total dollar amount submitted in the E
If not paying the perlhit application fee using EFT, leave blank.
EFT Transactirin Number Date of Submittal Total Dollar Amount
N/A II N/A s N/A
6. Key Dates
Estimat~d date construction will commence: 112009 Estimated date operation will commence: 512009
7. Pending per!it Applications - For Process Unit-Specific Permits Only
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[LAC 33:III.517·.D.18]'·
List all other proceJ~ units at this facility for which Part 70 permit applications have been submitted, but have not be
acted upon by LDE<ti as of the dale of submittal of this application. If none, state "none" in the table. **It is not necessa
to update this table tJuring the permit review process, unless requested by LDEQ. **
Process l!~it Name Permit Number Date Submitted
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11
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• 8. LAC 33:1.1701 Requirements - Answer all below for new sources and permit renewals -
DYes [8J No II
Does the company or owner have federal or state environmental permits identical to, or of a similar nature to, the perm
for which you are aflplying in Louisiana or other states? (This requirement applies to all individuals, partnerships,
corporations. or othler entities who own a controlling interest of 50% or more in your company. or who participate in th
environmental manJgement of the facility for an entity applying for the permit or an ownership interest in the permit.)
DYes [8J No
If yes, list Sta tes: N/A
--
Do you owe any outstanding fees or final penalties to the Department? DYes DNo
If yes. explain beloJ/ Add rows if necessary.
II
II
II
1 II. limi d li bili ? DYes DNo
s your company a corporation or 1m lie IQ I uy company.
If yes, attach a cop~ of your company's Certificate of Registration and/or Certificate of Good Standing from the
Secretary of State. liThe appropriate certificate(s) should be attached to the end of this application as an appendi
Note: *Please refer. to Appendix D for the Certificate of Good Standing .
•
form _7195 _rOO
06/06/07 UO'Ptional** Fee Explanation: Use the space provided 10 give an explanation of the fee determination displayed above.

II

In accordance with LAC 33:1IJ.21I.B.l3.d. since this pennit modification does not increase caoacity. chan~e emissions bv

e FT.

en

ry

it

e

x.

9. Permit Shield Request ILAC 33:III.517.E.7) - 0 Yes [8J No
• If yes, check the a~propriate boxes to indicate the type of permit shield being sought. Include the specific regulatory
citation(s) for which the shield is being requested. Give an explanation of the circumstances that will justify the permit
shield request. Att~bh additional pages if necessary. If additional pages are used, attach them directly behind this page and
enter "See Attache1lpages" into the Explanation field. ;
Type of Permit Shield request (check all that apply):
II
Non-applicability determination for: Specific Citation(s) Explanation
0 40 CFR 60
o 40 CFR 61
,
o 40 CFR63 I
D II
Prevention of Significant Deterioration ,
II
0 II
Nonattainment New Source Review I
II
II
Interpretation of monitoring, recordkeeping,
and/or reporting ~~quirements, and/or means
of cri'mpliance for: Specific Citation(s) Explanation •

•

o 40 CFR60

o 40 CFR61

o 40 CFR 63

II

o Prevention of Significant Deterioration

. II .

II

o NonattainmentNew Source Review

II

o

State Implementation Plan (SIP) Regulation(s) r'6ferenced in 40 CFR 52

Subpart T II

form_7195 _rOO 06/06/07

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10. Certification of Compliance With Applicable Requirements

Statement for AP~licable Requirements for Which the Company and Facility Referenced In This Application Is In

Compliance II

Based on information and belief, formed after reasonable inquiry, the company and facility referenced in this application is in compliance with and will continue to comply with all applicable requirements pertaining to the sources covered by the

permit 8PPlic8tionlias outlined in Tables 1 and 2 in the permit application. \

For requirements kromulgated as of the date of this certification with compliance dates effective during the permit term, I further certify that;:the company and facility referenced in this application will comply with such requirements on a timely basis and wiJl continue 10 comply with such requirements.

. II

CERTIFICATION: I certify, under provisions in Louisiana and United States law which provide criminal penalties for falsell statements, that based on information and belief formediafter reasonable inquiry, the statements and information I contained in this Application for

Approval of Emissions of Air Pollutants from Part 70

Sources, includirig all attachments thereto and the

compliance state&ent above, are true, accurate, and

complete. II

a. Responsible Of~cial
Name II
Lynn G. Bourgeois
Title II
Refinery Manager]
Company . II
Murphy Oil U.S.1\;, Inc.
Suite, mail drop, or division
II
Street or P.O. Box
P .0.Bolt 100 II
City II I ~tate I Zip
Meraux LA 70075
Business phone II
(504) 271-4141
Email Address II
Lynn _iourgeois@p1urphYOilcorp.com form_7195_rOO 06/06/07

CERTIFICATION: I certify that the engineering calculations, drawings, and design are true and accurate to the best of my knowledge.

b. Professional Engineer
Name
Mr. Paul Greywall, P.E.
Title
Director, Business Development
Company
Trinity Consultants, Inc.
Suite, mail drop, or division
Street or P.O. Box
12770 Merit Dr.
City I State I Zip
Dallas TX 75251
Business phone
(972) 661-8100
Email Address
Paul_ G reywa Il@trinityconsultants.com Louisiana Registration No.

29270

-------------- ----

11. Personnel rUr.4.C 33:11I.517.D.11
"
II
• a. Manager of Facility who is located at plant site b. On-site contact regardin ~ air pollution control
Name III DPrimary contact Name [2]Primary contact
Lynn G. Bourgeois 1 Mr. Mati Dobbins
Title II Title
Refinery Manager Environmental Engineer
Company IJ Company
Murphy Oil U.S.A., ~.nc. Murphy Oil U.S.A., Inc.
Suite, mail drop, 01ldiviSion Suite, mail drop, or division
Street or P.O. Box II Street or P.O. Box
P.O. Box 100 P.O. Box 100
City II State I Zip City State I Zip
Meraux LA 70075 Meraux LA 70075 ,
Business phone II Business phone !
(504) 271-4141 (504) 271-4141
Email address IJ Email address
Lynn _ Bourgeois@ll},urphyoilcorp.com Matt_ Dobbins@murphyoilcorp.com
II ;
c. Person to contac~lwith written correspondence d. Person who prepared this report !
Name II I Name I DPrimary contact
Mr. Matt Dobbins [2]Primary contact Ms. Valerie Barth
,
• Title II Title .
Environmental Engineer Principal Consultant
Company II Company
Murphy Oil U.S.A., Inc, Trinity Consultants
Suite, mail ~rop, 01idivision Suite, mail drop, or division
Suite 503
Street or P.O. Box 11 Street or P.O. Box
P.O. Box 100 4000 S. Sherwood Forest Blvd.
City " I State I ~~~75 City State I Zip
Meraux LA Baton Rouge LA 70816.
Business phone II Business phone I
(504) 271-4141 (225) 292-2661
Email address II Email address i
Matt~ Dobbins@mu,whyoilcorp.com vbarth@trinityconsultants.com
II
e. Person to contact'about Annual Maintenance Fees Oa [8]b Dc Dd D other (specify below) .
Name If Suite, mail drop, or division I
DPrimary contact
Title I) Street or P.O. Box ;
Company " City State Zip
I
• Business Phone II Email Address

form_7195_rOO
06/06/07
,
-~ --- • 12. Proposed Project Emissions [LAC 33:111.517.0.3]
II
List the total emissions following the proposed project for this facility or process unit (for process unit-specific
permits). Speciatelall criteria pollutants, TAP, and HAP for the proposed project.
II Pollutant Proposed Emission Rate (tons/year)
II 1,3-Butadiene 0.04
2~2,4-Trimethylpentane 4.271
II
II Ammonia 45.64
II Benzene 8.23
II Carbon Monoxide 1960.70
II Cumene 0.07
II Ethyl Benzene 1.48
II Formaldehyde 2.91
II Hydrochloric Acid 0.D3
II Hydrofluoric acid 0.50
II Hydrogen Sulfide 6.22
Methyl Tertiary Butyl Ether 10.43
II.
Naphthalene (and Methyl Naphthalenes) 0.53
II
11 N-hexane 7.91
• II Nitrogen Oxides 1220.06
II Particulate Matter (PM 1 0) 206.40
Polynuclear Aromatic Hydrocarbons 0:111
II
II . Sulfur Dioxide 684.49
II Toluene 8.25
II Total voe 600.30
Xylene (mixed Isomers) 8.11
I ~
• 13. History of Permitted Emissions (LAC 33:IlI.517.D.18]
• List each of the folloJing in chronological order:
"
• The Penni! Number and Date Action Issued for each air quality permit that has been issued to this facility or
I,
process unit (for process unit-specific permits) within the last ten (10) years.
• All small soJ~ce exemptions, authorizations to construct, administrative amendments, case-by-case insignificant
activities, and changes of tank service that have been approved since the currently effective Title V Operating
Permit or St~ie Operating Permit was issued to this facility or process unit (for process unit-specific permits). It
is not necess~ to list any such activities issued prior to the issuance of the currently effective Title V Operating
Permit or Sffite Operating_ Permit, if one exists.
Ji~rmit Number Date Action Issued
~pOO-OOOO 1- VO 04117/01
~pOO-OOOO 1- VI 02/08/02
30~.9-VO (rescinded) 03/31/06
304.6- VO (rescinded) 11109/06
2500-0000 J - V2 (incorporates 3029- VO and 3046- VO 11120107
11 items)
~.500-0000 1- V3 05/08/08
II
II
II
II
II
II
II
II
• JI
JI ,
II
II
II
II ,
II
II .
II
II
11
II
11
II
II
II
II ,
II ,
II
II
II
II
• II
U
11
torm_7195_rOO
06/06/07 14. Facility-wide Permitted Emissions - For Process Unit-Specific Permits Only [LAC
• 33:III.517.D.3J II
List each of the following:
• All currentl~leffective air quality permits for this facility. All process units located at this facility should be
represented ih this section. This includes any Acid Rain or PSD permits.
For each listed currently effective air quality permit:
• Show each J,brmitting action's grand total for each permitted pollutant. These rates should be those shown in
the pennittin~ action as issued by LDEQ and not those shown in the application for the permitting action.· For
administrative amendments, it is only necessary to state the emission rates that were amended.
• Group the pJmitted emission rates by permit action. Consult instructions.
As the last entry, sho~ the facility-wide grand total for each pollutant.
Permit Actions , Date Action Issued Pollutant Permitted Emission Rate
II (tonstyr)
N/A II
II
II
II
II I
II
II
II
II
II
II
'. II
II
II ,
II
II
II
II
II
II i
II
II
II ,
II ,
,
II
II
II
11
II
II
II
II
II
• II ;
II

.
form 7195 rOO
- -
06/06/07 •

•

•

15.a. Enforcement Actions (LAC 33:1I1.517.D.18] - [8J Yes 0 No

If yes, list all federallhd state air quality enforcement actions, seltleme~t agreements, and consent decrees received for this facility and/or pr&ess unit (for process unit-specific permits) since 'the issuance of the currently effective Title V

"

Operating Permit or State Operating Permit. For each action, list the type of action (or its tracking number), the

regulatory authority o~ authorities that issued the action, and the date that the action was issued. Summarize the conditions imposed b~ the enforcement action, settlement agreement, and consent decree in Section 23, Table 2. It is not necessary to submit a 'bopy of the referenced action. Add rows to table as necessary.

II

Type of Actloh Issuing Authority Date Action Issued Summary of Conditions'
or Tracking NuJ,ber I
Included? ,
AE-CN-08-0l22 !I Louisiana Department of August 29,2008 ~Yes DNo
Environmental Quality Note: The ongoing Jrrespondence related to enforcement action AE-CN-08-0122 including the compliance order, compliance plan, and!~equest for adjudicatory hearing have been included in Appendix E.

. II .

15.b. Schedule for Compliance [LAC 33:III.517.E.4] l'8l Yes 0 No

If the facility or pro~less unit for which application is being made is not in full compliance with all applicable regulations, give a dbscription of how compliance will be achieved, including a schedule for compliance below. Add rows as necessary, See instructions.

The compliance plaJ~ for Enforcement Tracking Nos. MM-CN-02-00 15 and AE-CN-08-0122 submitted by Murphy Oil USA, Inc. to thell.ouisiana Department of Envirorunental Quality on October 26, 2006 and October 8,2008,

respectively, are included in Appendix E of this application.

16. Letters of AI~proval for Alternate Methods of Compliance - 0 Yes l'8l No

If yes, list all corresp1bndence with LDEQ, EPA, or other regulatory bodies that provides for or supports a request for alternate methods of1bompliance with any applicable regulations for this facility or process unit (for process unitspecific. permits). Li~t the date of issuance of the letter and the regulation referenced by the letter, Attach as an appendix a copy of ~11 documents referenced in this table. Letters that are not included may not be incorporated into a final permit. ~dd rows to table as necessary.

Note: No alternate JLhOdS of compliance are being requested in this permit application that have not been

incorporated into lhel:current Title V Permit No. 2500-00001- V3. .

Date Letter Issued] Issuing Authority I
Referenced Regulationts) Copy of Letter Attached?
N/A II DYes DNo
II D Yes UNo
II DYes DNo
II DYes 0 No II

17. Initial Notifications and Performance Tests (LAC 33:111.517.E.l( - [8J Yes 0 No

If yes, list any initiailinotifications that have been submitted or one-time performance tests that have been performed for this facility or prdcess unit (for process unit-specific permits) since the issuance of the currently effective Title V Operating Permit or State Operating Permit in order to satisfy regulatory requirements. Any initial notification or one-time performance test requirements that have not been satisfied should be listed in Section 23, Table 2 of this

"

application. Any notifications or performance tests that recur periodically should also be properly noted in Section

23, Table 2 of this aplplication. Add rows to table as necessary .

form_7195_rOO 06/06/07


• Initial Notification or
One-time perform~nce Test'! Regulatory Citation Satisfied Date Completed/Approved
NSPS Notification of 40 CFR 60.7(a)(I) Submittal dated July 29, 2008
Construction Comm~ncement 40 CFR 63.9(b)(2)
(300-4) IJ
NESHAP Initial Notification
(300-4) II
NSPS Notification of 40 CFR 60.7(a)(I) Submittal dated August 8,2008
Construction Comm~ncement 40 CFR 63.9(b)(2)
(300-6A) II
NESHAP Initial Notification
(300-6A) II
NSPS Notification of 40 CFR 60.7(a)(I) Submittal dated September 19,2008
Construction Comm~ncement 40 CFR 63.9(b)(2)
(250-8) II
NESHAP Initial Notification
(250-8) II ••

18. Existing pJvention er Significant Deterioration or Nonattainment New Source Review Limitations ILA!C 33:III.517.D.18]

Do one or more emi~sions sources represented in this permit application currently operate under one or more NSR permits? C8] Yes D No I

If"yes," summarize the limitations from such permit(s) in the following table. Add rows to table as necessary. Be sure to

I .1. lirni fi h ' ( )' S 13 d 14 f h' r

note any annua emissions mutations rom sue permit s m ecuons an ot trns apphcatron,
Permit Date Emission Pollutant BACTILAER Averaging Description of Control
Number Issued Point ID Limit 1 Period Technology/Work
No. Practice Standards
PSD-LA-566 II CO 197.81b/hr Hourly High temperature
06/14/1991 2-77
II regeneration
PSD-LA-566 II High temperature
06/14/1991 2-77 CO 866.4 tpy Yearly
II regeneration
PSD-LA-566 II
06/14/1991 2-77 PMw 26.01b/hr Hourly ESP
II
PSD-LA-566 II
06/14/1991 2-77 PMIO 113.9 tpy Yearly ESP
II
..
PSD-LA-19 qp/07/1977 1-76 S02 5761bs/day Daily Emission limit
PSD-LA-19 ~~/071l977 1-76 TSP 105lbs/day Daily Emission limit 1 "

For example, Ib/MM Btu, ppmvd @ 15% O2, Ib/ton, Ib/hr

form_7195_rOO 06/06/07

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'.

19. Air Quality Dispersion Modeling ILAC 33:111.517.D.15]

Was Air Quality Dis}ersion Modeling as required by LAC 33:11I performed in support of this permit application? (Air Quality Dispersion Modelin~ is only required when applying/or PSD permits and as requested by LDEQ.)

~asY~: Q~a~~ D~l,,;on Modeling completed in accordance with LA C 33.111 ever been performed for this facility in support of a air perJlil application previously submitted for this facility or process unit (for process unit-specific permits) or as required by otherllregu{ations AND approved by LDEQ?

I8l Yes D No I .

If yes, enter the date the most recent Air Quality Dispersion Modeling results as required by LAC 33:III were submitted:

May 31, 2007 I

If the answer to eith~r question above is "yes," enter a summary of the most recent results in the following table. If the answer to both questions is 'I'tno," enter "none" in the table. Add rows to table as necessary.

I .

Calculated Maximum Louisiana Toxic Air Pollutant
Ambient Air Standard or
Pollutant Time Period Ground Level (National Ambient Air QualitY
Concentration Standard {NAAQS})
Visibility 24-hr 0.442 tldv 0.5 L'ldv Best Available Retrofit
Technology (BARD Exemption
Threshold
Formaldehyde II Annual 0.004 7.69
II .
Ammonia 8-hr 0.2 640
II ,
1,3-Butadiene Annual 0.35 0.92
Naphthalene II 8-hr 199.7 1,190
Polynuclear Annual 0.03 0.06
Aromatic
Hydrocarbons
Xylene II 8-hr 1485.6 10,300
n-Hexane II 8-hr 759.3 4,190
Hydrogen II 8-hr 36.00 61.90
Fluoride
Hydrogen II 8-lrr 50.5 330
Sulfide
Toluene II 8-hr 1211.6 8,900
Benzene II Annual 9.6 12 Note: The toxics Inodehng results listed above were submitted III March 2002 and are the only facility-wide modeling submitted since the issuance of Title V Permit No. 2500-00001- VO.

form _7195 _rOO 06/06/07

•

•

•

20. General Condition XVII Activities- ~ Yes 0 No

Enter all activities that qualify as Louisiana Air Emissions Permit General Condition XVII Activities.

• Expand thik table as necessary to include all such activities.

• See instructions to determine what qualifies as a General Condition XVII Activity.

• Do not incl~de emissions from General Condition XVII Activities in the proposed emissions totals for the permit li . 'I

apJ'ilcatlOn.
II Emission Rates - TPY
II
Work Activity Schedule PM10 S02 NO. CO VOC Other'
Carbon ReplacemeMtI Recharging 8 timeslyr - 3.5 2.5 - 0.14 0.04 (H2S)
II 0.02 (NHJ)
Changing Filters II 300 times/yr - - - - 0.07 -
Cleaning of Equipn:!ent 96 timeslyr - - - - 0.02 -
Clearing of Pipelin~s 240 times/yr - - - - . 0.47 -
C M' II 24 times/yr 0.02
ompressor amtenance - - - - -
Draining Compressor Bottles 7200 tirnes/yr - - - - 2.7 -
Instrument Maintenance 240 times/yr - - - - 0.43 -
" -
Miscellaneous Equipment 21 times/yr - - - - 4.4 -
Preparation II
Nitrogen Blowing q:fPipelines 240 times/yr - - - - 0.06 - :
Pump Maintenancej 1000 times/yr - - - - 3.6 -
Sampling II 360 times/yr - - - - 0.15 -
Sludge Removal II Twicelyr 1.95 ,
- - - - -
Solids Removal fro~ Sumps S nmes/yr - - - - 0.24 -
Solids Loading/Unloading 58 times/yr 1.45 - - - - -
Tank Gauging II 390 times/yr - - - - 0.076 -
Valve Maintenancej 960 times/yr - - - - 1.30 - !
Portable Waste Tanks (for storage As Required 0.06
II - - - - -
of samples to be recycled)
Painting Operations' 2,200 gallyr - - - - 2.9 -
"
Welding operalioJ (welding rod) 75lb/week,
100lb/week 0.04
during - - - - -
II
turnarounds
Parts Washers OpePations 400 gal/yr - - - - 1.3 -
" .
Taking Floating Roof Tanks Out 5 times/yr - 1.9
of Service II - - - , -
Taking Fixed ROofllfankS Out of 4 times/yr - 0.30
Service j - - - -
" Note: *No changes were made as part of this application. Calculations have been included III Appendix B of this application. I

21. Insignificant Activities [LAC 33:11I.501.B.5] - [8] Yes 0 No

Enter all activities lliat qualify as Insignificant Activities.

"

• Expand this table as necessary to include all such activities.

• For sourc~~ claimed to be insignificant based on size or emission rate (LAC 33:HI.501.B.5.A), information must be supplied to verify each claim. This may include but is not limited to operating hours, volumes, and heat input

form_}195 rOO 06/06/07

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•

•

ratings.

If aggregateemissions from all similar pieces of equipment (i.e. all LAC 33:1II.501.B.5.A.1 activities) claimed to be insignificant are greater than 5 tons per year for any pollutant, then the activities can not be claimed as insignificant' and must be represented as permitted emission sources. Consult instructions.

II

•

Emission Point ID No.

Citation

- EJpty Drum Washing See Appendix B LAC 33:III.501.B.5.A.7
- A~ine and Diesel Storage Tanks See Appendix B LAC 33:I11.501.B.5.A.3·
I~ See Appendix B LAC 33:III.50I.B.5.A.6
- Laboratory Equipment Vents
- Di~sel Storage Tank Y - V -310 See Appendix B LAC 33:III.501.B.5.A.3
StJrage and Use of Water Treating See Appendix B LAC 33:1II.501.B.5.B.8
- C~~micals
- A('6eous Caustic Storage Tanks See Appendix B LAC 33:1I1.50I.B.5.B.40 Description

Physical/Operating Data

form _7195 _rOO 06/06/07

•

••

•

22. Regulatory 'Applicability for Commonly Applicable Regulations - Answer all below

,

[LAC 33:III.511.D.101 .

Does thisfacility co~tain asbestos or asbestos containing materials? [8J Yes 0 No

If"yes," the facilityipr any portion thereof may be subject to 40 CFR 61, Subpart M, LAC 33:IlI.Chapter 27, and/or LAC 33:II1.5151 and this application must address compliance as stated in Section 23 of this application

Is the facility or prJhess unit represented in this permit subject to 40 CFR 68, or is any otherprocess unit located at the same facility as ~he process unit represented in this application subject to 40 CFR 68? [8J Yes 0 No

If "yes," the entire :facility is subject to 40 CFR 68 and LAC 33:IILChapter 59 and this application must address compliance as stated in Section 23 of this application;

II

Is the facility listed in LAC 33:111.5611

I

Table 5 [8J Yes 0 No

I

Table 6 [8J Yes 0 No

I .

Table 7 [8J Yes 0 No

Does the applicant bwn or operate commercial refrigeration equipment normally containing more than 50 pounds of refrigerant at thi~/acility or process unit? [8J Yes 0 No

If"yes," the entire facility is subject to 40 CFR 82, Subpart F and this application must address compliance as stated

in Section 23 ofthi~ application. .

form _7195 _rOO 06/06/07

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••

23. Applicable Regulations, Air Pollution Control Measures, Monitoring, and Recordkeeping Important points for Table I [LAC 33:III.517 .D.I 0]:

• List in Tabl~1 I, by Emission Point ID Number and Descriptive Name of the Equipment, state and federal pollution ab~tement programs and note the applicability or non-applicability of the regulations to each

• ~~~s~· the JadingS for the columns in Table I as necessary to reflect all applicable regulations, in addition to any regul~bons that do not apply but need an applicability determination to verify this fact.

• For each piJe of equipment, enter "I" for each regulation that applies. Enter "2" for each regulation that applies to thl~ type of source, but from which this source of emissions is exempt. Enter "3" for equipment that is subj~t to a regulation, but does not have any applicable requirements. Also, enter "3" for each regulation that have applicable requirements that apply to the particular emission source but the regulations ~tirrentlY do not apply due to meeting a specific criterion, such as it has not been constructed, modified or ~econstructed since the regulations have been in place.

• Leave the sJ'aces blank when the regulations clearly would not apply under any circumstances to the source.

For examplet LAC 33:111.2103 - Storage of Volatile Organic Compounds would never apply to a steam generating b8iler, no matter the circumstances.

C I· /I .

• onsu t mstructions.

II

Important points for Table 2 [LAC 33:III.517.D.4; LAC 33:III.5l7.D.7; LAC 33:111.517.0.10]:

• For each pi~he of equipment listed in Table 2, include all applicable limitation, recordkeeping, reporting, monitoring, ~nd testing requirements. Also include anyone-time notification or one-time tests performance test requirements that have not been fulfilled.

• Each of the~~ regulatory aspects (limitation, recordkeeping, reporting, etc.) should be addressed for each regulation tHJt is applicable to each emissions source or emissions point.

• For each re~ulation that provides a choice regarding the method of compliance, indicate the method of compliance that will be employed. It is not sufficient to state that all compliance options will be employed, though multiple compliance options may be approved as alternative operating scenarios.

• Consult instructions .

11

Important points for "Fable 3 [LAC 33:IIl.517.D.16]:

"

• Each time a 2 or a 3 is used to describe applicability of a SOUTce in Table I t an entry should be made in Table

3 that explaias the exemption or non-applicability status of the regulation to that source.

• Fill in all reqhested information in the table.

• The exact n~lgulatory citation that provides for the specific exemption or non-applicability determination

'"

should be entered into the Citation Providing for Exemption or Non-applicability column.

• Consult InstJ!uctions.

Important points for \fable 4 [LAC 33:IlI.517 .D.18]

• List any siri~le emission source that routes its emissions to another point where these emISSIOns are commingled;lwith the emissions of other sources before being released to the atmosphere. Do not list any single emission source in this table that does not route its emissions in this manner.

• List any andl1all emission sources that are routed as described above. This includes emission sources that do not otherwisJ appear in this permit application.

• Consult instiLctions .

form _7195 _rOO 06/06/07

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24. Emissions Inventory Questionnaire (EIQ) Forms [LAC 33:111.517.0.3; 517.D.61 Complete one (I) EIQ for: .

• Each emissiog source. If two emission sources have a common stack, the applicant may submit one EIQ sheet for the dhmmon emissions point. Note any emissions sources that route to this conunon point in Table 4 of the application.

• Each emissioris CAP that is proposed. In general, this applies to each source that is part of the CAP.

• Each altematJloperating scenario that a source may operate under. Some common scenarios are:

I. Souftes that combust multiple fuels

2. Sou~es that have Startup/Shutdown max lb/hr emission rates higher than the max Ib/hr for normal operMting conditions would need an EIQ for the Startup/Shutdown emission rates for those sources

• Fugitive emissions releases. One (I) ElQ should be completed for each of the following types of fugitive

.• II .. .

emISSIOns sources or emissions points:

E .11

I. quipment leaks.

2. Non11equiPment leaks (i.e. road dust, settling ponds, etc).

For each EIQ: I

• Fill in all requested information.

• Speciate all T~xic 'Air Pollutants and Hazardous Air Pollutants emitted by the source.

• Use appropridte significant figures.

C I· n .

• onsu t instructions.

II

The EIQ is in Microsoft Word Excel. Click on this link to get to the EIQ form,

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•

25.E Nonattainment New Source Review Offsets ILAC 33:I1L517.D.16, LAC 33:1IJ.504.DA & 5) [8J N/A Complete this section J~ly if the proposed project triggers Nonattainment New Source Review (NNSR).

This project tTl.·ggers NN[I SR review for: D NOx D VOC

NOx: I

Is the applicant proposing to use internal offsets? DYes D No

If not, ide~tify the sou)!e of the offsets. Company:

Facility/Unit:

Permit No.:

Is an ERe Bank Application included with this application, or has an application already been submitted to LDEQ?

DYes DNo II

If the ERe application-has already been submitted, give the date:

Identify the emissions Units from which the offsets will be obtained (reference specific Emission Point ID numbers).

VOC:

ls the applicant proposing to use internal offsets? DYes D No

[foot, identify the souj!e of the offsets. Company:

Facility/Unit:

Permit No.:

Is an ERe Bank Application included with this application, or has an application already been submitted to LDEQ?

DYes DNo II .

If the ERe applicationlhas already been submitted, give the date: __

Identify the emissions Jnits from which the offsets will be obtained (reference specific Emission Point ID numbers).

In order to expedite prles~ing, please be sure the ERe Bank Application is completed properly. In the case of NO x. the document should clearly differentiate between ozone season and non-ozone season actual emissions during the baseline period. Regarding NOk and voe, be sure to indicate if a portion of the reductions are no longer surplus (e.g., due to new or revised federal or state regulations, use in a netting analysis, etc.).

2S.F. Economic Imptt

Answer the following ~uestiolls.

How many temporary jobs will be added as a result of this project? Approximately, 75 te~porary jobs will be added as a result of this

I

How many permanent [cbs will be added as a result of this project?

No permanent jobs will be added as a result of this project.

project.

form_7195_rOO 06/06/07

•

•

'.

2S.C Notification of Federal Land Manager [LAC 33:III.S04.E.l, LAC 33:IIl.509.P.I] Complete this section Ilmly if the proposed project triggers NNSR or PSD

II

a. [s the proposed [agility or modification located within 100 kilometers of a Class I Area? 0 Yes 0 No

If Yes, determination ~fQ/d is not required; skip to the next question. If No, complete the Q/d equation below:

PMIO(NEI) +1!S02fNEI) + NOxfNEJ) + HZS04(NEJ) where: PM 10 (NEI) = net emissions increase ofPMIOI.2

Q/d = _ ___:.:...:..:....;~.:!---=...:c....=.:..o.... _ __;_:_;;,..='--~---'-"-='-

Class] Ian S02 (NEI) = net emissions increase of SO/2

NOX(NEI)

, H2S04 (NEI) Class] Ian

= net emissions increase ofNOXI,2

= net emissions increase ofH2S04J,2 = distance to nearest Class I Area'

1+ Q/d = ======-!l---=====----====~-=====

+

+

IfQID < 4, proceed to Section 26. IfQ/D ~4, complete the remainder of this Section.

b. Has the applicant lrovided a copy of the application to the Federal Land Manager? 0 Yes 0 No

c. Does the application contain modeling that demonstrates no adverse impact on Air Quality Related Values (AQRVs) in the Class] Area? [[J Yes 0 No

d. If Yes, indicate tJ model used: 0 VISCREEN 0 PLUVUE II 0 CA'LPUFF DOther:4

e. Has the Federal JLd Manager concurred that the proposed project will not adversely impact any AQRVs?

II

DYes 0 No [[Yes, please attach correspondence.

II

II f the net emissions Increase of any pollutant is negative, enter "0."

21f the project did no~1 trigger a netting analysis, use the project increase. In this case, the value will be less than the . ifi II I I

pollutant's sigru icance eve.

3]n kilometers, II

4Model must be approved by LDEQ and the Federal Land Manager,

form 7195 rOO 06106/07

•

•

•

26. Environmental Assessment Statement (EAS or "IT" Question Responses)

II

ILa. R.S. 30:2018) DYes [8J No

** This section is required when applying for new Part 70 operating permits and/or major modifications. Any applications for thes~: permit types that do not include answers to these questions will not be considered to be administratively complete. **

For new Part 70 operaJLg permits and/or major modifications, answers to these questions must be provided by the applicant to the local g6vemmental authority and the designated public library at no additional costs to these entities. Consult instructions tolldetermine what is considered to be a "local governmental authority" and a "designated public library". Indicate the Jlame and address of the local governmental authority and the designated public library to which the

'I

answers to these questions were sent:

II

Name of Local Governing Authority Name of Designated Public Library
II
Street or P.O. Box Street or P.O. Box
II
City II State J ZIP City I State I ZIP Answer the fOllowinJI five questions on separate pages using full and complete answers. Include as many pages as necessary in order to 'provide full and complete answers. This information is required per Louisiana Revised Statutes 30:2018 (La. R.S. 30:2018). The Environmental Assessment has been provided in appendix K of this submittal.

Question I: Have th] potential and real adverse environmental effects of the proposed facility been avoided to the maximum extent posJible? (This question requires the permittee to identify adverse environmental effects, both potential

and real.) II . :

Question 2: Does a cost benefit analysis of the environmental impact costs balanced against the social and economic benefits of the propo~~d facility demonstrate that the latter outweighs the former? (This question requires the permittee to perform a cost-benefit analysis, or at least a quantitative indication of the economic benefits and a qualitative description of the negative impactMexp'ected from the permittee's operation. The latter should come from the answer to Question I.) .

Question 3, A,-, "Je alternative projects which would off" more protection '0 the environment than the proposed facility without undriiy curtailing non-environmental benefits? (This question requires the permittee to demonstrate having considered altel'nate technologies.)

Question 4: Are theJ alternative sites which would offer more protection to the environment than the proposed facility site without unduly cJrtailing non-environmental benefits? (This is the question that deals directly with siting criteria.)

Question 5, Ace .hJ mitigating mea sur es which would offer' mure protection '0 'he e nv iconmen' than the facility as proposed without unauly curtailing non-environmental benefits? (This question requires the permittee to demonstrate having considered the !lnost stringent techniques for reducing or more efficiently handling waste.)

form_7195_rOO 06/06/07

PART 70 OPERATING PERMIT APPLICATION COMPLETENESS CHECKLIST

fon~p)", this checklist and submit with the completed air permit application. ,
Instructions:
LAC 33:111. Com nletenf'ss Questions Relative to the Part 70 Permit Yes No NA Location Within
Application the Permit
Application
517.A Timely. Was a C~py of the Application Also Submitted to EPA? X
Submittal
517.B.I,2 Does thellApplication include a Certification by a Responsible X AAE - Section 10
Certification Official?;l
517.8.3 Does_~~~!~~~lication Include Certification by a Professional X AAE - Section 10
Certification . Enginee~or their Designee:
517.0.1 Identifying Does th,IAPPlication Include:
Infonnation
1. CI 11 Name, Physical and Mailing Address of Facility? X AAE - Section I, 2

2. Map ihowing Location of the Facility? X Appendix A
3. II X AAE - Section I
Own7r and Operator Names and Agent?
4. Nam~ and Telephone Number of Plant Manager or Contact? X AAE - Section II
,
517.D.2 SIC Codes, Does the Application Include a Description of the Source's X Introduction &
Source Categories n. and Products? Appendix A
• 'V'-<OM~
Does th~ Application Include the Source's SIC Code? X AAE - Section 5
Does t~~~ Application Include EPA Source Category of HAPs if X
applicable? .
517.D.3,6 E1Q Has an ~IQ Sheet been Completed for each E~ission Point X AAE - Section 24
Sheets whether an Area or Point Source?
517.D.4 Monitoring Does th~ Application Include Identification and Description of X AAE - Section 23
Devices Complia nee Monitoring Devices or Activities?
II
517.0.5 Revisions For Revisions or Modifications, Does the Application include a X Introduction
and Modifications I'
';P\;UlI of the Proposed Change and any Resulting Change in
Only .missions
517.0.7 General Does Application Include Information Regarding Fuels, Fuel X AAE - Section 24
lnformation Use, "Jt Materials, Production Rates, and Operating Schedules & Appendix C
as 1It::';t;~~"'Y to substantiate emission rates?
517 D.8 Operating Has Inf~rm,~t.i~,n, Regarding any Limitations on Source Operation X
Limitations or any Annlicable Work Practice Standards been Identified?
,
II
517.D.9 Are Em11ssion Calculations Provided? X Appendix C
Calculations
517.0.10 Does th~ Application Include a Citation and Description of X ME - Section 23
Regulatory Review "
Applicable Louisiana and Federal Air Quality Requirements and
aandar~s?
• form_7195_rOO ,
06/06/07 LAC 33:111.

Corribleteness Questions Relative to the Part 70 Permit

11 Application

Yes

No

NA

Location Within the Permit Application

7.0.11 Test Methods

517.E.l Additional Part 70 Requirements

517.0.12 Major Sources of TAPs

Has a D~~cription of or a Reference to Applicable Test Methods Used to Detennine Compliance with Standards been Provided?

"

Does the IAnnlic.lltion include Information Regarding the Comnlia Ice History of Sources Owned or Operated by the Applican" (per LAC 33.III.5III)?

x

x

AAE - Section 23

517.D.13 Major Sources of TAPs

Does thelApnlil'Mion include a Demonstration to show that the Source Meets all Applicable MACT and Ambient Air Standard Requirements?

x

517.D.14 PSD Sources Only

If Requi)~d by DEQ, Does the Application Include Information Regardi~~ the Ambient Air Impact for Criteria Pollutants as Required'for the Source Impact Analysis per LAC 33:I1I.509.K, Land M?

, "

x

517 D.15 PSD Sources Only

517.D.16,18

Has any ~dditionallnformation been Provided? X

"

If .ui ed by DEQ, Does the Application Include a Detailed

.6.~'11b;~n. !Air Analysis?

X

517.D.17 Fees

..... ddi [1UI .... 1 Part 70 Requirements

SI7.E.3 Additional Part 70 Requirements

517.E.4 Additional Part 70 Requirements

517.E.5 Additional Part 70 Requirements Acid Rain

•

form_7195_rOO 06/06/07

L.__ _

Has the Code been Identified? X

AAE - Section 5

Is the AJ.~lil Fee Included with the Application? X

Does thel Cen ,.. Statement Include a Description of the X

Ci .• , I Status of Each Emission Point in the Source with All

Annl;c.".lle Requirements?

..

Does th~jCertification Statement Include a Statement that the X

Source J,ill continue to Comply with All Applicable

Requirements with which the Source is in Compliance? .

"

Does thJ!Certification Statement Include a Statement that the X

Source J,ill, on a timely basis, meet All Applicable Requirements

that willj~ecome Effective During the Permit Term?

Are Applicable Requirements for which the Source is not in

Compli~~ce at the Time of Submittal?

x

AAE - Section IO

AAE - Section 10

AAE - Section 10

Does the Application include a Compliance Plan Schedule?

x

AAE - Appendix E

Does th~ Schedule Include Milestone Dates for which Significant Actions }vi II occur?

x

AAE - Appendix E

Does th~ Schedule Include Submittal Dates for Certified Progress Reports~

Is this Shurce Covered by the Federal Acid Rain Program?

x

X

AAE - Appendix E

Are the ~t:ljull"lIJ"JlL:S of LAC 33.1I1.517.E 1-4 included in the Acid Ra in Portion of the Compliance Plan?

X

LAC 33:111. Con nleteness Questions Relative to the Part 70 Permit Yes No NA Location Within
Application the Permit
Application
17.E.6 Additional Have any, Exemptions from any Applicable Requirements been X
Part 70 Reques!(\~? .
Requirements
Is the Li: and explanations Provided? X
517.E.7 Additional Does the IAnnli~:lIi()ll Include a Request for a Permit Shield? X
Part 70
Requirements
Does thel:Request List those Federally Applicable Requirements X
for which the Shield is Requested along with the Corresponding
Draft Peikit Terms and conditions which are Proposed to
Maintai~lCompliance?
517.E.8 Additional Does the: IAnnlication Identify and Reasonably Anticipated X
Part 70 Alternati ~e Operating Scenarios?
Requirements
DOeSj~h;~ IAn!"l;~M;,.,n include Sufficient Information to Develop X
permit ~nns and Conditions for Each Scenario, Including Source
Process'~ nd Emissions Data?
517.F Does thellApplication Include a Request for Non-Disclosure X
Confidentiality (Confid~htial it y)?
"
525.8. Minor Does the IAnnli~"';nn Include a Listing of New Requirements X AAE - Section 23
Permit R ""':II ltin: for the Change?
Modifications
Does the IAnnli~Mi"'n Include Certification by the Responsible X AA.E - Section 10
Official hat 'the Proposed Action Fits the Definition ofa Minor
I\A :C:. as per LAC 33:1II.525.A.

Does the Certification also Request that Minor Modification X AA.E - Section 10
Procedui ~s be Used?
Does the: IAnnli,..",;{)", for Part 70 Sources, Include the Owner's X
SIHH1estf i Draft Permit and Completed Forms for the Permitting
Authorit. to Use to Notify Affected States?
La. R.S. 30:2018- Has a co ?y of the answers to the questions posed in the . X
PSD/NNSR only Envir il Assessment Statement (Section 26) been sent to
the local Igoveming authority at no cost to the local governing
authority
Has a co ~y of the answers to the questions posed in the X
EhvJJV'u' = Assessment Statement (Section 26) been sent to
the rlesipl lalerl public library at no cost to the designated public
.~
library?
• form 7195 rOO
- -
06106107 •

ApPENDIX A

AREA MAP & PLOT PLAN

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II Murphy Oil USA, Jne.

Trinity Consultants

Mlurphy Oill USA .. Meraux Refinery Meraux, St. Bernard Parish, Louisiana Area Map - Scale- 1 :24,000

2'15

216 .217

UTM E.ast (NAD27) (km)

Trioity& Glnsultants

Chalmette, LA Quad~ang'le

3317

-

3316 E

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3313

219

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ApPENDlxB

INSIGNIFICANT ACTIVITES AND GCXVII ACTIVITIES

Murphy Oil &SA, Inc.

Trinity Consultants

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MURPHY OIL USA, INC.
MERAUX REFINERY
MERAUX, ST. BERNARD PARISH, LOUISIANA
General Condition XVII (GC XVII) Activities Emissions Summary
.
Type or Activity VOC PM .. NO, SOl CO H1S NHJ
II (tpy) (tpy) (tpy) (tpy) (tpy) (tpy) (tpy)
Carbon replacement II 0.14 2.5 3.5 0.04 0.02
Changing filters II 0.07
Cleaning of eguipment II 0.02
Clearing of pipelines II 0.47
COflll'I'essor maintenance 0.02
Draining compressor bottles 2.7
Instrument maintenance emissions 0.43
Miscellaneous f?quipmeni preparation 4.4
Nitrogen blowing of pipelines 0.06
Pump maintenance II 3.6
Sampling emissions II 0.15
Sludge removal emission's 1.95
Solids removal from sumps 0.24
Taking floating roof tankS out of service 1.9
Solids loading and unloading 1.45
Tank gauging II 0.076
Valve maintenance II 1.30
Portable waste tanks II 0.06
Taking fixed roof tanks out ofservice 0.30
Paints Usage II 2.9
Welding Operation II 0.04
Parts Washers Operations'l 1.3
,
,
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,
,
,
04058 GC XVII Emiss Calcs030107.xls· GC XVII Summary
31112007 •

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General Permit Condition XVII Activities Emissions Estimation Methodology

. The state at Louisiana requires that emissions from General Permit Condition XVII

Activities be q8antified in the Title V operating permit-application. General Permit Condition XVII activities prod~ce air emissions Which are associated with routine operations that are short term or intermittent lin nature, that are under control upon release, and that Occur on a predictable basis. The st~te ot Louisiana is allowing these emissions to be determined on a per activity basis. Using this approach, an emission factor is developed for each activity, (l.e, X pounds of pollutant eachillime activity Y is performed). Actual emissions are then determined by the number of times each activity is performed throughout the year. Therefore, an applicant must determine an ~mjssion factor and the frequency rate In order to quantify air emissions from

General permitl\condltiOn XVII activities. .

, MOUSt chose to develop emission factors using process knowledge. To determine the' frequency rate cif activity, interviews were conducted with Unit Supervisors and Area Maintenance Supervisors. Approximately seven Unit and Area Maintenance Supervisors along with various operations, engIneering. and maintenance personnel, were interviewed. A survey of activities that may resultln e~issions was prepared based on the i1ifarmation contained·in the General Permit, Condition XVII Activities 'section of IheState of Louisiana's Permit Procedures manual. ThIs· survey was therilsent out to all intended interviewees· for thelr review. Interviews were scheduled with each persbQ. During 'the interview, supervisors were asked about frequency rates of ' activities perfQrih;ed in their operating units. The supervisors were also asked to provide I in1ormation that ~ould be used to estimate typical emissions for the routine activities done In their

un~ ~ .

. After all lithe interviews were completed the information was assembled into data

notebooks for each area, Using the appropriate data and equations, emission taotors for each activity were cal~ulated. The emission factor for each activity was applied refinery-wide. The emission factors 'hnd frequency rates were assembled into a single Lotus 4.0 spreadsheet sorted by unit and a~ity. The spreadsheet calculates emissions for individual pollutants for each activity done in the unit as well as refinery wide. The frequency rates used in the spreadsheet are maximum y~brly values so the calculated emission rates represent the "potential to ernlt'. Actual emissionsl~cari be found by simply entering the actuaJ frequency rate for a parucular year. The spreadsheet 'Is setup so that new operating units, activities, emission factors, and pollutants

I'

can be easily added: ,

II

Report Organization

Section 1.0 desJibes the various non-routine activities carried out at the Meraux Refinery. Section 2.0 cont~ins tables which summarizes the emissions from non-routine activities. Table 1 shows the totaillemissions in tons per activity per year. Table 2 shows the emission factor in pounds per activitY. Table 3 shows the number of activities carried out in one calendar year. Section 3.0 sho~ the model calculations and states the basis for each calculation .

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Section 1.0 General Permii Condition XVII Activities

Actlvrty oeSCli1iPtiOnS

I .

The activities at the Meraux Refinery are discussed below.

Carbon Replacement or Recharging

Carbon CharCO~1 is used as a nller and as a catalyst When carbon Is recharged or replaced the liquid in the ve~sel is pumped to the process and then vessel is drained and purged to a flare. Carbon filters afie placed In a fitter dumpster and disposed of according to their disposaJ profile. The average arfjlount of carbon replaced Is 83,688 pounds .. Based on a pressure of 100 psig,

. approximately 4.78 pounds <?f ammonia (NH3) and 9.58 pounds of hydrogen sUlnde (H2S) are emitted to' the Ilatmosphere during carbon replacement on vessels containing sour water. Approximately 34.09 pounds of vae are emitted to the atmosphere during carbon replacement on vessels cont~19\ng hydrocarbons. Additionally, NH3, H2S, and VOCs 'undergo combUstion and oxidizes to term NOxj 502 and C02. The emission factors for the following pollutants are NOx-634.93 poJnds per activity, S02-883.90 pounds per activity and C024593.97 pounds per

activity. II !:

Changing Alter~:

Occasionally thJI filters and screen baskets that remove conlamlnants from tho process musl be replaced or de~r;ted. Alters can be on process equipment, such as pumps, or in filter vessels . Rlters maybe In light hydrocarbon, heavy hydrocarbon, amine, or sour water service. Attars on equipment, sUch' as pumps, are removed and drained. When a fitter vessel Is maintained the filter vessel is ertlptied, the old filters are removed, and the new filters are Installed. Used filters are placed in a [,Iter dumpster and disposed accordingly. Screen' baskets are removed and washed. It Is estimated that 90 percent of the liquid in the filter is purged to the process and 10 percent 01 the r~maining liquid In the fitter, is emitted to the atmosphere. Based on a filter, volume of 6.5 g~"ons, apprOximately 0.46 pounds of vac are emitted each time' a fitter is changed.

Cleaning EquIpment .

Tho cleaning 01 J,QUiPment OCCUrs as pari of equipment malnlenance and as a part of regular housekeeping. Equipment may be washed with soap and water or may be hydroblasted to remove accumul~ted hydrocarbons and dirt. EqUipment maybe washed In place as part of regular houseke~ping or washed at a deSignated deaning pad as part of equipment maintenance. 'EqLipment that Is cleaned Indudes the outsIde of pumps, fin fans, economizer, process vessels, ~istillation towers, and other process 'equipment. The hydrocarbon, and dirt are washed to ~e sewer and the oil Is recovered In the oil .. ~ater separator and slop oil. Assuming that 10 gal/ons of hydrocarbons are washed to the sewer each time a piece of equipment Is cle~ned, and that 5% of this vaporizes to the atmosphere, approXimately 0,48 pounds of vac a~e emitted each time a piece of equipment is cleaned,

Page 1

MiscellaneQu$ EquIpment Preparation

Throughout the )1ar various pieces of equipment must be shutdown and prepared for mechanical work. \!This involves blocking the piece of equipment in, purging it to the tlare or draining rt to the process sewer, and cleaning the piece ot .equiprnent, Equipment in this category includes Mbat exchangers, process heaters, process furnaces, and any other equipment 'excluding tanks, p&nps, and process vessels. Approximately 90% ot the liquid in the equipment is pumped to the IprocesS. Approximately 5% ot the remaining liquid vaporizes during the

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Clearing at Pipelines

I

The clearing of process piping is done when the pipe must be repaired or when equipment

maintenance isl to be done. The pipeline is blocked in and drained back to the process or purged to the flare. Any liquid remaining in the pipe is drained to the process sewer or removed utilizing a vacu~:m truck. The volu.me of the cleared lines was found assuming an average pipe diameter of 10 inches and a pipeline length ot 150 teet. Assuming that the line is tilled with vapor at 100 p~ig and 25° C and then purged to a flare with a 98% destruction efficiency · approximately 3t95 pounds of vac are emitted to the atmosphere during each line c1earin~ . activity.

Compressor Maintenance

Compressors ar! serviced on a routine basis to maIntain mechanical integrrty. Before beginning maintenance thellgases in the compressor are purged to the flare. The compressor Is then swept with nitrogen to [the flare to' ensure a clean atmosphere. It Is assumed that 96% at the vac vapors sent to t~l~ tlare are combusted. Assuming a volume of 100 tf', a pressure of 100 pslg, and an compressor temperature ot25·C, approximately 1.75 pounds ofVOC are emitted during

each compressa'f maintenance activity. '

ij ~' . , ,

Draining Compressor Bottles

Some compress~r;:; have bottles that must be drained at a certain intervals. Compressor bottles

If '

maybe purged t01lthe nare, to the blowdown system. or vented to the atmosphere. Uquid in the

bottles may be drained to the sewer. After purging, the compressor bottle may be swept with nitrogen to the atinosphere. Some compressor bottles drain several Urnes each hour? others

.11 . •

drain several Urnes throughout the day, and others are purged only a jew times each year. A

bottle size of 2 fe~t In diameter and 5 feet In height was assumed. Assuming a pressure of 100 psia, 'a temperature of 25°C, and a 98% destruction efficiency in the flare; approximately 0.76

pounds of VaG a~e emitted each time a compressor bottle Is drained. '

II

Instrument Maintenance

Throughout the YJ~. instruments which provide Information about the process must be repaired and calibrated. When an instrument Is repaired or replaced it is blocked in anddralnad to a drip pan. The liquid frl; the drip pan Is dispose,d of appropriately or recycled back.to the process. Approximately 35~78 pounds of liquid is drained from the instrument and lina, of which approximately 10%, or 3.58 los, vaporizes to the atmosphere during an instrument maintenance activity.

Page 2

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process or clearing the equipment to the process sewer. Assuming Ihat 'miscellaneous equipmenl' is fPproximated by an exchanger bundle, approximately 419.46 pounds or voe are emitted during each miscellaneous equipment preparation activity.

Nitrogen BloJing of PIpelines

II

The niirogen blowing of pipelines and equipment is associated with the clearing at pipelines. After a section ht pipe is cleared it may be blown with nitrogen to purge the line. The volume of the lines was ~estimated assuming an average pipe diameter of 10 inches and a pipeline length of 150 feet. Assuming that the line is filled with vapor at atmospheric pressure, at a temperature of 25· Co and t~lal it is purged to a flare with a 98% destruction efficiency, approximately 0.51 pounds ot VOl are emitted to the atmosphere during each nitrogen blowing activity.

Pump Maintenance

When a pump I~ malntalned ills blocked and Ihe liquid In Ihe casing is pumped back to Ihe process. Any liquid remaining in the casing is either drained to the process sewer for recovery if it is a heavy liquid or purged to the tlare tt it Is a fight liquid. The pump casing may then be steamed to the nare and then steamed 10 the atmosphere. Rnally the pump casing may be nitrogen purgedlltQ·the. ~tlJ1osphere. Atter t~e pump Is ~Iocked in and drained, th~ casing Is checked to mak~ sure It IS clear. Any remalmng material IS 'contalned and the pump IS removed 10r servicing. The pumps are taken to the maintenance shop were they are Cleaned and repaired. Pump ~sing sizes range from 4 gallons for mercaptan pumps to t 70 gallons for blend pumps. Based ~;m operator Interview the average pump casing size was assumed to be 50 ganons, It Is estimated that 80% a' the liquid In the casing ·Is pumped to the process. The remaining 20% ~I either drained to the sewer or purged to the flare. Of the 10 gallons going to the flare or sew'~r, only 10% Is not combusted by the flare or vaporizes from the sewer . Theretore, assu~ing an' API denstty 01 60.74 (gasoline), approximately 7.24 Ibs of VaG are emitted to the atrt'Josphere during each pump maintenance.

•

Sampling

Sampling is done Ifor process control and lor monitoring purposes. The sample tap is opened to purge the sample lines and to wash out the sample bottle. It is assumed that approximately 1000 ml of sampJ~ is used to purge sample lines and to wash the sample bottle. The bottle is then filled and cap,'ped. Samples are generally collected in 1000 ml bottles. It [s estimated that hatt, or 500 ml, of the sample purged to the sewer vaporizes to Ihe atmosphere during the collection processlJ This results In an emission of 0.B1 pounds of vac per sampling activity.

Sludge Removal

Sludge is removed from tanks and other equipment such as distillation towers When shutdown during unit tumaro~nds. This is usually done with a vacuum truck or manually depending on the nature at the sludgk. Sludge may also be removed from the bottom of tanks while in service using a vacuum ~ck The sludge is unloaded from vacuum _~cks to trae tanks for disposal profile or the sludd~ can be reprocessed. The sludge is normaily heavy hydrocarbons so it is estimated that onl~ 1 % at the sludge is emitted to the atmosphere during the removal and

,I

disposal process. An average tank diameter of 90 leet and an average sludge depth of 0.5 feet

Page 3

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were assumed. Based on these assumptions, rt is estimated thaI 1946.38 pounds of Vac are

srnrtted durin~ each sludge removal activity. ,

Solids LOadl~g and Unloading

Solids are IQa~ed and unloaded from trucks, rail cars, and barges. Solids that are loaded or unloaded jnd~de catalyst, coke, clay, salt, and lime. During the loading and uri/oading operations emissions of particulates are controlled to the greatest extent possible. It is estimated that 50 poundt, or particulates are emiffed during each loading and unloading operation. '

Solids Removal From Sumps

perj~dfcallY sulps must be drained and the solids that have accumulated in them must be removed. Thellaccumulated solids in the sump are removed with a vacuum truck and erther recycled back tp the process or disposed of appropriately. The solids can be stored in open trae tanks or in sealbd drums. It was assumed that one 1,000 gallon frae tank is fined during each: solid removal a~ivity and that approximately 1 % of the weight of the solids is emitted as vae vapors to the atllnosphere. Based on this. approximately 79.4 pounds of vae are emitted each . time solids are ~Ie. moved from a sump.

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TakIng Floating Roof Tanks Out of Service

Periodically, t1oJ~in~ roof tanks are taken out of service for inspection, to repair the floating roof .: and/or the tank\~a"s, to clean the tank, and to remove un accumulated sludge. Operations is : responsible for t?klng the tanks out of service. However, Maintenance removes the seals that anew the roof tal settle on the support legs. This is essential opening about 20 vents that are 3

I,

inches in dlarneter on the root of the tank and allowing the support legs to slide Into these

openings. This j;woi.Jld allow emissions until the tank has been completely drained. It was estimated that the vapors escaping through these openings exit at a rate of 0.1 mls and have

" J

a density at 0.848 Ib/tt. Uquid remaining in the tank is floated out with water to the slop

system. Assumi~g that it takes 8 hours to take a floating roof tank out of service, approximately 753.90 pounds of vac would be emitted each time a floating root tank is taken out of service.

Tanr, Gauging

Tanks are gauged to determine the liquid level in the tank. Tanks can be gauged by instruments which do not redn in air emissions or tanks can be gauged manually which does result in air emissions. ManJaJ tank gauging consists of uncovering an openi,ng on top of the tank and inserting a calibrai~d rod into the opening to measure the liquid level. The amount of emissions is related to the vdlatility of the liquid, the size of the opening, and the length of time the opening is uncovered. ThJI diameter of the opening was assumed to be 3 inches. The length of time the opening is uncov~red was assumed to be 5 minutes. Based on an ext! velocity of 0.1 m/sec and a vapor den~ttv 01 0.0808 Ib/ff, approximately 0.39 pounds at" VaG are emitted to the atmosphere durjn~ wash tank gauging activity .

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Valve Maintenance

II ' . ,

Throughout Ihe year Ihe valves that control the fiow process streams, such as block valves and control valve'1, must be repaired. When valve is repaired or replaced it is blocked in and drained to a drip parit The liquid in the drip pan is disposed of appropriately or recovered back 10 the process. As1kuming an average line size ot 12 inches, approximately 27 pounds of liquid are contained in ~ valve, of which only 10% vaporizes ~o the atmosphere., Therefore, approximately 2,7 Ibs of vac are emitted to the atmosphere dUring each valve maIntenance.

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