BAB VIII

Menentukan Dew Point dan Bubble Point

Komponen
CH4O

Fraksi mol
0.45

C2 H 6 O

0.25

C3 H 8 O

0.15

C4H10O

0.10

C5H12O

0.05

Data Fisis
Komponen

T dalam K, P dalam atm

Tetapan Antoine
A
B

CH4O

18.5874

3626.548

-34.280

C2 H 6 O

18.9118

3803.986

-41.670

C3 H 8 O

17.5439

3166.377

-80.140

C4H10O

17.2160

3137.019

-94.420

C5H12O

16.5270

3026.886

-104.990

DEW POINT
T Trial
Pt

=
=

P0

= ln P

KI
Xi

= P /Pt
= Yi/Ki

Komponen
CH4O

-7.7141 0C
1 atm

A-(B/(T+C))

Yi

P0

KI

Xi

0.45

17.9656

17.9656

0.0250

C2 H 6 O

0.25

6.6896

6.6896

0.0374

C3 H 8 O

0.15

1.5556

1.5556

0.0964

C4H10O

0.10

0.3187

0.3187

0.3138

C5H12O

0.05

0.0948

0.0948
=

0.5275
1.0001

BUBBLE POINT
T Trial
Pt

=
=

-36.6194 0C
1 atm

P0

= ln P

KI
Yi

= P0/Pt
= Xi*Ki

Komponen
CH4O

Xi

P0

A-(B/(T+C))

KI

Yi

0.45

1.9024

1.9024

0.8561

C2 H 6 O

0.25

0.5354

0.5354

0.1338

C3 H 8 O

0.15

0.0657

0.0657

0.0099

C4H10O

0.10

0.0076

0.0076

0.0008

C5H12O

0.05

0.0015

0.0015

0.0001
1.0006

Menentukan Dew Point dan Bubble Point

Komponen
CH4O

Fraksi mol
0.55

C2 H 6 O

0.2

C3 H 8 O

0.15

C4H10O

0.10

Data Fisis
Komponen
CH4O

B
T C

log P A

T dalam C, P dalam mmHg

Tetapan Antoine
A
B
6.74756

585.000

C2 H 6 O

6.8196

785.000

C3 H 8 O

6.8429

926.100

C4H10O

6.8465

1014.810

T Trial
Pt

=
=

-16.1077
1

P0

= log P

KI
Xi

= P0/Pt
= Yi/Ki

DEW POINT
265.2859 K

-(B/(T+C))

Komponen
CH4O

Yi

P0
0.55

19895.6431

C2 H 6 O

0.20

2628.7349

C3 H 8 O

0.15

508.7877

C4H10O

0.10

108.8997

=
=

-93.1041
1

BUBBLE POINT
236.3806 K

T Trial
Pt

-(B/(T+C))

P0

= log P

KI
Yi

= P0/Pt
= Xi*Ki

Komponen
CH4O

Xi

P0
0.55

1361.8409

C2 H 6 O

0.20

52.3297

C3 H 8 O

0.15

3.4549

C4H10O

0.10

0.1878

T C

g P A

Antoine
C
255.000
247.000
240.000
227.110

C
atm

=
=

A-(B/(T+C))

KI

Xi

26.1785

0.0210

3.4589

0.0578

0.6695

0.2241

0.1433

0.6979

C
atm
0

256.8923 K
760 mmHg

1.0008

179.8959 K
760 mmHg

A-(B/(T+C))

KI

Yi

1.7919

0.9855

0.0689

0.0138

0.0045

0.0007

0.0002

0.0000

1.0000

Menentukan Dew Point dan Bubble Point

Komponen

Fraksi mol

C2H4

0.55

CH4

0.25

o2

0.15

o2

0.05

Data Fisis
Komponen
CH4O

T dalam C, P dalam mmHg

Tetapan Antoine
A
B

6.74756

585.000

255.000

C2 H 6 O

6.8196

785.000

247.000

C3 H 8 O

6.8429

926.100

240.000

C4H10O

6.8465

1014.810

227.110

DEW POINT
T Trial
Pt

=
=

P0

= log P

KI
Xi

= P /Pt
= Yi/Ki

Komponen
CH4O

-16.1077 0C
1 atm

=
=

256.8923
760

A-(B/(T+C))

Yi

P0
0.55

KI

Xi

###

26.1785

0.0210

C2 H 6 O

0.25 2628.7349

3.4589

0.0723

C3 H 8 O

0.15

508.7877

0.6695

0.2241

C4H10O

0.05

108.8997

0.1433

0.3489

0.6663

BUBBLE POINT
T Trial
Pt

=
=

-93.1041 0C
1 atm

179.8959
760

P0

= log P

KI
Yi

= P0/Pt
= Xi*Ki

Komponen
CH4O

Xi

P0

A-(B/(T+C))

KI

Yi

0.55 1361.8409

1.7919

0.9855

C2 H 6 O

0.25

52.3297

0.0689

0.0172

C3 H 8 O

0.15

3.4549

0.0045

0.0007

C4H10O

0.05

0.1878

0.0002

0.0000

1.0035

K
mmHg

K
mmHg

no.1

Tentukan Dew Point dan Bubble Point

Komponen
Fraksi Mol
H2
0.35
O2
0.4
CH4

0.2

CO2

0.05

Data Fisis

ln p A

B
C log T DT ET 2
T

T dalam K, P dalam mmHg

Komponen

Tetapan Antoine
C

H2

3.4132

-4.1316E+01

1.0947E+00

O2

20.6695

-5.2697E+02

-6.7062E+00

CH4

14.6667

-5.7097E+02

-3.3373E+00

CO2

35.0169

-1.5119E+03

-1.1334E+01

DEW POINT
T Trial
Pt

=
=

71.4226 0C
760 mmHg

P0

= ln P

KI
Xi

= P /Pt
= Yi/Ki

Komponen

Yi

P0

KI

H2

0.35

1.4208E+10

1.8695E+07

O2

0.40

7.1856E+02

9.4548E-01

CH4

0.20

4.4383E+02

5.8399E-01

CO2

0.05

1.6204E+02

2.1321E-01
=

BUBBLE POINT
T Trial
Pt

=
=

P0

= ln P

KI
Yi

= P0/Pt
= Xi*Ki

Komponen

Xi

-148.2713 0C
760 mmHg
=

P0

KI

H2

0.35

2.0924E+03

2.75313E+00

O2

0.40

5.4644E+01

7.19003E-02

CH4

0.20

2.7055E+01

3.55988E-02

CO2

0.05

1.3557E+00

1.78379E-03
=

no.2

Menentukan Dew Point dan Bubble Point

Komponen
Fraksi Mol
C2 H 4
0.55

log T DT ET 2

CH4

0.25

H2 O

0.15

CO2

0.05

Data fisis

ntoine
D

Komponen

T dalam K,P dalam mmHg

A

1.4589E-04

C2 H 4

18.7964 -9.9962E+02

1.2926E-02 -9.8832E-13

CH4

14.6667 -5.7097E+02

2.1999E-09

1.3096E-05

H2 O

29.8605 -3.1522E+03

9.3368E-03

1.7136E-09

CO2

35.0169 -1.5119E+03

-6.6896E-10

DEW POINT
=

344.4226 K

A+B/T+CLOGT+DT+ET^2

Xi

T Trial
Pt

=
=

P0

= ln P

KI
Xi

= P0/Pt
= Yi/Ki

Komponen
H2

1.8722E-08

302.9190
760

Yi

P0

0.55

7.5210E+13

4.2307E-01

O2

0.25

6.6799E+03

3.4247E-01

CH4

0.15

1.2475E+02

2.3451E-01
1.0000E+00

CO2

0.05

6.5431E+02

BUBBLE POINT
=

124.7287 K

A+B/T+CLOGT+DT+ET^2

Yi

T Trial
Pt

=
=

P0

= ln P

KI
Yi

= P0/Pt
= Xi*Ki

Komponen

Xi

-221.5256
760

P0

9.63594E-01

H2

0.55

1.3825E+03

2.87601E-02

O2

0.25

1.2209E-01

7.11976E-03

CH4

0.15

8.8269E-20

8.91895E-05
9.99563E-01

CO2

0.05

1.7194E-06

ble Point

Tetapan Antoine
C

4.5788E+00

9.9746E-11 6.7880E-06

-3.3373E+00

2.1999E-09 1.3096E-05

-7.3037E+00

2.4247E-09 1.8090E-06

-1.1334E+01

9.3368E-03 1.7136E-09

C
mmHg

A+B/T+CLOGT+DT+ET^2

KI

575.9190 K

Xi

9.8961E+10

5.5577E-12

8.7893E+00

2.8444E-02

1.6415E-01

9.1382E-01

8.6093E-01
=

5.8077E-02
1.0003E+00

C
mmHg

A+B/T+CLOGT+DT+ET^2

KI

51.4744 K

Yi

1.81909E+00

1.00050E+00

1.60643E-04

4.01606E-05

1.16143E-22

1.74214E-23

2.26230E-09
=

1.13115E-10
1.00054E+00