N,, The M M N,, and M M

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The Pauli exclusion principle is the quantum mechanical principle that states that

two identical fermions (particles with half-integer spin) cannot occupy the same quantum
state simultaneously. In the case of electrons, it can be stated as follows: it is impossible for two
electrons of a poly-electron atom to have the same values of the four quantum numbers: n,
the principal quantum number, , the angular momentum quantum number, m, the magnetic
quantum number, and ms, the spin quantum number. For two electrons residing in the
same orbital, n, , and m are the same, so ms, the spin, must be different, and thus the electrons
have opposite half-integer spins, 1/2 and -1/2. This principle was formulated by Austrian
physicist Wolfgang Pauli in 1925.
A more rigorous statement is that the total wave function for two
identical fermions is antisymmetric with respect to exchange of the particles. This means that the
wave function changes its sign if the space and spin co-ordinates of any two particles are
interchanged.
Particles with an integer spin, or bosons, are not subject to the Pauli exclusion principle: any number
of identical bosons can occupy the same quantum state, as with, for instance, photons produced by
a laser and BoseEinstein condensate.

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