KIMIA FISIKA HIDROCARBON

NAMA KELOMPOK : 1. ANDRI RAHMAT W 1401151

2. ILHAM RIFALDI 1401200
3. VALENTINUS DIMAS 1401194

1. For the gas composition given in the following text, determine apparent molecular weight, spesific
gravity, pseudo-critical pressure, pseudo critical temperature of gas

Mole Fraction ( Apparent Molecular

Component ( YiMi )
Yi ) Weight ( Mi )
C1 0.775 16.043 12.43333
C2 0.083 30.070 2.49581
C3 0.021 44.097 0.926037
i-C4 0.006 58.124 0.348744
n-C4 0.002 58.124 0.116248
i-C5 0.003 72.151 0.216453
n-C5 0.008 72.151 0.577208
C6 0.001 86.178 0.086178
C7 0.001 100.205 0.100205
N2 0.050 28.013 1.40065
CO2 0.030 44.010 1.3203
H2S 0.020 34.076 0.68152
𝑌𝑖 = 1 𝑀𝑖 = 643.242 𝑌𝑖𝑀𝑖 = 20.70268

𝑌𝑖𝑀𝑖 20.70268
𝑆𝑝𝑒𝑠𝑖𝑓𝑖𝑐 𝐺𝑟𝑎𝑣𝑖𝑡𝑦 = = = 0.713886
29 29

Mole Fraction ( Apparent Molecular

Component ( Pci ) ( Tci ) ( YiTci ) ( YiPci )
Yi ) Weight ( Mi )
C1 0.775 16.043 666.4 343.33 266.08075 516.46
C2 0.083 30.070 706.5 549.92 45.64336 58.6395
C3 0.021 44.097 616.0 666.06 13.98726 12.936
i-C4 0.006 58.124 527.9 734.48 4.40688 3.1674
n-C4 0.002 58.124 550.8 765.62 1.53124 1.1016
i-C5 0.003 72.151 490.4 828.63 2.48589 1.4712
n-C5 0.008 72.151 488.6 848.8 6.7904 3.9088
C6 0.001 86.178 436.9 913.60 0.9136 0.4369
C7 0.001 100.205 398.8 972.7 0.9727 0.3988
N2 0.050 28.013 493.1 227.49 11.3745 24.655
CO2 0.030 44.010 1071 547.91 16.4373 32.13
H2S 0.020 34.076 1300 672.45 13.449 26
 𝑌𝑖𝑇𝑐𝑖 = 384. 07288°𝑅 𝑌𝑖𝑃𝑐𝑖 = 681.3052 𝑃𝑠𝑖𝑎

𝑇𝑝𝑐 = 384.07288 °𝑅 𝑃𝑝𝑐 = 681.3052 𝑝𝑠𝑖𝑎

2. After you determine Ppc and Tpc, Determine Pseudo-Reduce Pressure and Pseudo-Reduce
Temperature . After that find gas compressibility Factor using Standing Kartz Correlation and Beggs
Brill Correlation. ( Standing Kartz Chart is attached )

Known : 𝑇𝑖 = 213℉ + 460 = 673°𝑅

𝑃𝑖 = 3250 𝑝𝑠𝑖𝑎
𝑇𝑝𝑐 = 384.07288 °𝑅
𝑃𝑝𝑐 = 681.3052 𝑝𝑠𝑖𝑎

Answer : 𝑃𝑖 𝑇𝑖
𝑃𝑝𝑟 = 𝑇𝑝𝑟 =
𝑃𝑝𝑐 𝑇𝑝𝑐
3250 𝑝𝑠𝑖𝑎 673 °𝑅
= =
681.3052 𝑝𝑠𝑖𝑎 384.07288 °𝑅
= 4.77 = 1.75
Beggs Brill Correlation

𝐴 = 1.39(𝑇𝑝𝑟 − 0.92)0.5 −0.36𝑇𝑝𝑟 − 0.10

= 1.39(1.75 − 0.92)0.5 −0.36 1.75 − 0.10
= 1.39(0.83)0.5 −0.63 − 0.10
= 1.39 0.911043358 − 0.63 − 0.10
= 1.266350268 − 0,63 − 0.10
= 0.536350268

𝐸 = 9(𝑇𝑝𝑟 − 1)
= 9(1.75 − 1)
= 9(0.75)
= 6.75

0.066 0.32𝑃𝑝𝑟 6
𝐵 = 0.62 − 0.23𝑇𝑝𝑟 𝑃𝑝𝑟 + − 0.037 𝑃𝑝𝑟 2 +
𝑇𝑝𝑟 − 0.86 10𝐸
0.066 2
0.32(4.77)6
= 0.62 − 0.23(1.75) 4.77 + − 0.037 4.77 +
1.75 − 0.86 106.75
0.066 0.32(4.77)6
= 0.62 − 0.23(1.75) 4.77 + − 0.037 4.772 +
1.75 − 0.86 106.75
= 1.037475 + 0.845436408 + 0.000670286
= 1.883581694

𝐶 = 0.132 − 0.32 𝑙𝑜𝑔 𝑇𝑝𝑟

= 0.132 − 0.32 𝑙𝑜𝑔 1.75
= 0.132 − 0.32 0.243038049
= 0.132 − 0.077772176
= 0.054227824

𝐹 = 0.3106 − 0.49𝑇𝑝𝑟 + 0.1824𝑇𝑝𝑟 2

2
= 0.3106 − 0.49 1.75 + 0.1824 1.75
= 0.3106 − 0.8575 + 0.5586
= 0.0117

𝐷 = 10𝐹
= 100.0117
= 1.027306415
 1−𝐴
𝑍 =𝐴+ + 𝐶𝑃𝑝𝑟 𝐷
𝑒𝐵
1 − 0.536350268
= 0.536350268 + + 0.054227824 (4.77)1
2.7181.88
= 0.536350268 + 0.070762154 + 0.25866672

= 0.865779142
= 0.87 𝐷𝑖𝑏𝑢𝑙𝑎𝑡𝑘𝑎𝑛