LAMPIRAN PERHITUNGAN

1. Diketahui : gram NaOH

Ditanya

= 0,71 gram

MrNaOH

= 40 gram/mol

Cp air

= 75,291 joule/mol.k

T1

= 304 K

T2

= 313 K

: S :..?
H :.....?

Jawab

: mol NaOH =

S = mol NaOH x Cpair x ln

= 0,01775 x 75,291 x ln

313
304

= 1,35 x ln 1,029
= 1,35 x 0,029
= 0,03915 J/K
H = (-S) . T2
= -0,03915 X 313
= -12,25 J

Diketahui : gram KNO3

Ditanya

= 0,71 gram

Mr KNO3

= 101 gram/mol

Cp air

= 75,291 joule/mol.k

T2

= 301 K

T1

= 304 K

:S..?
H..?

Jawab :S = mol KNO3 x Cpair x ln

0,71
40

= 0,01775 mol

x 75,291 x ln

0,71
101

301
304

= 0,007x 75,291 x ln 0,99

= 0,527 x (-0,010)
= -0,00527 J/K
H

=(-S) . T2
= - (-0,00527) . 301
= 1,58627 J

2. Diketahui

Ditanya

: gram Mg

= 0,71 gram

Ar Mg

= 24

Cpair

= 75,291 Joule/mol.k

MHCl

= 0,25 M

T2

= 308 K

T1

= 304 K

: S :?
H :?

Jawab : Reaksi

Mg(s)

2HCl (aq)

MgCl2 (s) +

Mula-mula: 0,030

0,00125

Reaksi :

0,000625

0,00125

0,000625

Sisa

0,029375

0,000625

= mol MgCl2 x Cpair x ln

= 0,000625 x 75,291 x ln

= 0,047 x ln 1,013
= 0,047 x 0,0129
= 0,00061 J/K
H

= (-S) . T2
= ( -0,00061) . 308

308
304

H2 (g)

= - 0,18788 J

3. Diketahui

: gram Ba(OH)2

= 0,149 gram

Mr Ba(OH)2

= 171 gram/mol

Mol Ba(OH)2

= 0,00087 mol

Gram NH4Cl

=0,78 gram

Mr NH4Cl

= 53,5 gram/mol

Mol NH4Cl

= 0,015 mol

T2

= 302 K

T1

= 304 K

Cpair
Ditanya

: S Dan H?

Jawab : Reaksi

= 75,291 Joule/mol.k

Ba(OH)2 (s) + 2NH4Cl (s)

Mula-mula:

0,00087

0,003

Reaksi :

0,00087

0,00174

0,00087

Sisa

0,00126

0,00087

= mol BaCl2 x Cpair x ln

= 0,00087 x 75,291 x ln

= 0,065 x ( -0,010)
= -0,00065 J/K
H

BaCl2 (s) + 2NH3 (g) + 2H2O (l)

= (-S) . T2
= -(-0,00065). 302
= 0,1963 J

302
304