054

2.1 (Amines)

(Classification of Amines)

(Amines)(NH3)

(1)(primary (1) amine)

(2) (secondary (2) amine)

(3)(tertiary (3) amine)

054

054

(Classification of Amines)

(Line-Bond Formulas for Amines)

055

055

2.1

2.1

055

056

(Naming Amines)

(Naming Amines)

ditri

IUPAC
eamine()

056
056

(Naming Amines)

(Naming Amines)

N-

NH2 (amino
group)

(diamine)

056
058

(Aromatic Amines)

2.2

(aniline)
IUPAC

a.
(ethylamine)

058

2.2

058

2.2 (Properties of Amines)

b.
(trimethylamine)
c.
N--N-(Nethyl-N-methylaniline)

NH

N--1-

059

061

2.2 (Properties of Amines)

(Solubility in Water)
()

061

061

2.3

(Solubility in Water)

(3)
(37)

NH
()NH

061

061

2.3

(Amines React as Bases)

(NH3)(
) (Br nsted-Lowry base)
(H+) (NH4+)
(OH )

CH3CH2NH2

061

062

(Basicity of Amines)

(Ionization of an Amine in Water)

(dialkyl ammoniumions)
K10-3

062

062

(Basicity of Amines)

(Amine Salts)

(amine
salt)

062

063

(Amine Salts)

(Amine Salts)

(quaternary ammonium
ion)

063

064

(Properties of Amine Salts)

(Properties of Amine Salts)

064

(Properties of Amine Salts)

(NaOH)

064

2.3
(Heterocyclic Amines and Alkaloids)

(heterocyclic amine)

(pyrrolidine)

(Pyrrole)

(Imidazole)

064

067

2.3

2.5

(Heterocyclic Amines and Alkaloids)

(pyridine)

(pyrimidine)

(purine)

a.
b.

067

067

2.5

(Alkaloids: Amines in Plants)

(alkaloids)

(coniine)

068

068

(Alkaloids: Amines in Plants)

(Alkaloids: Amines in Plants)

(atropine)

069

068

(Alkaloids: Amines in Plants)

(Alkaloids: Amines in Plants)

(heroin)

070

069

2.6

2.4 (Amides)

(amides)

()

070

072

2.7

(Preparation of Amides)
(amidation)

072

072

2.7

2.7

a.
OH H

073

073

(Naming Amides)

(Naming Amides)

IUPAC(IUPAC
)ic acidoic acid
amide

N-N,N-

073

073

2.8

2.8

b. N-(N-ethyl)
N--2-(N-ethyl-2chloropropanamide) (IUPAC) N---
(N-ethyl--chloropropion-amide) ()

IUPAC

N,N---

a. IUPAC(propanoic acid)
(propionic acid)oic
acidic acid amide IUPAC
(propanamide)
(propionamide)

074

074

(Physical Properties of Amides)

(Physical Properties of Amides)

NH2

074

074

2.5

2.5

(Hydrolysis of Amides)

(Hydrolysis of Amides)

(hydrolysis)

077

2.9

N-NaOH

()
()

N-HBr

078

078