Exp 17

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48 PHYSICAL CHEMISTRY PRACTICAL ‘Table 2: Standardisation of NaOH solution by standard oxalic acid solution [No.of | ~ Vol. of Burec reading, | Vol. of NaOH | Mean vol. of | Strength of | titrations | oxalic acid Tnitial Final required NaOH soln. | NaOH Soln solution (ot) ml) ol) con) wo H 10.0 00 2 10.0 | . 3 10.0 | ‘Table 3; Titration of saturated benzoic acid solutions at different temperatures against standard NaOH solution ‘Temp. ‘Vol of Sard. Burette reading Vol of NaOH | Strength of ben- ec) benzoic acid [~~ Initial soln. required} zoie acid soln. solution (nd) (mt S (marl) 50 10.0 00 40 + 100 | 35 100 . ' 25 100 ‘Table 4: Results for solubility curve and AH of the solution Temp. ‘Solubility Loss| T 1 eo s (K) 7 (mol) | 50 m8 40 . ; 33 | 35 wos | 2s a . 298 4 Results: From the graph of log S vs. ‘ AH = ~Slope x 2.303R ki/mol. Conclusion Solubility curve: From the nature of graph. itis seen that solubility of benz decreases) with temperature . ‘AH; Since the value of AH is (+ve/-ve), hence the process of dissolution of benzoic acid in water is {epothermic/exothermic) ‘oi acid in water (inoreases/ J iment 2 {> Determination of the heat of solution of oxalic acid at its saturati “different temperatures. jon from the solubility measurements at TONIC EQUILIBRIA 49. Theory: Solubility of a substance is defined as the number of gram of the substance required to sae co? Btams of a solvent through dissolution ata particular temperature. This definition Ie ves solubility a unit less quantity. However. solubility may also be expressed in molality unit, which comes from the above definition. TF

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