48 PHYSICAL CHEMISTRY PRACTICAL
‘Table 2: Standardisation of NaOH solution by standard oxalic acid solution
[No.of | ~ Vol. of Burec reading, | Vol. of NaOH | Mean vol. of | Strength of
| titrations | oxalic acid Tnitial Final required NaOH soln. | NaOH Soln
solution (ot) ml) ol) con) wo
H 10.0 00
2 10.0 | .
3 10.0 |
‘Table 3; Titration of saturated benzoic acid solutions at different temperatures against standard
NaOH solution
‘Temp. ‘Vol of Sard. Burette reading Vol of NaOH | Strength of ben-
ec) benzoic acid [~~ Initial soln. required} zoie acid soln.
solution (nd) (mt S (marl)
50 10.0 00
40 + 100 |
35 100 . '
25 100
‘Table 4: Results for solubility curve and AH of the solution
Temp. ‘Solubility Loss| T 1
eo s (K) 7
(mol) |
50 m8
40 . ; 33 |
35 wos |
2s a . 298 4
Results: From the graph of log S vs. ‘
AH = ~Slope x 2.303R
ki/mol.
Conclusion
Solubility curve: From the nature of graph. itis seen that solubility of benz
decreases) with temperature .
‘AH; Since the value of AH is (+ve/-ve), hence the process of dissolution of benzoic acid in water
is {epothermic/exothermic)
‘oi acid in water (inoreases/
J iment 2 {>
Determination of the heat of solution of oxalic acid at its saturati
“different temperatures.
jon from the solubility measurements atTONIC EQUILIBRIA 49.
Theory: Solubility of a substance is defined as the number of gram of the substance required to
sae co? Btams of a solvent through dissolution ata particular temperature. This definition Ie ves
solubility a unit less quantity.
However. solubility may also be expressed in molality unit, which comes from the above definition.
TF