Ist Semester 2008-2009 CHL121- Chemical Engineering Thermodynamics — Major Test Time: 120 min, Max. Marks-60 (to be scaled down to 30) 1. One mole of oxygen andfour moles of nitrogen gas, both initially at 25°C and 1 bar are mixed together. The final pressure of the mixture is also 1 dar. fa) Determine total change in entropy and Gibbs free energy due to mixing, (b) Represent A G for oxygen and for nitrogen graphically, G in terms of () InPand (ii) frap (446) +4}. vi An equimolar liquid solution of benzene and toluene is contained in a piston: cylinder arrangement. It is heated at a constant pressure of 1 bar, ‘The initial temperature is 25°C. (a) Show that the first bubble of vapours will be formed at about 91.5%C. Also determine the composition of this bubble. (b) Also show that the mixture solution will completely evaporate at about'98.5°C, (©) Show (x1,y3) for (a) and (b) above In T-x:-Vs diagram, (44444) - Methanol (1) and water (2) form @ non-ideal solution. At 60%C,\the vapour! bal liquid equilibrium (VLE) data are given below: PckPa) x vy 48.852 0.3039 0.6943 pétermine achuntycenetficients for methanol and water, G" (yolar excess Gibbs energy) and G) mien» (4tatasa) ee = 4. Partial molarVolumes of methanol anid water for 30. mole % metharol solution Heir pure-species volumes both at 25°C are Methane! (1) Vo =)38.632 on’ mot! ¥, 40.727 em’ mol | Water (2) 29.765 cn mol” 18.068 om? mol’ Determine volumes of pure water and pure methanol required to obtain one titer of 30% mathanol solution (6) EB (a) Fora pur component at saturation conditions, {v'-) ap= = (s aT Show that aH" =7 (¥"-v') (ap Jar) “ Jb) Estimate the latent heat of vaporization of water at 50°C, and compare it with the reported value 2382.9 k] kg? Data: tT kPa ve ve V" and VY in cm’g 49°C 1174 1.012 12620 50°C 12.34 1.012 12050 51°C 12.96 1.013 11500 JO Determine the values of V' and VY at 50°C end compare those with the above given values. (44444) Note : Useful data on reverse.4 Revere) Vignal Ct) Predeedtos of pare comprnanlt eu) Nene) Bematne orca 6a Tolusrne e162. 548 Vethard asch £1006 babe 4S SD (iw) Vapi ea CR Carte A rg.ecal Tolaune ) 1h: 0048 Met owel 16-5938 Wage 16-2620 Bing ne Ge) Racket’ competetion ¢ V ®) Pokgue covrelakion Picbary Hoag hy.o4 Bo-47 ano a 18S 70 3 les 3,44 0 3,149-89 oho Bre 0-083- 16 Ze Y, ced [omeh) o-21 194-0 626k 31G@-0 ot2h s18-° 0-324 5&4 my SC, € paeeed 214-19 234-26 226-35 0 28ST t eo -| ve zl ) Cas ow ° 1B zl Oyu BIE I d 1M.