CAU HOI Li THUYET VE HOA HOC HUU CO’ THPT Vai sue “giao heu” va sding tao trong nhitng ném gan déy, cdc cdu hoi li theyét hitu co trong dé thi thit DH ngay cing gay ra nhiing khé khan khing nho voi cc si tie. Khéng con chi kiém tra cdc kién thiee co ban va noi bat, cic dé thi gio day bit déu tim dén mang kién thie mé hoc sinh cling nue gido vién it quan tém truéc déy nhue céu tric phan tir, tinh chat vat li, diéu kign phan ing, mg dung thuc té,... Diéu dé dai hoi hoc sinh hon bao gic hét phai doc ki va thyc sv hiéu cdc tri thitc diege cung cdp trong sdch gido khoa THPT dé khong bj be ngé trude cae edu hoi trong dé thi. (lemongrass.31.08@gmail.com) PHAN 2. DAP AN ‘(CAu 1. Cho so dé chuyén héa sau: Benzen + etilen "> X —22"_5 y_8*0._ hon hop ZH khi' T Vay khi Ta A.CO2 B.CH, C.hdn hyp CO: val; D. CéHsCOOH (Cau 2. Cho CHsBr phan img véi NHs, sn pham tao ra amin la A. CHsNHz B. (CHs):NH C. (CHs)sN D. hn hgp CHsNHa, (CH3)2NH, (CH3)sN (Cau 3. Cho so dé chuyén héa sau: Crt, 9 x, 2g x, [|| sy, TE XS] society y. Trong so dé trén, Xs la: ‘A. Caosu cloropren B. Cao su Buna C. Cao su thign nhién D. (-CHs-CH=CH-CHa-CHz-CCICH-CH-)y CAu 4, Phan tir nao sau day 6 g6e CCC 06 dé len xp xi 90"? A. Xiclopropan B. Propen C. Xiclobutan D. Propan Cu 5. Chon nhin dinh diing dudi day. A. Hidrocacbon no Ii hidrocacbon khong ¢6 phan ting eng them hidro. B. Hidrocacbon no 1a hidrocacbon ma trong phin tir chi c6 C lai héa sp", C. Do chi c6 lién két o, ankan trong 46i hoat déng héa hoe. D, Phan irng flo héa C,Hyo tao ra 4 loai din xudt mono khde nhau. Céiu 6. Cho cic chit sau: Bro, HBr, A.2 Bl phan ung v6i xiclohexan la: D.4 ‘Cfu 7. Trong s6 cic hidrocacbon cé ti khdi so véi Hy bing 20, thi sé Iugng chat lim mat mau dung dich thude tim la, Al B.2 a2 D4(Cu 8, Phan img nao sau diy tao ra HBr? (1) Benzen + Bry > (3) CH=CHBr + KOH 2 (5) CH; -OCH, +Br > A. CK2)(3 4), B. C24) Ciiu 9, Hidrocacbon X 06 CTPT Ii C;2Hio, khéng kim mat mau dung dich KMnOs 6 nhiét a9 thong va (2) Xiclopentan + Bry ——> (4) CH}CH=CHCH;Br + HO —> C.(IQ)BKS) D.()GB\4) hi dun néng. Cho X phan ting véi HNOs/H:SO, thu due sin phim C)sHeNOs. $6 lugng chat C)2HyNO> 66 thé tgo ra la: AL B.2 Cfu 10. Cho so dé chuyén héa sau: ca D4 ‘Cumen %"* > C,H, Br 22" > C, Hy, "> X(C, HB) Vay chat X 1a: A, L-brom-2-phenylpropen C. p-bromisopropenylbenzen Cu 11. Cho so dé chuyén héa sau: B. 3-brom-2-phenylpropen D, o-bromisopropenylbenzen CH,OH+CO—*\> X(duy nhat) HA" 5 yHseunnrwe , 720,180.60, yg Vay chit M la: A. CoH B. CHs-CHs C. CHxCHO D. CH;COOGHs (Cau 12. Chuyén héa hidrocacbon X (CsHio) theo so dé sau: X22 C1,0, 2! 50,140, Vay chat X la: A. Naphtalen Cfiu 13. Hidrocacbon X eé ki B. o-Xilen C. Dimetylbenzen D. Etylbenzen Iugng mol bing 100 gam, khi phan img véi clo tao ra hn hop gom 3 dong phan monoclo cia X. $é lugng hgp chat thoa man tinh chat trén cua X 1a: A2 B.3 C4 DS Cfu 14. Khi 6 vong benzen di c6 sin nhém thé day electron cing manh thi phan img vao vong cang dé xiy ra, Trong s6 ede nhém ~CHs, ~OH, -NHz, ~OCHs, nhém nio diy electron yéu nhit? A.-NH> B.-CHy Cfiu 18. Cho eée phan img sau: (1) Gala + KMn0, > (3) CH;COOC(CHs)(C)CH:CI + NaOH ——> (5) CHsCLCH:-CCI + NaOH —> ‘Sé phan img tao ra ancol hode axit da chite li: A.2 BA Cf 16. Cho ede phin img cong sau diy: 1) CH=CH: + HCI 3) CH:CH-CHe + HI > Phan img xay ra dé dang nhat la phan img: A) B.Q) C.-OH D.-OCH; (2) Benzen-1,2-diamin + HNO, —*° (4) Tripanmitin + NaOH — (6) 3-clopropen + H>O “> 2) CH: 4) CH2=CH2 + HBr > c.@) Dd.) Cau héi Ii thuyét vé héa hoc hitu co 2012 ‘emonGrass.31.08@Gmall.com — Trang 2/14Cu 17. Cho ede nhiin din sau: (1) Phan tmg céng Hp vio anken la phiin ting toa nhiét, (2) Tron hex-2-en long vai nude brom, lic ki rdi dé yén thi mau vang cam ciia dung dich bj nhat di. (3) Aken cong nude ludn tgo it nhit 2 ancol. (4) Suc etilen vao dung dich thudc tim thay xuat hign két tua den. (5) Trong phong thi nghiém, etilen duge diéu ché tir etanol. han dinh ding ta: AS B.3 c.2 D4 ‘Cu 18. Cho day bién héa: Cumen 9X —H80.20% yy HHO 7 HOE ny Biét M lam mat mau dung dich nue brom. Vay M la: A. phenol B. axit metaerylic . isopropenylbenzen 1D. axit-2-hidroxylisobutirie ‘Cfiu 19, Hop chat X 6 cng thie cau tao nhu sau: 4CH, ~CH = CH ~CH, ~CH, ~CH =C(Cl)-CH,+, Hay cho biét qua trinh diéu ché chat X tir axetilen (cdc chat v6 co céin thiét c6 dit) phai trai qua it nhdt bao mhiéu giai doan: A.2 B.3 C4 DS (Cfiu 20. Khi dun néng mdi chat toluen, stiren, phenol, anilin vi dung dich KMnO, dae thi c6 phan tmg héa hoe xay ra véi A. toluen B. toluen va stiren CC, toluen, stiren va phenol D, cdi 4 chat toluen, stiren, phenol va anilin Céu 21. Hop chit X khong no mach hé c6 c6ng thie phan tir CsHsOz, khi tham gia phan img xa phong héa thu duge 1 andehit vi 1 mudi cia axit hitu co. Cé bao nhiéu céng thite edu tao pha: hgp voi X (khong ké ding phan cis, trans)? A2 B.3 C4 DS Cau 22. Cho cic chat long hoc dung dich sau: phenol, anilin, natri phenolat, axit axetic, kali axetat, S6 dung dich lam di mau phenolphtalein li A2 B3 C4 D.S Cu 23. Cho anilin tic dung véi nude brom duge két tia A. Cho A tie dung véi HNO> ban diu 6 0°C ~ 5°C, sau d6 dun néng nhe duge két tia B, Vay B I A. Axit picrie B. Mudiciia A voi HNO: —C.2,4,6-tribromphenol—D. ai Cfu 24, Chat A chia C,H, O, mach hi c6 nguén géc tir thye vat va thuong gip trong doi séng. Khi liy cing sé mol cia A cho phan img hét voi NaxCO hoae véi Na thi ti 1¢ sé mol CO; va sé mol H; thu duge tuong ting 1a 3:4, Biét A c6 khdi long mol phan tir i 192 gam va chi chita cde nhom chite phin img v6i Na. Tén goi ciia A 66 thé la: A. axit laurie (trong qua dira) B. axit tactarie (trong qua nho) C. axit malic (trong qua tio) D. axit xitrie (trong qua chanh) CAu 25, Chon nhin xét sai? A. Cac chat hiru co c6 % s6 mol trong hén hyp bing % khdi lugng trong hdn hop dé duoc goi la dng phan eta nhaw, Cau hei lithuyét v8 héa hoc hitu co 2012 LemonGrass,31,08@Gmail.com — Trang 3/14B. Gée lign két HCH trong phan tir C:Hy < CHy < CoH. ‘6 3 céich biéu dign céng thite cau tao cua hgp chat hiru co, ién két ha hoe trong phan tir hop chat khi chu yéu a lién két cOng héa tri. ‘Cfiu 26. Cho cae chat sau: CHjOH, C)HsOH, CHsCHO, C2H2, C2Ha, CsHio, CH}COONa, CHjCN. SO 6 thé tao duge CH;COOH chi bang 1 phan img la: AB B.S c4 D.6 (Cf 27. Chon nhin xét ding. A. Nhiing quy tim vio dung dich axit a-aminoaxetic thay quy tim 46i miu. B. Cac aminoaxit la hgp chat hiru co nén nhigt 46 néng chay tuong doi thip. C. Khi cho a-aminoaxetic tic dung vii C2HsOH (xt: HCI khi) thu duge CI HyN°CH:COOC2Hs. D. c-aminoenantoic 1a nguyén ligu dé sin xudt to nilon-6. (Cfu 28. Chon nbn xét ding. A. Nhigt d s6i etia CHs;COOC:IIs < CHsCHCH2COON < CIis[CUz]sCHZO1. B. Gidng nhur xa phong, chit giat rita tong hgp khong thé gift rim trong nude eimg. C. Ngay nay xa phong con duge san xudt tir ankan. D. MG bj Gi Ia do lign két C-C cita gc axit béo bj oxi hoa chim b6i oxi trong khong Khi. ‘Cfiu 29. Cho so dé phan img: CH, i ye, yr sca y _ emee y Biét cdc chit trong so dé trén déu mach hé va c6 sé C nhw nhau. Phat biéu ndo sau day khong ding’ A. Xa khdng e6 kha niing tham gia phan ting tring hep. B. X; téc dung duge véi Na va giai phong Ho. C. X, cng voi HO (xt H’) thu duge san pham chinh la propan-2-ol. D. Khi thity phan chat béo ta luén thu duge Xs. ‘CAu 30. Chon nhiin xét ding? A. Trong dung dich, andehit c6 ca lién két hido lién phan tir va lién két hidro véi nude, xeton chi cé lién &t hidro voi nuse. B. Day sip xép theo chiéu gidm dan nhiét d6 s6i tir trai sang phai la: n-hexan > isohexan > neohexan. C. Thity phan khong hodn toan n-peptit e6 thé thu duge (n-2) tripeptit. D. Benzen ¢6 mii thom nhe nén durge goi li hidrocacbon thom. ‘Cafu 31. Chon nhin xét diing. A. Khi dun néng hén hop gdm C:HsBr, KOH, C:HsOH thi khong c6 khi thoat ra, B. Trir etin, cdc ankin ¢6 lién két = dau mach khi phan img voi AgNOs/NH; thi khdi hrgng phan tir thay doi 107 dv. C. Khi dun hén hgp C)HsOH va axit HBr dén khi két thiie phan img ta duge dung dich déng nhit. D. Cae ancol CsHs0H, CH:CH3CH;OH, CH;CH;CH:CH,OH tan v6 han trong murdc. (Cu 32. Hop chét Cottiy khi tie dung véi clo c6 chiéu sing tao ra hdn hop 2 efit déng phan CeffisCt. Neu thay 2 nguyén tir H cia Coy, trén bang 2 nguyén tir clo sé tgo ra hn hgp gém sé lugng dong phan la: AA BS C6 D.7 =CHBr; HOOC-CH=CH- Céiu 33. Cho cite chit sau: CHy=CH-CHy-CHs; CHs-CH=C(C:Hs)-CHs; CICH: (CHs; (CH3):C=CH-CHs; CHBr=CH-CHy, 6 dong phan hinh hoc la: A2 B3 C4 D.S Cau hei lithuyét v8 héa hoc hitu co 2012 LemonGrass.31,08@Gmail.com — Trang 4/14C4u 34, Khi thue hign phin img tich nude di véi rugu X, chi thu duge 1 anken duy nbdt, Oxi héa hoan oan lugng chit X thu duge 5,6 lit CO» (dktc) va 5,4 gam nude. C6 bao nhiéu e6ng thire céu tao phit hyp vsi Xx: Ad B3 C4 DS ‘Cu 35. Cho naphtalen tic dung véi brom c6 Fe xic tac. Sé lugng din xuat monobromnaphtalen thu duge ki: Al B.2 c.3 D4 Cf 36, Dé dét chiy hoan to’n 1 mol ancol X no, da chire, mach hé o6 kha nding héa toan Cu(OH); edn mot Iugng vita di 5,5 mol O2, S6 cng thite cau tao théa man diéu kign ca X la: A.6 B.S C3 D.4 Cfu 37. Hop chat hitu eo X mg véi céng thire phéin tir CsHiO2N2. Cho X vao dung dich NaOH dun néng thiy tao ra NHs. Mat khée khi X tic dung voi dung dich HC! tao ra hn hgp sin phim trong 6 ¢6 mudi cia aminoaxit. $6 CTCT théa man diéu A3 B4 cl D.2 Cf 38. Khing dinh khong ding vé chat béo la A. Chat béo la trieste cia glixerol vii axit béo. B. Dun chit béo v6i dung dich NaOH thi thu duge sin phim e6 kha nding hoa tan Cu(OH),, C. Chat béo va dau mé béi tron mdy cé cing thanh phan nguyén t6. D. Chat béo nhe hon nuée. cotia X as ‘Cau 39, Hop chat hitu co X c6 CTPT CsHsBrs. Khi dun néng X voi dung dich NaOH dur tao sin pham hiru co cé kha nang tham gia phan img trang bac. $6 CTCT théa man diéu kign cia X la: Al B3 C4 D.2 Cfu 40. DHV). Khi dun néng stiren v6i dung dich KMnO, rdi axit héa thi thu durge axit hifu eo X. Sye khi etilen vao dung dich KMnO, thu duge ancol da chire Y. Thyc hign phan img este héa gitta X va Y thu duge este Z khOng 6 kha ning tic dung voi Na. Cong thie phan tir ca Z ta A. CigHsOu, B. CioHi202 C. CygHsOs D. CoHoOs Cfu 41. Cho cic chit: phenol, anilin, axit glutamic, axetilen, dimetylamin, axit axetic, axit acrylic, vinyl axetat. Sé lugng cae chat tac dung duge voi HCI la: A.6 B.4 Gs DS ‘Cfu 42. Axit cacboxylic X mach cacbon phan nhanh va c6 kha nang lam mat mau dung dich KMnOy. X c6 tn goi li: A. axit metacrylic B. axit acrylic C. axit fomic D. axit isobutylic ‘Cau 43. Cho phan img X + aH, —““->CH, ~CH, —CH, -OH . Biét rang X mach ha, a la 86 lién ket x cia X. Sé CTCT thoa man digu kign cia X la: A2 B3 C4 D.S (Cfiu 44, Nhin xét nio sau day khdng ding vé glucozo? A. Lén men glucozo chi thu duge CHsOH va CO>. B. Vong 6 canh cia glucozo e6 duge la do phan img eng cha nhém -OH & Cs vao lién két C=O cha hom chite andehit. C. Glucozo 06 thé tao este chita 5 gc CHsCOO trong phan tir khi tham gia phan img v6i anhidrit axetic e6 mit piridin. D, Glucozo tac dung duge voi Ho (xti¢ tée Ni, dun néng), Cu(OH)s, dung dich AgNOs trong NH. Cau héi Ii thuyét v8 héa hac hitu co 2012 LemonGrass 31,08@Gmail.com ~ Trang 5/14Cu 45. Trong cdc chit sau: amoniac, hidroflorua, metylamin, ancol etylic, axit axetic, axeton, axetandehit, phin ti ciia nd €6 thé co glixerol, etylclorua, tristearin. Cé bao nhiéu chat trong cic chat trén ma gitra céic lién két hidro? A.6. B.S. C4 D.8. Cau 46, Trong nhiing chat sau: C:Hz, CsHe, CH}OH, HCHO, CH, CHsCOOH e6 bao nhiéu chat durge sinh ra tir CHy biing mot phan tn Al G2; D4. Cu 47. Hai hyp chat hitu co mach hé ¢6 céng thite phén tir lan lugt la CzHsO3N2 va C3H;O2N déu téc dung: voi dung dich NaH dun néng, cho hai amin don chiie bae 1 thodt ra, Nhgn xét ndo sau day diing vé hai hop chat hitu co trén? A. Ching déu tac dung véi dung dich brom, B. Chiang déu 1a chat ludmg tinh. C. Phin tir cia ching déu e6 lién két ion, D. Ching déu téc dung véi Ha (xe tie Cau 48. Phit biéu nio sau day khng ding A. Chat git rira téng hop rira t vét ban bam trén vai, da,...do lim giam stre cing bé mat cua cic chit ban. B, Chat gigt ria tong hop c6 thé git rita cd trong nude cig, C. Thinh phin chinh cia chét gige rira tong hgp thugng 12 natri lauryl sunfat hoge natri dodeeylbenzen- sunfonat D. Cae logi bét gift phd bién hign nay déu c6 thinh phin chinh la hin hgp mudi natri hodc kali cua axit i, dun néng). 8 Cfiu 49, Nhiing nbn xét ndo trong cée nbn xét sau Li ding? (1) Metyl-, dimetyl-, trimetyl- va etylamin 1a nhiing chit khi mii khai kh6 chiu, dc (2) Cac amin déng ding cia metylamin cé d6 tan trong nuée giam dan theo chiéu ting cia ki phan tt, (3) Anilin ¢6 tinh baz va kim xanh quy (4) Lye bazo cua ede amin ludn én hon le bazo cia amoniac. A. (1), 2). B. (2), (3), (4). C. (1), 2), @). D. (1), (2), (4). Cfu 0. Khi tich nue cia glixerol 6 digu kign thich hop thu duge hyp chat hitu co X e6 cng thire CsH,O. Nhan xét nao sau day khéng ding vé X? A. Cé phan ing véi brom trong dung méi nucée B. Cong HCI theo quy tée eng Maccopnhicop. C. Cé phan ting tring hop. D. Cé phan tg tring bac. éi lugng Am. (Céu 51. Phat biéu sai la A. Nuc ép tir qua chanh khdng hoa tan duge CaCO, B. Gidm an lam quy tim hod 40. C. Chit tay mau lam sach ede vét bin nhér nhimng phan img hoa hoe. D. Léng tring trimg gap Cu(OH); tgo thanh hgp chat c6 mau tim. (Cau $2. Khang dinh cing la A. Toluen kim mat mau dung dich thudc tim ngay 6 nhiét 46 thuong. B. Etylamin khdng c6 ign két hidro tién phan tr C. Fomandehit c6 thé tham gia phin img tring hyp. D, Lue axit ciia o-nitrophenol manh hon luc axit eiia m-nitrophenol Cau hoi li thuyét vé héa hoc hitu co 2012 LemonGrass.31.08@Gmail.com - Trang 6/14Cau $3. Phat bidu dhing li A. Sé déng phan cdu tao mach hé, bén va tham gia phan img trang bac img voi cng thite B. Cc axit cacboxylic no, don chire, mach hé déu khéng kim mat mau nuée brom. C. Cie andehit no, mach hi déu c6 phan img e6ng hyp voi nude brom, D, Axeton khong tao duge lién két hidro yéi nude. PH4Oe la 3. (Cau 54, bt chiy hodn toan 0,1 mol hidrocacbon X, thu duye 0,4 mol COs va 0,4 mol HO. X kin # dung dich brom. $6 céng thite edu tg0 (khéng ké dng phan hinh hoc) thoa man diéu kign trén ctia X AL2. B.S. C4. D.3. Cfiu 55. Cho cde dng phin mach nhanh cua penten tac dung v6i nude thi tao thanh san pham chinh gom: A. Hai nirgu bac 2 B. Hai rurgu bie 3. C, Hai rugu bac 2 va mét rugu bic 3. D. M6t rugu bac 2 va mot rugu bie 3. ‘Cfiu 56. Dot chay cdc rugu trong cing mét day dng ding thi ti 1é sé mol H2O : CO> tang din khi sé nguyén tir cacbon ting, H6i chiing cé theé nim & day ding ding nao? A, Rugu no don chire B. Rugu khong no C. Rugu thom D. Rugu no da chite ‘Cf $7. Thity phan hoan ton | tetrapeptit X thu duge 2 mol Gly, | mol Ala, 1 mol Vé tao cata peptit X la A.10 B.24 C8 D.12 |. $6 ding phan céiu ‘Cfiu 58. M6t hidrocacbon A cé céng thie la (CsHs)s, khong lim mat mau dung dich brom. S6 lién két o vi 6 lién két x trong mét phan tir A tuong tg 1a: A. 18 va3 BIT va3 C.i7vad D.18 vad Cfiu 59. Phit biéu nao sau diy khdng diing? A. Metyl a-glucozit khong thé chuyén sang dang mach hé duge. B. Cé thé phan biét glucoza va fructozo bing dung dich brom. C. Cé thé phan biét glucozo va fructozo bing phan img trang guong. D. Glucozo va Fructozo la ding phan cia nhau. (Cu 60. Cho phurong trinh sau: C\H,CH=CH, +KMnO, +H,SO, > C,H,COOH + CO, + MnSO, +K,SO, +H,0 ‘Téng hé s6 nguyén, t6i gin ciia cdc chat tham gia phan img khi cn bang la: AI8 B14 eis D.21 Cfu 61. Cho céc chat sau: isopren, stiren, xilen, axetilen, caprolactam, xiclohexan, xenlulozo. C6 bao nhiéu chat khong cé kha nang tham gia phan img tring hop. Al Ba C2 D.3 Cu 62. Hop chit hitu eo X e6 Ong thie phiin tir CHsO:Ch. Khi thay phan X trong moi trudng kiém thu duge nhiéu sin phim, trong 46 6 ha tao phi hop v6i X li AS B.2 Cia D3 ft c6 kha ning tham gia phan dng tring guong. $6 cdng thite edu Cfu 63. Trong cic phin tir polime: tinh bét (amilozo) (1); xenluloze (2); tinh bot (amilopectin) (3); poli(vinyl clorua) (4); nhya phenolfomandehit (5); nhing phan tt polime ¢6 edu tao mach thing la: A. (3), (4) va (2) B. (2), (4) va(5) C. (2), 3) va (4) D. (1), (4) va (2) Cfiu 64, Dau m6 dé lau bj 6i thiu li do: ‘A. Chit béo bj pln hy thal ee andehit &6 mdi kh ehju, Cau héi Ii thuyét v8 héa hac hitu co 2012 LemonGrass 31,08@Gmail.com ~ Trang 7/14B. Chat béo bj thiy phan voi nude trong khong khi. C. Chat béo bj hidro hoa. D. Chat béo bj oxi héa cham boi oxi khong Khi, ‘Cfiu 65. Chat nao sau day duge ding lam thuéc né khong khoi: A. Xenlulozo triaxetat, B. Glicogen. C. Sobitol. D. Xenlulozo trinitrat, ‘Cfiu 66. C6 4 chat hitu co ki: CHsCOOH (1); C:HsOH (2); CeHsOH (3); CICHs-COOH (4). Thir tur ede chat trén theo chiéu gidm dan tinh axit tir trai qua phai la: A.Q),3).4),) B.(1), 4), @), 2) C.(4), (1,8), @) D.2),G),(4),() ‘Cfiu 67. Nhan xét no sau day khong ding? A. Brom tham gia phan ting véi ankan wu tién thé yao Cacbon bac cao. B. Khong thé tao ra dn xuat iot cia hidrocacbon bing cfc cho iot phan ting v6i ankan, C. Propan tic dung véi elo theo tiI¢ 1:1 thu duge sin phim chinh n-propylelorua, D. Benzylclorua dé thiy phan hon so véi metylclorua, (Cf 68. Nguyén nhan ndo sau day gay ra tinh bazo cua amin? A. Do phan tir amin bj phan eve. B. Do amin dé tan trong nue. C. Do amin 6 kha nding téc dung voi axit. D. Do nguyén tir nite cén ep electron ty do. ‘Cfiu 69. Trong thyc té, phenol duge ding dé san xudt cac chat trong day: A. poli(phenol fomandehit), chat digt c6 2.4-D va axit picric. B. nhya poli(vinylclorua), nhya novolac va chit diét c6 2,4-D C. nhua rezol, nhya rezit va thude tri siu 666 D. nhya rezit, chat digt c6 2,4-D va thude nd TNT. ‘Cau 70, Chat hiru co X thinh phan chita C, H, Cl trong dé clo chiém 71,72% vé khdi lugng. Chit X 6 sé dng phan mach ho lit A.2 B.3 C4 D.S (CA 71. Cho ba chat hiru co mach ha: CoH (X), C3Hy (Y), CH (Z). Nhain xét nao sau day ding? ALX, Y,Z la ding ding ké B. Ba chit trén khong thé la dng diing ciia nhau. C.X va la dong Z 06 thé ciing day dong. D. Ba chit trén c6 thé cing day déng ding hodc khdng phai 1 déng dang cua nhau. ‘Cfiu 72. Chat 3-MCPD thudng Lin trong nude tuong va cé thé giy ung thu. Chat nay A, CH(OH)2-CH-CH,Cl B. CH,OH-CHCI-CH2OH C. CH; CHCLCH(OH): D. CH:Cl-CHOH-CH.OH ‘Cu 73. Anken diéu kién thudng 6 thé khi, khi c6ng HBr chi thu duge mét sin pham duy nhat cé: ALL chat B. 2 chat C.3 chat D.4 chat ‘Cfu 74. Oxi héa hoan toan ancol sec butylic bing CuO nung néng, thu duge chit hitu co X. Tén goi cua X is A.etyl metyl xeton —_B. 2-metylpropanal C. dimetyl xeton D. metyl propanon Cau hei lithuyét v8 héa hoc hitu co 2012 LemonGrass.31,08@Gmail.com - Trang 8/14C4u 75. Khi oxi hoa nugu etylic bing dung dich KMnO, thu duge mot két ta mau nau den, phan ding nhur sau: KMnO, + C:HsOH — CH3COOK + ... ‘Sau khi can bang phuong trinh tng cac hé sé nguyén tdi gidin 1a: ALI B.19 €.22 D.20 CAu 76, Trong cdc cong thire phan tir sau: CsHyOs, CyHsO2, CsHyO2, CsH¢Os, CsHyO2, CoH02. $6 chit 66 dng phan este la: AB BS 4 D.6 Cau 77. Hn hgp g6m hidrocacbon X va oxi cé ti Ig sé mol tuong img la 1:10. Dot chiy hoan toan hén hop trén thu duge hon hop Khi Y. Cho Y qua dung dich H»SOs die thu duge hin hop Khi Z ¢6 ti kh6i v6i hidro baing 19. Sé dng phin céu tao cia X e6 kha ning lim mat mau dung dich brom li: AS B.6 C4 D.3 Cfiu 78, X 06 c6ng thire phin tit CsH)20sN2, khi cho X téc dung véi dung dich NaOH dur, dun néng thi phan hoi thu duge mét chat hit co no, don chite, bée 1, mach hé va phan rin chi chira chit v6 co. $6 céng thire cu tgo phu hyp X la: Ad B.S C7 D.10 Céu 79. Triglixerit la este ba ln este ciia glixerol. Khi dun néng glixerol v6i hdn hop 4 axit CisHs)COOH, (CipHasCOOH, Cy7Hs;COOH vai CiHy;COOH thi thu duge t6i da bao nhiéu triglixerit? A.40 B.27 C.48 D.54 (Cu 80. Ba hidrocacbon X, Y, X ké tiép nhau trong cing day ding dang, khOi lnong phan tr cia Z gap d6i khdi hrong phan tir ctia X. Khi cho cée déng phén cdu tao cia ba chit nay cng HBr, sé déng phan céu too cchi sinh ra mt sn phim duy nit Li A3 B.2 ca DS Cfu 81. To nilon-6,6 gidng nhur ec logi to thude logi poliamit Khae, duge sit dung rng rdi trong nbiéu Tinh ‘vue cita dii song vi ching 06 dic tinh: A. bén voi mdi truéng kiém B. bén voi méi truing axit C. 66 d6 ben co hoc cao D. bén voi nhigt Cfu 82. Khi dun néng glixerol véi chat xic tic thich hgp né téch nude dé tao thanh sin phim hi co. Ti khdi cia X so véi hidro la 28. Tén goi ciia X la: A. propenal B. propinol C. propenol D. propenon ‘Cfu 83. DSPs. Cho propin tic dung vai dung dich KMnO, sau khi phan img xay ra hoan toan, sin phim thu duge gbm: A. CHCOOK, KHCOs, MnOs, HO B, CH}COOH, CO», KOH, Mn0s, HO C. CHsCOOK, K2COs, KOH, MnO», HO. D. CH\COOK, K:COs, KHCOs, MnO, HO (Cfiu 84, Vai cong thie CsHsO, s6 dong phin cau tao, mach ho, lim mat mau dung dich brom 6 diéu kign thudmg Li: AT B.6 ca DS ‘Cfu 85. Mét andehit no, mach hé A e6 cng thire (CH;O)p. Tir A diéu ché caosubuna tdi thiéu qua A.3 phan img B.4 phin img C.2 phan ting D. 5 phan img Cfiu 86. X 1 hop chat thom cé céng thie phan tir C7HsO> tic dung véi dung dich Br tao ra duge din xuat tribrom. X tée dung voi dung dich NaOH theo t1@ mol 1:1. $6 déng phn X bi: Cau héi Ii thuyét v8 héa hac hitu co 2012 LemonGrass 31,08@Gmail.com — Trang 9/14Ad B.S C6 D.2 CAu 87. Nhgn dinh nao sau day khng ding? A. Phin tit mantoze do 2 géc a-glucozo lién két véi nhau qua nguyén tir oxi, géc thir nhat 6 C;, géc thir hai 6 C(C1-O-Cs) B. Phan tir saccarozo do 2 gdc a~glucozo va B-fructozo lién két voi nhau qua nguyén tir oxi, géc o~ glucoze 6 C), gbe P-fiuctoza & CC-O-Cy) C. Tinh bét 6 2 loai lién két a-[1,4]}-glicozit va a-[1,6}-glicozit D. Xenlulozo c6 cdc lién két B-[1,4]}-glicozit ‘CA 88. Chon phat biéu ding. A. Hidrocacbon C;Hon ¢6 3n— I lién két 6 trong I phan ti. B. Cac andehit no, don chttc, mach hé phan tng véi brom trong nude tao thinh axit cacboxylic. C. Tritetilen, cde anken mach thing e6 ndi doi ¢ C2 tae dung voi HBr déu tgo 3 ding phan. D. Cae déng phin este cia CsHsO2 déu phan img voi NaOH theo ti Ig mol 1:2 Cfu 89. Cho cde polime sau: PE (1), PVC (2), cao su buna (3), poli isopren (4), amiloze (5), amilopectin (6), xenlulozo (7), cao su Iuu ho’ (8), nhya rezit (9). Cie polime 6 cau trie Midng phan nhdinh li A. 1,2,3,4,6,7. B. 1,3,4,5,8. C.12,4,68. D. 1,2,3,4,5,7. Cfiu 90, CNH). Trong c: it : propen (1) ; 2-metylbut-2-en(II) ; 3,4-dimetylhex-3-en(III) ; 3-cloprop-1- en(IV) ; 1,2-dicloeten (V), chat nao c6 déng phan hinh hge : AJAY B.1, 11, IL IV CULV DLV Cfu 91. Nhan dinh nao sau day khéng ding? A. Axeton khong Lim mat miu dung dich KMnO, 6 digu kign thuring. B. Cac xeton khi cho phan img véi Hp déu sinh ra ancol bic 2. C. Trit axetilen, cic ankin khi cong nude déu cho sin phim chinh la xeton, D. Cac hgp chat c6 chira nhém ~CH=O cé thé phan tg hodc khéng phan img véi dung dich Bra. Cfiu 92. C6 cac nh§n xét sau: 1- Chat béo thuge loai chat este. 2- To nilon, to capron, to enang déu diéu ché bing phan img tring ngung. 3- Vinyl axetat khong diéu ché duge truc tip tir axit va ancol twong tng. 4- Nitro benzen phan tmg vii HNO; da (xtc tac H2SO, dac) tao thanh m-dinitrobenzen. 5- Phenyl amoni clorua phan tng véi nude brom dir tao thanh (2,4,6-tribromphenyl) amoni clorua. Nhiing cau ching la: A.1,3,4. B. 2, 3,4. C. Tat ca. D.1,2,4, 5. Cfu 93. Cho ce chit sau: axetilen, axit oxalic, axit acrylic, fomandehit, phenyl fomat, vinyl axetilen, glucézo, andehit axetic, metyl axetat, sacearoza, natri fomat, axeton, $6 chat ¢6 thé tham gia phan img tring gurong la A6 B8 C7 Ds Cfiu 94. Cho cae phan img: a) HBr + C)HsOH — b) CHy + Br: > c) CzHy + HBr —> d) GH, + Bry 5h) CoH> + 2HBr > 9) GoH,Br; + Mg > 'Sé phan img tao ra ety! bromua la Ad B.2 c3 mt ‘Cu 95. Cho ede phat biéu sau: Cau héi Ii thuyét v8 héa hac hitu co 2012 LemonGrass.31,08@Gmail,com ~ Trang 10/14a) Chat béo la trieste ctia glixerol vGi cdc axit monocacboxylic cé sé chin nguyén tir cacbon, mach ccacbon dai khong phan nln, b) Lipit gdm chat béo, sap, steroit, photpholi ©) Chit béo la ede chat long d) Chat béo chita chi yéu cde gée khong no cita axit béo thudng la chat long 6 nhigt 6 phong va duge goi La dau ) Phan ing thay phan chat béo trong m6i trréng kiém 1a phan tng thudn nghich g) Chat béo la thanh phin chinh cita diu, mo déng thye vat Nhiing phat biéu diing la Ac, de B.a,b, de C.a,b, d, g D.a,b,e Cfiu 96. Cho cée nhin dinh sau: a) Sacearozo va glucozo déu cé phan ing trang bac b) Co thé ding chi Cu(OH)» dé nhan biét ede lo mat nhan chita Glixerol, Glucozo, Fructozo, Etanal ©) Trong sor dd digu ché: Xentulozo—“°"_5 xs", y_BOMOsWE 7 Vay 1a divinyl 4) G dang mgch he, glucozo e6 § nhém -OH canh nhau ©) Trong phan tir amilopectin, ce ge a-glucozo lién két vii nhau béi cic glicozit g) Xenlulozo c6 cdu tric mach phan nhanh. h) Nho dung dich H,SO, dae vio vai soi bong, vai bi den va thing ngay do phin ing H:SO, oxi hoa tinh bot (Ce nhdn dinh ding 1a Acde B.aboh Cdeh D.bdeg Cf 97. Cho amin X tée dung v6i CHsI thu duge amin Y bée Ill e6 eéng thite phan tir i CsHisN. Hay cho biét X c6 bao nhiéu cng thie edu tao? AS B.3 C2 D4 én ket a-1,4- va -1,6- Cau 98. $6. idrocacbon 6 thé Khi c6 thé téc dung durge véi dung dich AgNOs trong NH li: A2 Bd C3 DS Ciu 99, Cho cic chit sau: divinyl, toluen, etilen, xiclopropan, stiren, vinylaxctilen, propilen, benzen. Sé chat lam mat mau dung dich KMnOy & nhiét 46 thurng 1a: Ad B.5. C.7. D.6 Céu 100. X e6 cng thire phan tir i CsHsCh. Thily phan X trong dung dich NaOH dun néng thu durge chit hitu co Y ¢6 kha ning téc dung véi Cu(OH):. Hay cho biét X ¢6 bao nhigu cng thire edu tgo théa man tinh cchat trén? AB B.S @2 D4 Cfiu 101, Nhjin xét nio sau day khdng ding? A. To poliamit kém bén trong cic méi trudng axit va bazo. B. Khi cho fomandehit dur tde dung v6i phenol, c6 bazo xite tac thu durge nhura novolac. C, Saccarozo khong tao két tia khi cho vao dung dich AgNO; trong NH D, To xenlulozo axetat thude loai to héa hoc Cfiu 102. Cac chat déu khéng bj thuy phan trong dung dich H2SO, loang, néng 1a A. poli (vinyl axetat); polietilen, cao su buna B. to capron; nilon-6,6, polietylen ilon-6,6; poli(etylen-terephtalat); polistiren D. polietilen; cao su buna; polistiren Cau hei lithuyét v8 héa hoc hitu co 2012 LemonGrass.31.08@Gmail.com—Trang 11/14CAu 103. Cho cée chat sau: CHsCOOCH;CHSCI, CIHsN-CH;COOH, CHCl (thom), HCOOCsHs (thom), CéHsCOOCHS (thom), HO-CsHy-CH:OH (thom), CHsCCh, CHsCOO(CI)>-CHs, HCOOC«HACI (thom). Co bao nhiéu chat khi tac dung voi NaOH dac du, & nhiét dO va ap suat cao tao ra san phim cé chira 2 mi AS B4 C6 D.7 CAu 104. So sinh tinh bazo eiia cée chét sau: (1) Natri axetat; (2) Natri phenolat; (3) Natri etylat; (4) Natri hidroxit: A.Q<(N<4. (8) Axit no da chire e6 cdng thire don gidn la (C3H,Os). Cong thite edu tgo phit hgp v6i edng thire nay 1a CH(COOH) -CH(COOH)-CH(COOH), 86 phat biéu diing la Cau hoi li thuyét vé héa hoc hitu co 2012 kemonGrass.31.08 @Gmail.com - Trang 12/14AS B.4 C6 D.2 Cafu 111. Tir etilen va benzen, chat vo co va diéu kign phan img c6 dit. Tong s6 phan tig it nhat dé c6 thé digu ché duge polibutadien, polistiren, poli (butadien - stiren), poli (vinyl clorua) li: AOI B.12 c.13 D.10 ‘CAu 112. Cho céc phat biéu sau: (a) Thye hign phan img este hoa gitta butan-1,2-4-triol va hén hop axit axetic, axit fomie trieste t6i da thu durge 1a 8. (b) Dé digu ché CH;CH:-C(OH)(C2H.)CHs ta e6 thé diing anken thich hp 1 3-ctylbut-2en. (c) Taco thé diing it nhat 4 phan tng dé tir nhm cacbua diéu ché but-I,3-dien. (4) Ta c6 thé diing it nhit 2 phan ting dé téch anilin khoi hén hop anilin, benzen, phenol. (e) Ta ¢6 thé ding nude brom hoge dung dich thudc tim dé nhin biét propilen hoc xiclopropan hat bigu diing li: A.2 B3 C4 DS Cfiu 112. Cho day chit: Cg, CHa, CHa, CoHo, CyHe, CoHsOH. $6 chat trong day bing m6t phan tng trye tip tao ra CoHsCl la: A3 B.2 cl D4 ‘Cfu 113, Nhan dinh nao sau day sai: A. Ban chat cau tao cia sgi bing la xenlulozo. B, Ban chat cu tao héa hoe cia te nilon la poliamit. C. Quiin éo nilon, len, to tim nén duge gigt vai xa phing ¢6 46 kiém cao. D. Cée nhan djnh khée déu ding. CA 114, Cho cée chit: C,H,OH, CH,COOH, C,H,OH, C,H,ONa, CH,COONa, C,H,ONa, H;0,HICI, Cu(OH), .CH, nhau li: A. 10 B.9 cil D.12. ‘Cfiu 115, Cho cdc phat biéu: (a) Este cia glixerol vi axit béo duge goi la chit béo (b) Chit béo cd tn goi chung Ia glixer (©) Tripanmitin cdn 6 t8n goi khéc 1a tripanmitoylglixerol (d) Chat béo la thanh phan chinh cua dau mé d9ng thye vat (€) Xa phing li mudi natri hoge kali ctia axit béo (®) Phan ing cia chat béo véi dung dich kiém duge goi la phan tg xa phong hod (g) Glixerol tan v6 han trong nude (h) Diu ma bj 6i do phan img hidro hod cic adc axit béo khong no 6 phit biéu khdng ding trong cde phat biéu trén 1d: AQ Ba as Ds 'H -CH,,. Trong s6 cae cp chat duge tao tir cée chat tén, sO cp chat phin img voi Cau 116. Cho cae phat biéu sau (a) Thude trir situ 666 duge san x ing phan img thé clo vao phan tir benzen. (b) Benzen bj oxi héa bai thude tim 6 80-100°C. (c) Etylbenzen duge diu ché bing phan ting gitta etilen va benzen. (d) C6 thé nhan biét benzen bing phan img véi hn hyp HNOs die va H:SO, dm dic tgo chat hitu co mau vang, mii hanh nbn, (e) Benzen o6 thé hoa tan duge brom, iot, Iuu huynh. Cau hei lithuyét v8 héa hoc hitu co 2012 LemonGrass.31.08@Gmail.com Trang 13/14(f) Benzen ¢6 miti thom nhe, nhung ¢6 hai cho site khoe. (g) Sau nguyén tir C trong benzen déu lai héa sp’. phat bigu ding 6 trén la: AB B4 C6 DS (Cf 117. Cho eée nh§n dink sau vé dn xuat halogen: (0) RG ol tbs ard yb, ta gt Cas pray eat URN SE the. (b) Cac din xuat halogen CH3I, CCl, CI CHC; 6 thé long trong diéu kign thuong, (c) Lign két trong phan tir dan xuat halogen khéng phan cye nén ching hau nhu kh6ng tan trong nude. (@) Ankyl halogenua khdng phan ting véi nude & mhigt 46 thutmg eding nhur khi dun si (e) Dun s6i dung dich gm C)HsBr va KOH trong rugu etylic, rdi dan san phim qua dung dich brom thi xuit hign céc gigt chat long khéng tan trong nude. (f) CCls duge ding kim dung méi vi ching hoa tan duge nhieu hgp chat phan cye va khong phan eye. (g) Ding lim thudc gly mé, héa chét digt stu bo, sir dung trong may lanh 1a mot sb tmg dung cia cdc dn ‘xuat halogen, (h) Dun néng anlyl bromua véi nude 6 nhigt d6 thich hgp c6 xc tic axit ¢6 thé thu duge propan-1,2-diol ‘6 nhdn dinh ding o wén la: Ad BS er D.6 Cf 118. Nhin dinh no sau day king ding? A. Axeton khong lim mat miu dung dich KMnO, 6 diéu kign throng. B. Cc xeton khi cho phan img véi Hz déu sinh ra ancol bac 2. C. Trit axetilen, cde ankin khi cOng muée déu cho san phim chinh la xeton. D. Axetophenon cin cé tén goi khac li metyl benzyl xeton. Cfiu 119. Cho ede chat va dung dich sau: benzen, toluen, stiren, etilen, xiclopropan, o-crezol, dung dich natri phenolat, nitrobenzen, vinyl axetat, etyl acrylat, metyl fomiat, foocmon, axeton. $6 chit va dung dich cé thé Jam mat mau dung dich Br2 (chi diing xtic tac dnh séing hodie mhigt db) la AB. B11 c.10 D9 Cfiu 120, Phat biéu khdng ching li A. Anken C:Hjo 6 5 déng phan edu tao. B. Dé phan biét cdc hidrocacbon no cé cng thie phan tir CsHs, ta c6 thé ding nude brom C. Bét chy hon toan mgt hidrocacbon thi khdi Iugng CO? thu duge luén én hon khoi lrgng H2O D. Néu mét hidrocacbon tac dung vii AgNOyNHs duge két tia ving hidrocacbon dé la ankin Cac cau hoi lay tir dé thi thie dai hoc cia cic truéng THPT trén ca mece néim 2011-2012 vi tie cde nguén dé hiv te Internet. Moi thitc mic vé céu hoi vi dép dn xin lién hé lemongrass.3 1.08@gmail.com Cau hei lithuyét v8 héa hoc hitu co 2012 LemonGrass.31.08@Gmail.com Trang 14/14