Square Planer Complex

PRESENTED BY:
SUSHIL .T. YADAV
M. Sc. PART I
ROLL No : 09

AGENDA
Introduction
Ligand Substitution Reaction Mechanism
Factor effecting the substitution reaction

Introduction
Types of Substitution Mechanism

Types of Substitution Mechanism

Dissociative
Associative
Interchange

Dissociative

Associative

Interchange

Ligand substitution

Rate Laws

Reaction Mechanism

Cont.

Factors Affect The Rate Of Substitution

Size of Metal ion

Charge on metal ion
Size of incoming ligand
Charge on the incoming ligand
Size & charge on leaving group
Trans effect

Size of Metal ion

Large size so that the association with incoming
ligand will be easy

Charge on metal ion

Charge on metal ion should be greater which
will assist in association with incoming
ligand

Size of incoming ligand

Size of incoming ligands be smaller so that it
can approach the metal ion very closely &
easily

Charge on the incoming ligand

To have a maximum interaction between
incoming ligand & metal ion charge on
ligand should be greater

Size & charge on leaving group

Leaving group should be small to make its
departure easy

Trans effect

References
Reaction Mechanism , By Prof Teap.G. Yeow
Substitution reaction of Metal Complex , By Fred Basolo
Mechanisms of Inorganic Reactions, By Pearson
Kinetics and Mechanism of Reactions of Transition Metal
Complexes (2nd Edition) , By Wilkins, R. G
Inorganic Chemistry (3rd Edition .), By Miessler, G. L.; Tarr, D. A
Inorganic and Bioinorganic Solvent Exchange Mechanisms , By Helm,
Lothar; Merbach

Thank You