The diaphragm cell process was the first commercial process used to produce chlorine and caustic soda from brine in the 1880s. It accounts for around 70% of chlorine and caustic soda production in North America today. In the diaphragm cell process, all reactions occur within a single cell and the cell effluent contains both salt and caustic soda. A diaphragm made of asbestos separates the chlorine produced at the anode from the hydrogen and caustic soda produced at the cathode. Brine enters the anode compartment and percolates through the diaphragm into the cathode chamber at a controlled rate to optimize caustic soda concentration and current efficiency. The diaph
The diaphragm cell process was the first commercial process used to produce chlorine and caustic soda from brine in the 1880s. It accounts for around 70% of chlorine and caustic soda production in North America today. In the diaphragm cell process, all reactions occur within a single cell and the cell effluent contains both salt and caustic soda. A diaphragm made of asbestos separates the chlorine produced at the anode from the hydrogen and caustic soda produced at the cathode. Brine enters the anode compartment and percolates through the diaphragm into the cathode chamber at a controlled rate to optimize caustic soda concentration and current efficiency. The diaph
The diaphragm cell process was the first commercial process used to produce chlorine and caustic soda from brine in the 1880s. It accounts for around 70% of chlorine and caustic soda production in North America today. In the diaphragm cell process, all reactions occur within a single cell and the cell effluent contains both salt and caustic soda. A diaphragm made of asbestos separates the chlorine produced at the anode from the hydrogen and caustic soda produced at the cathode. Brine enters the anode compartment and percolates through the diaphragm into the cathode chamber at a controlled rate to optimize caustic soda concentration and current efficiency. The diaph
The diaphragm cell process was the first commercial process used to produce chlorine and caustic soda from brine in the 1880s. It accounts for around 70% of chlorine and caustic soda production in North America today. In the diaphragm cell process, all reactions occur within a single cell and the cell effluent contains both salt and caustic soda. A diaphragm made of asbestos separates the chlorine produced at the anode from the hydrogen and caustic soda produced at the cathode. Brine enters the anode compartment and percolates through the diaphragm into the cathode chamber at a controlled rate to optimize caustic soda concentration and current efficiency. The diaph
The diaphragm process was developed in the 1880s in the USA and was the first commercial process used to produce chlorine and caustic soda from brine. In North America, diaphragm cells are still the primary technology, accounting for roughly 70% of all USA production. The process differs from the mercury cell process in that all reactions take place within one cell and the cell effluent contains both salt and caustic soda. A diaphragm is employed to separate the chlorine liberated at the anode, and the hydrogen and caustic soda produced directly at the cathode. Without the diaphragm to isolate them, the hydrogen and chlorine would spontaneously ignite and the caustic soda and chlorine would react to form sodium hypochlorite (NaClO), with further reaction to produce sodium chlorate (NaClO 3) [Kirk-Othmer, 1991]. The diaphragm is usually made of asbestos and separates the feed brine (anolyte) from the caustic-containing catholyte. Purified brine enters the anode compartment and percolates through the diaphragm into the cathode chamber. The percolation rate is controlled by maintaining a higher liquid level in the anode compartment to establish a positive and carefully controlled hydrostatic head. The percolation rate is determined as a compromise between a low rate that would produce a desirably high concentration of caustic soda in the catholyte (which provides the cell effluent) and a high rate to limit back-migration of hydroxyl ions from catholyte to anolyte, which decreases cathode current efficiency [Kirk-Othmer, 1991]. In the diaphragm cell, saturated brine (about 25% NaCl) is decomposed to approximately 50% of its original concentration in a pass through the electrolyser as compared to a 16% decomposition of salt per pass in mercury cells. Heating caused by passage of current through the diaphragm cell raises the operating temperature of the electrolyte to 80-99 C.