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Numbers and Units Assignment
Numbers and Units Assignment
Numbers and Units Assignment
12 hrs.
7 % recovery
_______7%_____
13 hr.
_________0.15
________12 h_____________
________0.175 g_____________
________13 h_____________
15 mLs
_______5 s______________
100 C
________100 C__________300 K
_______300 C ______________
c. The paragraph below contains several errors in the use of numbers and units. Identify at least
10 errors and correct them.
3-Benzyloxy-6-bromo-4-methoxyphenethyliminophosphorane. To a solution of LAH
(250 mg) in THF (15 mLl) was added a solution of 3-benzyloxy-6-bromo-4-methoxy-nitrostyrene (500 mg, 1.37 mmol) in THF (15 mL), which was then boiled under reflux for
eight hours. Addition of several millilitersmL of water followed by extraction with ether and
drying the ether layer (K2CO3) gave the corresponding phenethylamine, which was purified
by column chromatorgraphy on silica gel (hexane-CH2Cl2, 6:4 v/v): yellow oil (330 mg, 72
%); 1H NMR (400 MHz, CDCl3, ): 7.33 (m, 6H), 6.77 (s, 1H), 5.05 (s, 2H), 4.62 (s,
2H), 3.82 (s, 3H), 2.94 (m, 4H). The amine (160 mg, 0.48 mmol) and triphenylphosphine
(130 mg, 0.48 mmol) in 100 mgs of CCl4 and CH2Cl2 (7 mL) were stirred at 40 C for
seventy-two72 hours under dry N2.