equilibrium, with equilibrium descriptions following from teh 1st and 2nd laws of thermodynamics for closed systems open systems with heat, mass and/or electricity transported over system boundaries are much more important in engineering applications. Change and movement is more common than equilibrium state (also in nature as a result of the constant energy influx from the sun).
Thermodynamics is precise about what cannot
happen how can thermodynamics be applied to systems that are away from equilibrium how are concepts from thermodynamics useful for building kinetic models