PERHITUNGAN

1. Pembuatan Larutan NaOH 0,2 N

M=

N
ek

M=

gr
mr

0,2
1

1000
v

gr
40

0,2 =

= 0,2 M

1000
100

gr = 0,8 gram
2. Pembuatan Larutan C2H2O4 0,025 N
M=

N
ek

0,025
2

M=

gr
mr

1000
v

1000
100

0,0125 =

gr
126

= 0,0125 M

gr = 0,01575 = 0,2 gram

3. Standarisasi NaOH
Diketahui : V C2H2O4
M C2H2O4

= 5 ml
= 0,0125 M

V NaOH rata rata =

Ditanya : M NaOH = ?
Jawab

1 ml+ 1ml
2

= 1 ml

2 NaOH + H2C2O4 Na2C2O4 + 2 H2O

n NaOH = 2 n C2H2O4
=2(Mxv)
= 2 ( 0,0125 x 5 )
= 2 ( 0,0625)
= 0,125 mol
M NaOH =

n NaOH
V rata ratatitrasi
0,125
1

= 0,125 M

4. Kelarutan C2H2O4 Sebagai Fungsi Suhu

a. T = 60 OC
Diketahui : V C2H2O4 = 5 ml
M NaOH

= 0,125 M

V NaOH rata-rata=

11 +11,3
2

= 11,15 ml
Ditanya : n C2H2O4
Jawab :
2 NaOH + H2C2O4 Na2C2O4 + 2 H2O
n C2H2O4 =

1
2

x n NaOH

M C2H2O4 . V C2H2O4 =

M C2H2O4. 5 =

1
2

1
2

x M NaOH Standarisasi x V NaOH

x 0,125 x 11,15

M C2H2O4. = 0,69 M
n C2H2O4 = M C2H2O4 x V C2H2O4
= 0,69 x 5
= 3,45 mol
b. T = 50OC
Diketahui : V C2H2O4

= 5 ml

M NaOH

= 0,125 M

V rata-rata

9,8+10,3
2

= 10,05 ml

Ditanya : n C2H2O4
jawab :
2 NaOH + H2C2O4 Na2C2O4 + 2 H2O
n C2H2O4 =

1
2

x n NaOH

M C2H2O4 . V C2H2O4 =

M C2H2O4. 5 =

1
2

1
2

x M NaOH Standarisasi x V NaOH

x 0,125 x 10,05

M C2H2O4 = 0,63 M
n C2H2O4 = M C2H2O4 x V C2H2O4
= 0,63 x 5

= 3,15 mol

c. T = 40 OC
Diketahui : V C2H2O4

= 5 ml

M NaOH

= 0,125 M

V rata-rata

6,5+ 6,2
2

= 6,35 ml

Ditanya : n C2H2O4
Jawab :
2 NaOH + H2C2O4 Na2C2O4 + 2 H2O
M C2H2O4 . V C2H2O4 =

M C2H2O4. 5 =

1
2

1
2

x M NaOH Standarisasi x V NaOH

x 0,125 x 6,35

M C2H2O4. = 0,39 M
n C2H2O4 = M C2H2O4 x V C2H2O4
= 0,39 x 5
= 1,95 mol

d. T = 30OC
Diketahui : V C2H2O4

= 5 ml

M NaOH

= 0,125 M

V rata-rata

4+2,8
2

ditanya : n C2H2O4

= 3,4 ml

Jawab :
2 NaOH + H2C2O4 Na2C2O4 + 2 H2O
M C2H2O4 . V C2H2O4 =

M C2H2O4. 5 =

1
2

1
2

x M NaOH Standarisasi x V NaOH

x 0,125 x 3,4

M C2H2O4 = 0,21 mol

n C2H2O4 = M C2H2O4 x V C2H2O4
= 0,21 x 5
= 1,05 mol

T ( K)

1/ T ( K)

mol

Log mol

333

3,003 x 10 3

3,45

0,537

323

3,096 x 10 -3

3,15

0,498

313

3,194 x 10-3

1,95

0,290

303

3,300 x 10-3

1,05

-0,553

Grafik Hubungan antara Log Mol terhadap 1/T

0.6

f(x) = - 1788.92x + 5.97

R = 0.93

0.5
0.4
Log Mol

0.3

Linear ()

0.2
0.1
0
0

1/T (K)

Log mol =
Hps

Hps
1
x
2,303 x R T

= m x 2,303 x R
= -1788,9 X 2,303 X 8,314
= - 34252,32 J/mol
= - 34, 25 KJ/ mol