Chem 142 Lab 5 Autosaved

Page 1 of 18
Name:
Claire Fahlman
ID Number:
1530566
Quiz Section: AN
Lab Partner: Leah Hatzialexiou
Note: All sections of this

report must be typed.
Chem 142 Experiment #5

Kinetics I: Method of Initial Rates
By signing below, you certify that you have not falsified data, that you have not plagiarized any part of this lab
report, and that all calculations and responses other than the reporting of raw data are your own independent
work. Failure to sign this declaration will result in 5 points being deducted from your report score.
Signature:
Grading: 60 pts.
(Lab notebook pages are worth 10 pts - total for report and notebook is 60 pts)
Data, Calculations and Graphs
Stock Solutions
Soln.
Conc.
S2O32-
0.0005
Units
IBrO3-
0.010
0.040
HCl
0.100
Table of Recorded Reagent Volumes, Temperature, Time of Reaction, and Calculated Rate
Experiment
Run
Test Tube #1
H2O
S2O32-
Test Tube #2
I-
BrO3-
H+
Temp.
Celsius
Time
mL
mL
mL
mL
mL
sec.
0.00
0.50
1.00
0.50
0.50
23.6
31.1
47.2
0.25
0.50
0.75
0.50
0.50
23.68
3**
0.50
0.50
0.50
0.50
0.50
24.45
67.4
0.75
0.50
0.25
0.50
0.50
23.65
149.8
0.00
0.50
0.50
1.00
0.50
24.15
39.8
0.25
0.50
0.50
0.75
0.50
23.93
59.3
7**
0.50
0.50
0.50
0.50
0.50
23.45
72
0.75
0.50
0.50
0.25
0.50
23.75
152.3
0.00
0.50
0.50
0.50
1.00
23.55
21
10
0.25
0.50
0.50
0.50
0.75
22.98
37.6
11**
0.50
0.50
0.50
0.50
0.50
22.53
102.2
12
0.75
0.50
0.50
0.50
0.25
22.38
463.1
13
0.50
0.50
0.50
0.50
0.50
0.94
227.8
14*
0.75
0.50
0.50
0.50
0.25
20.69
85.7
15*
0.75
0.50
0.50
0.50
0.25
1.08
103.9
* Measurements made with a drop of 1.0 mM Ammonium Molybdate

** Repeated measurements for calculating k and Ea
A drop of 1% Starch indicator solution is included in each run.
Page 2 of 18
Show your calculation for the "Rate" here using data for Run #1:
Rate= -(1/6)(-0.0001/t)
Rate=-(1/6)(-0.0001/31.1)
Rate=5.36E-07 M/s
Reaction Order Determination for IShow your calculation for the concentration of BrO 3- used in Runs 1-4:
M1V1=M2V2
M2=[BrO3-]
(0.040M BrO3- )(0.50 mL)=[BrO3- ](2.5 mL)
[BrO3- ]= (0.040M BrO3- )(0.50 mL)(2.5 mL)
[BrO3- ]=0.050 M
Table of Recorded Temperature, Initial Concentrations, Time of Reaction, and Calculated Rate
Experiment
Run #
Temp
Celsius
Initial Concentrations (M)

S2O3
2-
BrO3
Time
Rate
sec
M/sec
0.0200
31.1
5.36E-07
0.0200
0.0080
47.2
3.53E-07
0.0020
0.0200
0.0080
67.4
2.47E-07
0.0010
0.0200
0.0080
149.8
1.11E-07
Run 1
23.6
0.0001
0.0040
Run 2
23.68
0.0001
0.0030
Run 3
24.45
0.0001
Run 4
23.65
0.0001
0.0080
READ THIS BEFORE PROCEEDING:

Recall that since BrO3- and H+ are held constant, the rate law takes on the
following form:
Rate = B[I-]i
where "B" is the pseudo rate constant that includes k, [H+], and [BrO3-].
Therefore, a plot of log(Rate) vs. log([I-]) (y-axis vs x-axis) will yield a straight
line with a slope equal to i, the order of the reaction with respect to I-.
X-axis
Y-axis
log(I-)
log(Rate)
-2.40
-6.27
-2.50
-6.45
-2.70
-6.61
-3.00
-6.96
Place your plot relating to

the reaction
order for
I - here,Respect
making it large
Reaction
Order
with
to I-enough to cover this box
(so that it is easy to read).
Refer to the text box
above for hints
about what
to plot. -2.80
-3.10
-3.00
-2.90
-2.70
-2.60
-2.50
-2.40
-5.80
-2.30
-6.00
FOR FULL CREDIT:

- plot the correct data on each axis
-6.20
- correctly label each axis and format the axis such that the data being plotted fills the majority of the graph (axes do NOT need to
start at 0)
f(x) = 1.1023809524x - 3.6511904762
-6.40
log(rate)title the plot

- appropriately
R = 0.9888644405
-6.60
- use Excel to add a trendline for the data...be sure to choose the trendline options that "display equation on chart" and "display
R-squared on chart"
-6.80
-7.00
Refer to the text box

above for hints
about what
to plot. -2.80
-3.10
-3.00
-2.90
FOR FULL CREDIT:
-2.70
Page 3 of 18
-2.60
-2.50
-2.40
-5.80
-2.30
-6.00
-6.20
start at 0)
f(x) = 1.1023809524x - 3.6511904762
-6.40
log(rate)title the plot

- appropriately
R = 0.9888644405
-6.60
R-squared on chart"
-6.80
-7.00
-7.20
log(I-)
What is the order with respect to I- as determined from your data?

1
Round to the nearest whole number.
If no trendline equation is provided on the plot, no credit will be given for your answer to this question.
Page 4 of 18
Reaction Order Determination for BrO3Table of Recorded Temperature, Initial Concentrations, Time of Reaction, and Calculated Rate
Experiment
Temp
Time
Rate
Run #
Celsius
S2O32-
Run 5
24.15
0.0001
0.0020
0.0200
Run 6
23.93
0.0001
0.0020
0.0200
0.0120
59.3
2.81E-07
Run 7
23.45
0.0001
0.0020
0.0200
0.0080
72
2.32E-07
Run 8
23.75
0.0001
0.0020
0.0200
0.0040
152.3
1.10E-07
BrO3-
sec
M/sec
0.0160
39.8
4.19E-07
X-axis
Y-axis
log(BrO3-)
log(Rate)
-1.80
-6.38
-1.92
-6.55
-2.10
-6.64
-2.40
-6.96
Place your plot relating

to the reaction
orderwith
for BrO
it large enough to cover this
3 here, making
Reaction
Order
Respect
to BrO3box (so that it is easy to read).
Refer to the text box above for hints about what to plot.
FOR FULL CREDIT:
start at 0)
f(x) = 0.9243759178x - 4.732907489
R = 0.9814104965
- appropriately title the plot
R-squared on chart"
.
What is the order with respect to BrO3- as determined from your data?
1
Page 5 of 18
Reaction Order Determination for H+

Table of Recorded Temperature, Initial Concentrations, Time of Reaction, and Calculated Rate
Experiment
Temp
Run #
Celsius

S2O3
2-
BrO3
Time
Rate
sec
M/sec
Run 9
23.55
0.0001
0.0020
0.0400
0.0080
21
7.94E-07
Run 10
22.98
0.0001
0.0020
0.0300
0.0080
37.6
4.43E-07
Run 11
22.53
0.0001
0.0020
0.0200
0.0080
102.2
1.63E-07
Run 12
22.38
0.0001
0.0020
0.0100
0.0080
463.1
3.60E-08
X-axis
Y-axis
log(H+)
log(Rate)
-1.40
-6.10
-1.52
-6.35
-1.70
-6.79
-2.00
-7.44
Place your plot relating to the reaction order for H+ here, making it large enough to cover this
Reaction
Order with Respect to H+
box (so that it is easy to
read).
Refer to the text box above for hints about what to plot.
FOR FULL CREDIT:
- correctly label each axis and format the axis such that the data being plotted fills the majority of the graph (axes do NOT need
to start at 0)
- appropriately title the plot
R-squared on chart"
.
f(x) = 2.2496328928x - 2.9468575624

R = 0.9993536415
What is the order with respect to H+ as determined from your data?

2
Page 6 of 18
Calculation of Rate Constant, k

Show your calculation of k using Run 3:
rate=k[I-][BrO3-][H+]^2
k=rate/([I-][BrO3][H+]^2)
k=1.11E-07 /(0.0020)(0.0080)(0.0200)^2
k=17.34 s^-1 M^-3
Table of Initial Concentrations, Time of Reaction, Calculated Rate, and Calculated k

Experiment
Run #
S2O32-
Run 3
0.0001
0.0020
Run 7
0.0001
Run 11
0.0001
Time
sec
M/sec
0.0200
0.0080
67.4
1.11E-07
17.34
0.0020
0.0200
0.0080
72
2.32E-07
36.25
0.0020
0.0200
0.0080
102.2
1.63E-07
25.47
H
i
n
t
:
Rate
BrO3-
Average:
26.35
Std Deviation:
9.49
Units:
s^-1M^-3
Determination of Activation Energy, Ea
U:Show the calculation of Ea uncatalyzed using the average room temp data and 0C data
s
eln(k2/k1)=-(Ea/R)((1/T2)-(1/T1)
ln(11.41/26.35)=-(Ea/8.13466)((1/274.09)-(1/296.65))
t Ea=25081.70 J/mol= 25.08 kJ/mol
h
e
r
o
u
n
Table of Temperature, Initial Concentrations, Time of Reaction, and Calculated Rate
d
Activation Energy: Uncatalyzed
e
d
Experiment
Temp
Time
Rate
v
a
l
u
e
s
Run #
Celsius
S2O32-
I-
H+
BrO3-
sec
M/sec
Ave *
23.5
0.0001
0.0020
0.0200
0.0080
80.53
1.7E-07
Run 13
0.94
0.0001
0.0020
0.0200
0.0080
227.8
7.3E-08
* Average value from runs # 3, 7, & 11

Ea of the uncatalyzed reaction:
Ea =
25.08
kJ/mol
Table
of Temperature, Initial Concentrations, Time of Reaction, and Calculated Rate
f
o
r
Activation Energy: Catalyzed with Ammonium Molybdate
Experiment
t
h
e
r
x
Temp
Time
Rate
e
s
f
o
r
t
h
e
r
x
n
o
r
d
e
r
s
f
r
o
m
y
o
u
r
c
o
n
c
l
u
s
i
o
n
s
a
n
d
n
o
t
t
h
e
l
i
n
e
a
r
r
e
g
r
e
Page 7 of 18
Run #
Celsius
S2O32-
I-
H+
BrO3-
sec
M/sec
Run 14
20.69
0.0001
0.0020
0.0100
0.0080
85.7
1.95E-07
Run 15
1.08
0.0001
0.0020
0.0100
0.0080
103.9
1.6E-07
Ea of the catalyzed reaction:
Ea =
32.8
kJ/mol
t
h
e
r
x
n
Page 8 of 18
o
Results and Discussion
r
d
e 1. Based on your data and the average value for the rate constant at room temperature for the
r uncatalyzed, write the complete rate law, including the value and units for the rate constant. (3 pt)
s
Rate=26.35s^-1M^-3[I-][BrO3-][H+]^2
f
r
o
m2. The literature values for the reaction orders are 1 for BrO - and I- and 2 for H+. Calculate the % error
3
for the experimental value for the order with respect to [I-].
(2 pts)
y
o Percent error=((Theoretical Value-Experimental Value)/Theoretical Value)(100)
u Percent error=((1-1.1024)/1)(100)
r Percent error=-10.24
c
o
n
c
l 3. Discuss your most likely sources of error.
(2 pts)
u
s Our most likely source of error were measurement mistakes or other human error. We could easily have put
i slightly too much of any of the solutions for any of the runs, which would have thrown off our data. We could also
o have made incorrect calculations.
n
s
a
n
d 4. How do the activation energies for the catalyzed and uncatalyzed reaction compare to each other? Is
this in line with what is expected? Explain.
(3 pts)
n
o The catalyzed reaction had a faster rate than the uncatalyzed reaction, which is what was expected. The
catalyst is supposed to lower the activation energy for a reaction, causing it to have a faster rate.
t
t
h
e
lLaboratory Waste Evaluation (1 pt)
iLaboratory waste is considered anything generated during an experiment that is disposed of down the sewer drain, thrown in
nthe garbage, collected in a container for disposal by the UW Environmental Health & Safety department, or released into the
eenvironment. Based on the written lab procedure and your actions during the lab, list the identity and approximate amount
a(mass or volume) of waste that you generated while performing this experiment.
r5 disposable pipettes
300 mL H2O
r1 Trough of ice
e5 paper towels
g9 mL of 0.0005M Na2S2O3
r9mL of 0.010M KI
e9mL of 0.040 KBrO3
9mL of 0.100 HCl
s9mL of color comparison solution
sseveral drops of starch solution
i
o
n
v
300 mL H2O
r1 Trough of ice
e5 paper towels
g9 mL of 0.0005M Na2S2O3
r9mL of 0.010M KI
e9mL of 0.040 KBrO3
9mL of 0.100 HCl
s9mL of color comparison solution
sseveral drops of starch solution
i
o
n
v
a
l
u
e
s
w
h
e
n
d
e
t
e
r
m
i
n
i
n
g
k
.
Page 9 of 18
Page 10 of 18
ll sections of this
must be typed.
d any part of this lab

ur own independent
t score.
otebook is 60 pts)
(4 pts)
Rate
M/s
5.36E-07
3.53E-07
2.47E-07
1.11E-07
4.19E-07
2.81E-07
2.32E-07
1.10E-07
7.94E-07
4.43E-07
1.63E-07
3.60E-08
7.32E-08
1.95E-07
1.60E-07
Page 11 of 18
(4 pts)
(3 pts)
alculated Rate
over this box
40
-5.80
-2.30
-6.00
-6.20
s do NOT need to
-6.40
-6.60
t" and "display
-6.80
-7.00
(5 pts)
40
-5.80
-2.30
-6.00
Page 12 of 18
-6.20
s do NOT need to
-6.40
-6.60
t" and "display
-6.80
-7.00
-7.20
(2 pts)
Page 13 of 18
alculated Rate
o cover this
do NOT need to
" and "display
(2 pts)
Page 14 of 18
alculated Rate
(2 pts)
Page 15 of 18
(3 pts)
(4 pts)
(6 pts)
Page 16 of 18
(4 pts)
Page 17 of 18
ure for the

onstant. (3 pt)
lculate the % error

(2 pts)
(2 pts)
uld easily have put

ur data. We could also
are to each other? Is

3 pts)
s expected. The
er rate.
e sewer drain, thrown in

ent, or released into the
d approximate amount
Page 18 of 18

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Page 1 of 18

Note: All sections of this

Chem 142 Experiment #5

Data, Calculations and Graphs

* Measurements made with a drop of 1.0 mM Ammonium Molybdate

Initial Concentrations (M)

READ THIS BEFORE PROCEEDING:

Place your plot relating to

FOR FULL CREDIT:

log(rate)title the plot

Refer to the text box

log(rate)title the plot

What is the order with respect to I- as determined from your data?

Initial Concentrations (M)

Place your plot relating

- appropriately title the plot

Reaction Order Determination for H+

Initial Concentrations (M)

f(x) = 2.2496328928x - 2.9468575624

What is the order with respect to H+ as determined from your data?

Calculation of Rate Constant, k

Table of Initial Concentrations, Time of Reaction, Calculated Rate, and Calculated k

Initial Concentrations (M)

Determination of Activation Energy, Ea

* Average value from runs # 3, 7, & 11

Activation Energy: Catalyzed with Ammonium Molybdate

Initial Concentrations (M)

Ea of the catalyzed reaction:

d any part of this lab

over this box

t" and "display

t" and "display

" and "display

ure for the

lculate the % error

uld easily have put

are to each other? Is

e sewer drain, thrown in

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