Professional Documents
Culture Documents
Vle 2
Vle 2
Vle 2
Raoults law
p1=x1.p10
Where,
p1-partial pressure of component
p10-vapour pressure of pure component
x1 -mole fraction of component in liquid phase
Daltons law
Ptotal = p1+ p2
Where,
Ptotal -Total pressure
p1 ,p2 -Partial pressure of component.
yiP=xiPisat (i=1,2,3..n)
Where:
yi = Vapor-phase mole fraction.
xi = Liquid-phase mole fraction.
Pi = Vapor pressure of pure species i at the T of the system.
yi P = Partial pressure of species i.
yi P = xi i Pisat ( i= 1,2,..,N)
Where
i = Activity coefficient.
Equilibrium Diagram
Vapor composition is drawn against liquid comp at
constant pressure. Vapour is always rich in more
volatile component the curve lies above the diagonal
line.
P-x-y Diagram
Fugacity coefficient () :
Fugacity coefficient is defined as the ratio of fugacity
of component to its pressure.
=f/P
- Is the measure of non ideal behavior of the gas.
Activity(a):
It is defined as the fugacity of the existing condition
to the standard state fugacity
a=f/ fo
Activity coefficient :
It measure the extent to which real solution depart from
ideality.
ln=bx
ln=bx
Thank You