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Vapour Liquid Equilibrium
Vapour Liquid Equilibrium
Vapour Liquid Equilibrium
EQUILIBRIUM
What is equilibrium?
Raoults law
Raoults law states that the partial pressure is equal to product of vapor
pressure and mole fraction in liquid phase.
p1=x1.p10
Where,
p1-partial pressure of component
p10-vapour pressure of pure component
x1 -mole fraction of component in liquid phase
Daltons law
Ptotal = p1+ p2
Where,
Ptotal -Total pressure
p1 ,p2 -Partial pressure of component.
yiP=xiPisat (i=1,2,3..n)
Where:
yi = Vapor-phase mole fraction.
xi = Liquid-phase mole fraction.
Pi = Vapor pressure of pure species i at the T of the system.
yi P = Partial pressure of species i.
yi P = xi i Pisat ( i= 1,2,..,N)
Where
i = Activity coefficient.
Fugacity coefficient () :
Fugacity coefficient is defined as the ratio of fugacity
of component to its pressure.
=f/P
- Is the measure of non ideal behavior of the gas.
Activity(a):
It is defined as the fugacity of the existing condition
to the standard state fugacity
a=f/ fo
Activity coefficient :
It measure the extent to which real solution depart from
ideality.
ln=bx
ln=bx
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