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Amity Water Technology Why So Dumb
Amity Water Technology Why So Dumb
Amity Water Technology Why So Dumb
Hardness of Water
Types of Hardness
8
9
Sludges
12
Priming
13
Foaming
14
Boiler Corrosion
15
Caustic Embrittlement
16
Carry Over
17
Water Softening
18
18
22
Internal treatment
25
Colloidal condition
25
Phosphate conditioning
25
Calgon conditioning
26
Alkalinity of Water
27
iv) Paper Industry: Paper Industry require water free from SiO2
(as it produces cracks in the paper); Turbidity (Fe and Mn as
they affect the brightness and colour of the paper); Alkalinity
(consumes alum and increases the cost of production);
Hardness (as Ca and Mg salts increase the ash content of the
paper.)
Hardness of Water
The soap consuming capacity of water is known as hardness of
water. Hardness in water is due to the formation of soap by the
cations of a soluble salt, when it dissolves in water. Generally,
soap consists of sodium salts of oleic acid, palmitic acid and
stearic acid. When these salts are dissolved in water, they do
not allow lather to be formed due to insolubility. It is due to the
reason that carbon dioxide present in water breaks sodium or
potassium soaps into free fatty acids. Hardness of water is due
to the presence of Ca2+ and Mg2+ contents of water.
2 C17H35COONa + CaCl2
Sodium stearate
(C17H35COO)2Ca + 2NaCl
Calcium stearate (insoluble)
2C17H35COONa + Ca(HCO3)2
(C17H35COO)2Ca + NaHCO3
Types of Hardness
i) Temporary hardness
ii) Permanent hardness
Ca(HCO3)2
HOOCH2C
CH2COOH
NCH2CH2N
HCOOCH2C
CH2COOH
2Na+
Na2H2Y
H2Y2-
Mg2+ + HD2blue
MgD- + H+
wine red
Units of hardness
Priming
Boiler problems
Boiler corroison
Foaming
Carry over
Scales
Scales are hard deposits firmly sticking to the inner surface of
the boiler. They are difficult to remove, even with the help of
hammer and chisel. Scales are major source of boiler troubles.
CaCO3
H2 O +
CO2
MgCl2
2H2O
Mg(OH)2
2HCl
Removal of Scale
iv) If the scales are adherent and hard, they can be removed by
adding chemicals viz. HCl, EDTA etc.
Sludges
Sludge is soft, loose and slimy precipitate formed within the
boiler. These are formed by substances which have greater
solubility in hot water than in cold water. Examples include
MgCO3, MgCl2, CaCl2, MgSO4 etc. Sludges are formed at
comparatively colder portions of the boilers and get collected at
places, where the flow rate is slow; they can be easily removed
(scrapped off) with a wire brush.
Priming
When steam is produced rapidly in the boilers, some droplets of
the liquid water are carried along with steam. This process of
wet-steam formation is called priming.
Foaming
It is the formation of small but persistent foam or bubbles at the
water surface in boilers, which do not break easily. Foaming is
caused by the presence of oil and alkalis in boiler feed water.
Boiler Corrosion
The decay of boiler material by is environment is known as
corrosion.
Prevention of corrosion:
Na2SO3
O2
Na2SO4
Caustic Embrittlement
It is the phenomenon during which the boiler material becomes
brittle due to the accumulation of caustic substance. This type
of boiler corrosion is caused by the use of highly alkaline water
in the high pressure boiler.
Na2CO3
H2 O
2NaOH
CO2
This NaOH containing water flows into the small clacks of boiler
by capillary action. The caustic dissolves the iron of
surrounding area inside the boiler as sodium ferroate. At these
areas corrosion takes place in such a manner that inter
granular cracks occur in an irregular fashion. Such a
phenomenon is known as caustic embrittlement.
Carry Over
The phenomenon of carrying of water along with impurities by
steam is called carry over. This is mainly due to priming and
foaming.
Water Softening
The process whereby we remove or reduce the hardness of
water irrespective of whether it is temporary or permanent is
termed as softening of water. Water softening is very essential
since hard water is unsuitable for domestic as well as industrial
use. Water can be made soft by external as well internal
treatment.
Ca(OH)2
+ Na2CO3 + H2o
CaCO3
(Soluble impurities)
2NaOH
(Insoluble ppt.)
i) It is very economical.
ii) Treated water is alkaline and hence has less corrosion
tendencies.
iii) It removes not only hardness causing salt but also minerals.
iv) Due to alkaline nature of treated water, amount of
pathogenic bacteria in water is considerably reduced.
v) Iron and manganese are also removed from the water to
some extent.
Process
xRSO3-H+ +
M+
solid
(RSO3-)x Mx+
solution
xH+
solid
solution
x[RN(CH3)3+ ]OH- + A+
solid
solid
[RN(CH3)3+]xAx- + xOHsolution
solution
H+
OH-
H2O
Thus the water coming out from the exchanges is free from
cations as well as anions. Ion free water is known as deionised
or demineralised water. Thus it is known as pure as distilled
water.
Internal treatment
In this water softening is done by treating raw water inside the
boiler. This method is known as sequestration.
Internal treatment methods are followed by blow down
operation, so that the accumulated sludge is removed.
CO32- +
HCO3-
H2 O
H2O
HCO3H2 O
OH-
+ CO2 + OH-
CaSO4
Na3PO4
Ca(PO4)2
Na2SO4
Na2[Na4(PO3)6]
2Na+
[Na4(PO3)6]2-
Calgon
CaSO4 + [Na4(PO3)6]2-
[Ca2(PO3)6]2- + Na2SO4
Soluble complex
Alkalinity of Water
Alkalinity is a measure of the ability of water to neutralize the
acids. The alkalinity of water is normally due to the presence of
bicarbonates and hydroxides of sodium, potassium, Ca and
Mg. Presence of borates, silicates phosphates can also
contribute to the total alkalinity to some extent.
Thus,
Ca(HCO3)2
162
Ca(OH)2
74
Thus,
Ca(OH)2
2 x Mg(HCO3)2
Na2CO3