Statistical Physics Week 4 Tutorial Problem 1 In this problem, we'll show how quantum expressions recover their classical counterparts in the small fi limit, an important check on the quantum answers! A, To order «3, what are the Taylor expansions for cosh and sinh x around x = 0? Use the usual Taylor formula A Fla+2) =f) +2f"@) + FI" a+ @ to derive your answer. B. Use your answer from the provious part to find the ‘Taylor expansion for coth « around x = 0 to linear order. You may find it useful to do the Taylor expansion for tanh. firs, although you don’t necessarily need to, Note that coth. blows up at x= 0, so you can’t just plug it into the usual Taylor formula! €.tnclan woh ha these eaten o 1 onesie ut oars en Nhw Bhs = SMa (E) @ Use the Taylor expansion you found for eoth x to expand H in the limit of small fh. As f+ 0, what is the limiting value of E? D. What is the classical energy E(p,q) for a single classical oscillator with frequency w and mass m? E. The Equipartition of Energy theorem say's that every quadratic term in the Hamiltonian results in an average thermal energy of Ska. According to this theorem, what is the average thermal energy of N classical oscillators? How does your answer compare to the small A limit of the quantum answe:? F, Recalling that the partition funetion for NV quantum oscillators (which we derived in class) is @) derive the entropy of the system of N quantum harmonic oscillators. Recall that the Helmboltz free energy is given by F = —kpT log Zy. G. Show that your answer to the previous part recovers the classical expression (derived in class) s :w (1 — log (hw)) @ in the small f limit. Problem 2 In last week's homework, you used the fact that the average magnetization can be derived via M = -0F/0H. In this problem we explore this in a little more detail. A. Consider a system described by the usual quantities p,V,T,S, and additionally Mf and H. From the partial derivative given above, write the differential form of F that incorporates the energy due to magnetic work, such tha F = F(T,V,H). Remember that in the absence of a magnetic field, dF = -SdT — paV. B. Using a Legendre transformation (which is what we use to go between the different thermodynamic potentials), find a thermodynamic potential & which is a function of T,V, and M. Write its db as well as & itself, C. Using the differential you just derived, find a Maxwell relation for (9H/2T) ay.Week UT ete ( thal | A\ Cox: Cailo)=l Suelo) -0 So Cox A [4 xsuhl €)t Beatle) « Rouble) Aisi aa Subyto : u x + Xeeshlo) + Eesvblo)-+ Sto tc\ > Aye+ 3 B\ Gsthx — cOskX 12772) 1 Oak) Sx ak) X (GN) \ Cte =— x (eh a) =t(4e te C\ Ee Nie extt (Phe tio 2 (Oa Nee «Be alee +66) 4phst + 06)D\ EF dmts* | Bad Oscallelor tes DgtheT= eT “Talal Cersy {NisT ] A/S F \ ee UT la ( al Jott clay) oNlsTlng( 2544 BE) = 2 _ face (astes v2 7 ree te = QhoT™ © Tem: yeSthy 1 atsmll x e\ leg(Qsnh(ES) ) — log cae fe ainDechlonZ A \ OF =-SIT-pOV- HOH B\ a= —sr-pov'- A(HH)+ HOM > &lFsHH) 2-S8T -p0N +H. z [ee Ts HH | [gee sor pV HOM | Fl.)