The following information will be needed for questions 1 4:

Mass numbers: Na-23, Mg-24, O-16, H-1, C-12, S-32, Ca-40, K-39, F-19, N- 14
Avogadros number: 6.02x1023
Molar volumes of gases: At r.t.p. 24 dm3; At s.t.p. 22.4 dm3
1. How many particles (state whether atoms or molecules) are present in the
following:
1.25 moles of Ca(OH)2
a.
3.2 moles of HF
b.
0.0028 moles of CH4
c.
2. How many moles are present in the following?
2.5 x 1020 molecules of H2O
a.
7.5 x 1024 atoms of Fe
b.
9.0 x 1022 electrons
c.
40 g of NaOH
d.
40 g of HF
e.
40 g of K2O
f.
50 dm3 of F2 (g) at r.t.p.
g.
45 dm3 of O2 (g) at s.t.p.
h.
100 dm3of SO3 (g) at r.t.p.
i.
60 dm3 of NO2 (g) at s.t.p.
j.
3. What is the mass of the following amounts of substances?
3.5 moles of Mg(OH)2
a.
0.02 moles of H2S
b.
1.5 moles of KF
c.
0.75 moles of MgS
d.
4. What is the volume of the following?
5 moles of SO3 (g) at s.t.p.
a.
.02 moles of NO2 (g) at r.t.p.
b.
0.35 moles of H2 (g) at r.t.p.
c.
1.55 moles of CO2 (g) at s.t.p.
d.
5.
a. When chemical reactions occur, heat may be given off or taken in from the
environment. What changes occur during a reaction that can account for this
fact?

b. i.
ii.

Define the term heat of neutralization.

It is observed that when a strong acid (such as HCl or HNO 3) is
completely neutralized by a strong base (such as NaOH or KOH), the
heat of neutralization (in kJ mol-1) is always the same. Account for this
observation.

c. When 12.0 g potassium nitrate (KNO3) is dissolved in 100cm3, the

temperature drops by 4.20 C
Relative atomic mass: K=39, N=14, O=16
Specific heat capacity of water = 4.2 Jg-1K-1
Heat change = M x c x T
1 cm3 of solution = 1g

i.

Using the above information, calculate EACH of the following:

a. The number of moles of KNO3 used in the experiment
b. The heat change for the reaction
c. The enthalpy change in kJ mol -1 for the reaction

ii.
iii.

State ONE assumption you made in your calculation.

Draw a labeled energy profile diagram to represent the enthalpy
change for the reaction.