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  • MBD Toolkit B

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    This document describes several organic reactions including substitution reactions using bromine, chlorine, nitric acid, sulfuric acid and hydrogen chloride. It also describes Friedel-Crafts alkylation and acylation reactions using alkyl/acyl chlorides and aluminum chloride as the catalyst. The Friedel-Crafts reactions form carbon-carbon bonds and all substitution reactions of arenes discussed are electrophilic in nature.

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    This document describes several organic reactions including substitution reactions using bromine, chlorine, nitric acid, sulfuric acid and hydrogen chloride. It also describes Friedel-Crafts alkylation and acylation reactions using alkyl/acyl chlorides and aluminum chloride as the catalyst. The Friedel-Crafts reactions form carbon-carbon bonds and all substitution reactions of arenes discussed are electrophilic in nature.

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    160 views1 page

    MBD Toolkit B

    Uploaded by

    OCRChemistrySalters
    This document describes several organic reactions including substitution reactions using bromine, chlorine, nitric acid, sulfuric acid and hydrogen chloride. It also describes Friedel-Crafts alkylation and acylation reactions using alkyl/acyl chlorides and aluminum chloride as the catalyst. The Friedel-Crafts reactions form carbon-carbon bonds and all substitution reactions of arenes discussed are electrophilic in nature.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as PPT, PDF, TXT or read online from Scribd
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    of 1

    Br Cl

    substitution
    substitution
    Cl2(g)
    Br2(l) AlCl3
    FeBr3 (or Fe) room temp
    room temp

    SO 2OH c.HNO3 NO 2 NH2


    c. H2SO4 c. H2SO4
    Sn + c.HCl
    reflux <55C reflux
    substitution substitution reduction

    Friedel-Crafts Friedel-Crafts
    alkylation RCl acylation
    AlCl3 RCOCl
    substitution reflux Or (RCO)2O substitution
    O
    AlCl3
    R C
    R

    Notes: 1. The Friedel-Crafts reactions are carbon-carbon bond forming reactions.


    2. All substitution reactions of arenes are electrophilic.

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