KALIBRASI REFRAKTOMETER

VOLUME (ml)
Metanol
10
9
8
7
6
5
4
3
2
1
0
pikno
pikno + air
50.579

indeks bias
N

Air
0
1
2
3
4
5
6
7
8
9
10
22.694

1.335
1.334
1.333
1.332
1.330
1.329
1.328
1.327
1.326
1.324
1.319

air

pikno + metanol

27.885

44.838

(70:30)
Air-metanol

REFLUKS TOTAL

temperatur (oC)

(menit)

Td

Tw

4
8
12
16
20
24

60
69
72
73
68
64

71
71
71
71
71
71

#VALUE!

71

(55:45)
Metanol:Air

REFLUKS TOTAL

temperatur (oC)

(menit)

Td

Tw

0
4
8
12
16

56
66.8
66.8
69.8
69

66
67
67
67
67

1.326
1.327
1.329
1.332
1.335
1.330
1.333
1.334
1.328
1.319
1.324

20
24
28
32
36
40
44
48

69
69
69
60
60
60
60
60

67
67
67
68
68
68
68
68

(60:40)
air-metanol

REFLUKS PARSIAL (4:6)

temperatur (oC)

(menit)

Td

Tw

0
4
8
12
16
20
24
28
32
36
40
44
48

57
60
60
60
60
60
60.5
60.5
60.5
60.5
60.5
60.5
60.5

70
71
71
71
71
71
68
68
68
68
68
68
68

(40:60)
Metanol:Air

REFLUKS PARSIAL (5:2)

temperatur (oC)

(menit)

Td

Tw

0
4
8
12
16
20
24
28
32
36
40
44
48

59
60
60
60
60
60
60
60
60
60
60
60
60

68
71
71
71
71
71
68
68
68
68
68
68
68

(7/3)

(55:45)
Metanol:Air

REFLUKS PARSIAL (5:2)

(7/3)

temperatur (oC)

(menit)

Td

Tw

0
4
8
12
16
20
24
28
32
36
40
44
48

57
58
58
57
57
59
60
60
60
60
60
60
60

64
65
66
66
67
67
68
68
68
68
68
68
68
Fraksi mol

Jenis refluk

xw

xd

Refluks Total
(Perbandingan
campuran=40:60)

0.1

0.99

Refluks Total
(Perbandingan
campuran=55:45)

0.2

0.865

Refluks Parsial 7:3

(Perbandingan
campuran=40:60)

0.08

0.99

Refluks Parsial 5:3

(Perbandingan
campuran=40:60)

0.08

0.99

Refluks Parsial 7:3

(Perbandingan
campuran=55:45)

0.08

0.865

ER
densitas
air
0.99708
0.99708
0.99708
0.99708
0.99708
0.99708
0.99708
0.99708
0.99708
0.99708
0.99708

mol

metanol
0.7917998752
0.7917998752
0.7917998752
0.7917998752
0.7917998752
0.7917998752
0.7917998752
0.7917998752
0.7917998752
0.7917998752
0.7917998752

air
0.5539333333
0.49854
0.4431466667
0.3877533333
0.33236
0.2769666667
0.2215733333
0.16618
0.1107866667
0.0553933333
0

metanol
0
0.0247437
0.0494875
0.0742312
0.098975
0.1237187
0.1484625
0.1732062
0.19795
0.2226937
0.2474375

x (fraksi)
metanol
0
0.0472855239
0.1004548534
0.1606790418
0.2294619912
0.3087677549
0.4012111061
0.510351367
0.6411612555
0.8008057776
1

Metanol
22.144

temperatur (K)

indeks bias

Td

Tw

Nd

Nw

333
342
345
346
341
337
#VALUE!

344
344
344
344
344
344
344

1.333
1.332
1.334
1.329
1.329
1.329

1.332
1.335
1.333
1.329
1.329
1.329

1.324

1.330

temperatur (K)

indeks bias

Td

Tw

Nd

Nw

329
339.8
339.8
342.8
342

339
340
340
340
340

1.332
1.323
1.325
1.327
1.324

1.333
1.333
1.333
1.334
1.333

Trata-rata
(oC)
(K)
65.5
70
71.5
72
69.5
67.5
#VALUE!

338.5
343
344.5
345
342.5
340.5
#VALUE!

Trata-rata
(oC)
(K)
61
66.9
66.9
68.4
68

334
339.9
339.9
341.4
341

342
342
342
333
333
333
333

340
340
340
341
341
341
341

333

341

temperatur (K)
Td

1.325
1.325
1.325
1.324
1.324
1.324
1.324
1.324

1.333
1.333
1.333
1.332
1.332
1.332
1.332
1.332

indeks bias
Tw

Nd

Nw

330
333
333
333

343
344
344
344

333
333
333.5
333.5
333.5
333.5
333.5
333.5

344
344
341
341
341
341
341
341

333.5

341

1.334
1.324
1.325
1.321
1.321
1.321
1.326
1.326
1.326
1.326
1.326
1.326
1.326

1.332
1.331
1.332
1.331
1.331
1.331
1.332
1.332
1.332
1.332
1.332
1.332
1.332

temperatur (K)

indeks bias

Td

Tw

Nd

Nw

332
333
333
333
333
333
333
333
333
333
333
333

341
344
344
344
344
344
341
341
341
341
341
341

333

341

1.333
1.321
1.321
1.321
1.321
1.321
1.321
1.321
1.321
1.321
1.321
1.321
1.321

1.331
1.330
1.329
1.331
1.331
1.331
1.330
1.330
1.330
1.330
1.330
1.330
1.330

68
68
68
64
64
64
64
64

341
341
341
337
337
337
337
337

Trata-rata
(oC)
(K)
63.5
65.5
65.5
65.5
65.5
65.5
64.25
64.25
64.25
64.25
64.25
64.25
64.25

336.5
338.5
338.5
338.5
338.5
338.5
337.25
337.25
337.25
337.25
337.25
337.25
337.25

Trata-rata
(oC)
(K)
63.5
65.5
65.5
65.5
65.5
65.5
64
64
64
64
64
64
64

336.5
338.5
338.5
338.5
338.5
338.5
337
337
337
337
337
337
337

\lmk90ol.

temperatur (K)
Td

indeks bias
Tw

Nd

Nw

330
331
331
330
330
332
333
333
333
333
333
333

337
338
339
339
340
340
341
341
341
341
341
341

333

341

1.335
1.330
1.325
1.325
1.325
1.325
1.323
1.323
1.323
1.323
1.323
1.323
1.323

1.332
1.333
1.332
1.331
1.331
1.331
1.332
1.332
1.332
1.332
1.332
1.332
1.332

Jumlah Tahapan

Frenske
Underwood

Mc Cabe
Thiele

HETP

3.9767353345

4.9203442688

0.2845329

4.0275011671

2.3283624233

2.02

0.601281

4.0639304256

5.0190521143

0.2789371

4.0639304256

5.0190521143

0.2789371

Trata-rata
(oC)
(K)
60.5
61.5
62
61.5
62
63
64
64
64
64
64
64
64

333.5
334.5
335
334.5
335
336
337
337
337
337
337
337
337

4.1394218467

3.0268439807

3.05

0.462528

i
n
d
e
k
b
i
a
s

Ln Pa

Pa

LnPb

Pb

Alpha

4.629698
4.8031784
4.8598834
4.878663
4.7841537
4.7074318
#VALUE!

102.483108
121.8972435
129.0091567
131.4547916
119.6001077
110.7673238
#VALUE!

3.2293372
3.4263121
3.4906809
3.5119969
3.4047145
3.3176075
#VALUE!

25.26290771
30.76298323
32.80827963
33.51512863
30.10569844
27.59425292
#VALUE!

4.0566632
3.962465
3.9322134
3.9222523
3.9726734
4.0141447
#VALUE!

0.1

data kesetimbangan
Xa

Ya

#VALUE!
#VALUE!
#VALUE!
#VALUE!
#VALUE!
#VALUE!
#VALUE!
#VALUE!
#VALUE!
#VALUE!
#VALUE!

0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1

1
0

3.9767353

Ln Pa

Pa

LnPb

Pb

Alpha

4.4509918
4.6842188
4.6842188
4.7420807
4.7267064

85.71191074
108.2256963
108.2256963
114.6725554
112.9230249

3.026353
3.2912496
3.2912496
3.3569482
3.3394924

20.6218866
26.87642856
26.87642856
28.70146694
28.20480693

4.1563564
4.0267886
4.0267886
3.9953552
4.0036801

data kesetimbangan
Xa

Ya
0
0.1
0.2
0.3
0.4

0.0000
0.3124
0.5055
0.6367
0.7316

1
0

0.2

0.3

4.7267064
4.7267064
4.7267064
4.5707214
4.5707214
4.5707214
4.5707214

4.5707214 96.61378564

Ln Pa

Pa

3.162357 23.62621624 4.0892619

4.0275012

LnPb

Pb

Alpha

data kesetimbangan
Xa

102.483108
102.483108
97.57209544
97.57209544
97.57209544
97.57209544
97.57209544
97.57209544

3.2293372
3.2293372
3.1735671
3.1735671
3.1735671
3.1735671
3.1735671
3.1735671

25.26290771
25.26290771
23.8925601
23.8925601
23.8925601
23.8925601
23.8925601
23.8925601

Ya

0.0000
0.3107
0.5035
0.6348
0.7301
0.8022
0.8589
0.9044
0.9420
0.9733
1.0000

0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1

4.5509321 94.72065503 3.1398801 23.10109692 4.1002666

4.629698 102.483108 3.2293372 25.26290771 4.0566632
4.629698 102.483108 3.2293372 25.26290771 4.0566632
4.629698 102.483108 3.2293372 25.26290771 4.0566632
4.629698
4.629698
4.5805915
4.5805915
4.5805915
4.5805915
4.5805915
4.5805915

0.8001
0.8598
0.9051
0.9424
0.9735
1.0000

0.5
0.6
0.7
0.8
0.9
1

112.9230249 3.3394924 28.20480693 4.0036801

112.9230249 3.3394924 28.20480693 4.0036801
112.9230249 3.3394924 28.20480693 4.0036801
96.61378564 3.162357 23.62621624 4.0892619
96.61378564 3.162357 23.62621624 4.0892619
96.61378564 3.162357 23.62621624 4.0892619
96.61378564 3.162357 23.62621624 4.0892619

4.0566632
4.0566632
4.0837857
4.0837857
4.0837857
4.0837857
4.0837857
4.0837857

1
0

4.5805915 97.57209544 3.1735671 23.8925601 4.0837857

4.0639304

Pa

LnPb

Pb

Alpha

4.5509321
4.629698
4.629698
4.629698
4.629698
4.629698
4.5707214
4.5707214
4.5707214
4.5707214
4.5707214
4.5707214

94.72065503
102.483108
102.483108
102.483108
102.483108
102.483108
96.61378564
96.61378564
96.61378564
96.61378564
96.61378564
96.61378564

3.1398801
3.2293372
3.2293372
3.2293372
3.2293372
3.2293372
3.162357
3.162357
3.162357
3.162357
3.162357
3.162357

23.10109692
25.26290771
25.26290771
25.26290771
25.26290771
25.26290771
23.62621624
23.62621624
23.62621624
23.62621624
23.62621624
23.62621624

4.1002666
4.0566632
4.0566632
4.0566632
4.0566632
4.0566632
4.0892619
4.0892619
4.0892619
4.0892619
4.0892619
4.0892619

4.5707214 96.61378564

3.162357 23.62621624 4.0892619

data kesetimbangan
Xa

1.1

Ya
0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1

0.0000
0.3107
0.5035
0.6348
0.7301
0.8022
0.8589
0.9044
0.9420
0.9733
1.0000

1
0

y metanol

Ln Pa

1
0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0

4.0639304

Ln Pa

Pa

LnPb

Pb

Alpha

4.4308027
4.4711134
4.4911679
4.4711134
4.4911679
4.5310769
4.5707214
4.5707214
4.5707214
4.5707214
4.5707214
4.5707214

83.998816
87.45404296
89.22559553
87.45404296
89.22559553
92.85851022
96.61378564
96.61378564
96.61378564
96.61378564
96.61378564
96.61378564

3.0034162
3.0492121
3.0719939
3.0492121
3.0719939
3.1173276
3.162357
3.162357
3.162357
3.162357
3.162357
3.162357

20.15427145
21.09871353
21.58489884
21.09871353
21.58489884
22.58593963
23.62621624
23.62621624
23.62621624
23.62621624
23.62621624
23.62621624

4.1677922
4.1449941
4.1337046
4.1449941
4.1337046
4.1113415
4.0892619
4.0892619
4.0892619
4.0892619
4.0892619
4.0892619

4.5707214 96.61378564

3.162357 23.62621624 4.0892619

4.1394218

data kesetimbangan
Xa

Ya
0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1

0.0000
0.3136
0.5069
0.6379
0.7327
0.8044
0.8605
0.9056
0.9427
0.9737
1.0000

1
0

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1.1

X metanol

1
0

0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0
0

0.1

1
0

y metanol

0.2

y metanol

0.1

0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1

0.2

0.3

0.4

0.5
x metanol

0.6

0.7

0.8

0.9

0.7
0.6
0.5
0.4
0.3
0.2
0.1

Xw

0
0

0.1

0.2

0.3

0.4

0.5
x metanol

0.6

0.7

0.8

y metanol

Chart Title

1
0

1.1
1

q line

0.9
0.8
0.7

Intersept

0.6
0.5
0.4
0.3
0.2
0

Xf

Xw

0.1
0

0.1

0.2

0.3

0.4

0.5

0.6

x metanol

0.7

0.8

y metanol

1.1

1 1
0 0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.2

Xf

0.1
0

0.1

0.2

0.3

0.4

0.5

x metanol

0.6

0.7

0.8

0.9

Chart Title
y metanol

1
0

1.1
1
0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0

0.1

0.2

0.3

0.4

0.5

y metanol

0.6

0.7

0.8

0.9

Xd
0.7

0.8

0.9

Xd
0.99

Xw
0.1

Xd
0.6

0.7

0.8

0.9

Xd
0.6

0.7

0.7

0.8

0.8

0.9

0.9

Xd
0.865

Xw
0.2

Xd
0.99

Xw
0.08

Xf
0.4

Intersept
0.297

Xd
0.99

Xw
0.08

Xf
0.4

Intersept
0.282857143

Xd
0.865

0.7

0.8

0.9

Xw
0.08

Xf
0.55

Intersep
0.2595

jenis refluk

Fraksi mol
xw

xd

Jumlah Tahapan

Frenske Underwood

REFLUKS TOTAL METANOL

(60;40)
fraksi mol

indeks bias

ALPHA

1.33

xd
0.99

xw
0.1

#VALUE!

(65;45)
1.333

0.865

0.2

4.00368

Nd

Nw

1.324
1.325

REFLUKS TOTAL METANOL

(1-Xw)/Xw
60;40
9
65;35
4
REFLUKS PARSIAL METANOL
(60;40)(4;6)
9
(65;35)(5;2)
9
9
(60;40)(5;2)

Xd/(1-Xd)
LOG A
99
#VALUE!
6.40740741 0.602459
6.69230769 0.608169
7.33333333 0.608169
15.6666667 0.611645

REFLUKS PARSIAL METANOL (4;6)

60;40
Nd

indeks bias
Nw

1.326

1.332

fraksi mol
ALPHA

xd
xw
0.87
0.1
4.056663
REFLUKS PARSIAL METANOL (5;2)
indeks bias
Nd

1.323

Y*Z
LOG C
891
2.949878
25.6296 1.408742

Nm
#VALUE!
2.338319222

Nw

1.332

HETP
#VALUE!
0.598721
Nm=

60.2308 1.779818
66
1.819544
141
2.149219

2.9265196829
2.9918395675
3.5138346201

0.478384
0.46794
0.398425

Log

XD

( 1X D
Log

REFLUKS parsial methanol(5;2)

65;35
indeks bias
Nw

Nd

1.325

1.332

60;40
fraksi mol
xd
xw
0.94
0.1

Log

ALPHA

4.0892618889

XD

( 1X W )

( 1X D )

XW

Log

fraksi mol
xd
xw
0.88
0.1

ALPHA

4.056663