THI TH HA 11 C BN

S 1
I. PHN TRC NGHIM (3 im)
Cu 1. Ankin C6H10 c bao nhiu ng phn phn ng vi dung dch AgNO3/NH3 to kt ta?
A. 3.
B. 4.
C. 5.
D. 6.
Cu 2. Cho s : C6H6 X Y C6H5OH. Cht Y l
A. C6H5Cl
B. C6H5ONa
C. C6H5CH3
D. C6H5CHO
Cu 3. Dy cc cht c nhit si tng dn l
A. CH3COOH, CH3CHO, C2H5OH, C2H6 B. CH3CHO, C2H5OH, C2H6, CH3COOH
C. C2H6, CH3CHO, C2H5OH, CH3COOH
D. C2H6, C2H5OH, CH3CHO, CH3COOH
Cu 4. Khi cho 2-metylbut-2-en phn ng cng vi HCl th sn phm chnh thu c c tn l
A. 2-clo-2-metylbutan
B. 2-metyl-2-clo butan
C. 2-clo-3-metylbutan
D. 3-clo-2-metylbutan
Cu 5. Hn hp X gm metan v anken, cho 5,6 lt X qua dung dch brom d thy khi lng bnh brom tng 7,28
gam v c 2,688 lt kh bay ra (ktc). CTPT ca anken l:
A. C2H4
B. C5H10.
C. C3H6.
D. C4H8.
Cu 6. Dy gm cc cht u tc dng vi ancol etylic l
A. HBr (to), Na, CuO (to), CH3COOH (xc tc).
B. Ca, CuO (to), C6H5OH (phenol), HOCH2CH2OH.
C. NaOH, K, MgO, HCOOH (xc tc).
D. Na2CO3, CuO (to), CH3COOH (xc tc), (CH3CO)2O.
Cu 7. Khi cho 2-metylbutan tc dng vi clo (nh sng, t l 1:1) th thu c bao nhiu sn phm th monoclo?
A. 2.
B. 3.
C. 4.
D. 5.
Cu 8. Cho 20 gam dung dch fomalin 33% tc dng vi AgNO3/NH3 d th lng kt ta l
A. 144 gam.
B. 95,04 gam. C. 47,52 gam. D. 118,8 gam.
Cu 9. C5H10O2 c bao nhiu ng phn axit?
A. 2.
B. 3.
C. 4.
D. 5.
Cu 10. Phn ng no sau y khng xy ra:
A. Benzen + Cl2 (as).
B. Benzen + H2 (Ni, p, to).
C. Benzen + HNO3 () /H2SO4 ().
D. Benzen + Br2 (dd).
Cu 11: Cho 8,7 gam anehit X tac dng hon ton vi lng dung dch AgNO3/NH3 (d) c 64,8 gam Ag. X
c cng thc phn t l
A C3H4O.
B C2H2O2.
C CH2O.
D C2H4O.
Cu 12: Axit axetic (CH3COOH) tac dng c vi tt c cac cht trong dy no sau y?
A Cu, C2H5OH, dd Na2CO3.
B Cu, dd Na2CO3, CH3OH.
C Mg, Ag, dd Na2CO3.
D Mg, dd Na2CO3, CH3OH
II. PHN T LUN (7 im)
Bi 1. Vit cac phng trnh phn ng xy ra trong s sau:
1
C2H4
C2H2

2
3

C2H5OH

4
5

6
CH3COOH
CH3CH=O

Bi 2. Trnh by cch phn bit cc cht ring bit: C2H5OH, C6H5OH, CH3CHO, CH3COOH?
Bi 3. Dn 8,94 lit hn hp kh X gm propan, propilen v propin qua dung dch nc brom d, thy khi lng
bnh ng brom tng ln m gam v cn 2,8 lit mt kh thot ra. Nu dn ton b kh X trn qua dung dch
AgNO3/NH3 th to ra 22,05 gam kt ta. Tnh m v phn trm th tch ca mi kh trong X (bit cac kh o ktc).
Bi 4: Cho 26,8 gam hn hp X gm ancol tylic v 1 axt cacboxylic mch h no n chc tac dng vi Na d
th sinh ra 4,48 lt kh (kc) . Mc khac cng lng hn hp ban u khi tac dng vi 1 lng d dung dch
Na2CO3 thi sinh ra 3,36 lt kh (kc) .
1/ Xac nh khi lng mi cht trong hn hp ban u
(1,5)
2/ Xac nh cng thc cu to ca axt .
( 0,5)
3/ Nu un nng lng hn hp X ban u vi H2SO4 th sau khi phn ng t trng thai cn bng thu
c 7,65gam este. Tnh hiu sut phn ng ny?
(1)

 S 2
I. PHN TRC NGHIM (3 im)
Cu 1: Cho s phn ng sau: CH4 X Y PVC. Trong , X v Y ln lt l:
A. C2H6, CH2=CHCl.
B. C3H4, CH3CH=CHCl.
C. C2H2, CH2=CHCl.
D. C2H4, CH2=CHCl.
Cu 2: S ng phn cu to ng vi cng thc phn t C5H12 l:
A. 3 ng phn.
B. 4 ng phn.
C. 5 ng phn.
D. 2 ng phn.
Cu 3: Cht khng lm i mu qu tm l:
A. NaOH.
B. C6H5OH.
C. CH3COOH.
D. CH3COONa.
Cu 4: Ch dng duy nht mt thuc th no di y c th phn bit c: benzen, stiren, toluen?
A. Oxi khng kh.
B. dd KMnO4.
C. dd Brom.
D. dd HCl.
Cu 5: Hp cht c cng thc cu to sau: CH3CHCH2CH2OH, c tn gi l:
CH3
A. 2-metylbutan-4-ol. B. 4-metylbutan-1-ol. C. pentan-1-ol.
D. 3-metylbutan-1-ol.
Cu 6: Cho dy cac cht sau: buta-1,3-ien, propen, but-2-en, pent-2-en. S cht c ng phn hnh hc:
A.
4.
B. 1.
C. 2.
D. 3.
Cu 7: phn bit ba cht lng sau: Glixerol, etanol, phenol, thuc th cn dng l:
A. Cu(OH)2, Na.
B. Cu(OH)2, dd Br2.
C. Qu tm, Na.
D. Dd Br2, qu tm.
Cu 8: Dy no sau y gm cac cht u c kh nng phn ng vi dung dch AgNO3/NH3?
A. CH3COCH3, HCCH.
B. HCHO, CH3COCH3.
C. CH3CHO, CH3-CCH.
D. CH3-CC-CH3, CH3CHO.
Cu 9: Cht no sau y khi cng HCl ch cho mt sn phm duy nht:
A. CH2=CH-CH2-CH3.
B. CH2=CH-CH3.
C. CH2=C(CH3)2.
D. CH3-CH=CH-CH3.
Cu 10: S ng phn ancol no, n chc, mch h c cng cng thc phn t C4H10O l:
A. 6.
B. 4.
C. 8.
D. 2.
Cu 11: Hy chn cu phat biu ng v phenol:
1. Phenol tan trong dung dch NaOH to thnh natriphenolat.
2. Phenol tan v hn trong nc lnh.
3. Phenol c tnh axit nhng n l axit yu hn axit cacbonic.
4. Phenol phn ng c vi dung dch nc Br2 to kt ta trng.
A. 1, 2, 3.
B. 1, 2, 4.
C. 2, 3, 4.
D. 1, 3, 4.
Cu 14: Dy ng ng ca ancol no, n chc, mch h c cng thc chung l:
A. CnH2n-1OH (n 3).
B. CnH2n-7OH (n 6).
C. CnH2n+1OH (n 1).
D. CnH2n+2-x(OH)x (n x, x > 1).
II. T LUN (7 im).
Cu 1. (1,5 im). Hon thnh s phn ng sau.
(1)
(2)
(3)
(4)
(5)
C2H4
C2H5OH
CH3CHO
C2H5OH
CH3COOH.
C2H5Cl
Cu 2. (3,5 im). Ly 4,04 gam hn hp A gm hai ancol no, n chc, mch h, k tip nhau trong cng dy
ng ng tac dng vi Na kim loi d thu c 1,12 lt H2 (ktc).
a. Tm cng thc phn t ca hai ancol.
b. Tnh thnh phn phn trm v khi lng tng ancol trong hn hp A.
c. Oxi ha hon ton 4,04 gam hn hp ancol trn bng CuO, un nng sau , em ton b sn phm hu c
cho tac dng vi lng d dung dch AgNO3/NH3 th thu c a gam Ag. Tnh a.
Cu 3: Hn hp A gm C2H5OH v C6H5OH. Cho A tc dng ht vi Na sinh ra 3,36 lt H2 (ktc). Cng lng
hn hp A nh trn tac dng va vi 100 ml dung dch NaOH 1M. Tnh khi lng tng cht trong A?
Cu 4: Cho 6,9 gam mt ancol no, n chc phn ng vi CuO nung nng, thu c 9,3 gam hn hp X gm
anehit, nc v ancol d. Cho hn hp X phn ng hon ton vi lng d dung dch AgNO3 trong NH3, un
nng. Tnh khi lng Ag sinh ra?