6.

4 Energy balance on Phase Separator (V-802)

Stream

Temperature ( )

8
9
10

350
90
90

Reference state: C6H6 (g), C3H6 (g), C3H8 (g), C9H12 (g), DISB at 25C and 1 atm.
Stream 8
Compone nin(mol/s Hin(kJ/mol

Stream 9
nout(mol/s)

Stream 10
Hout(kJ/mol nout(mol/s) Hout(kJ/mol

nt
C6H6
C3H6
C3H8
C9H12
DISB

7.88
5.97
5.27
0.77
0

)
H6
H7
H8
H9
H10

)
108.96
8.86
8.06
94.39
2.79

)
H1
H2
H3
H4
H5

101.08
2.89
2.79
93.62
2.79

)
H11
H12
H13
H14
H15

C pg , C 6 H 6 = 126.5 103 +23.4 105 T

C pl , C 6 H 6 = 74.06 103 +32.95 105 T

80.1

^
H

25

350

126.5 103 +23.4 105 T dT+ 30.765 +

=77.5263 kJ/mol.
Cp, C 3H 6

3
5
= 59.58 x 10 +17.71 x 10
T

350

^
H

59.58 x 103+ 17.71 x 105 T

25

dT

=30.1555 kJ/mol.
Cp, C 3H 8

5
= 0.068032+22.59 x 10 T

74.06 103 +32.95 105 T

80.1

350

^
H

0.068032+22.59 x 105 T
25

= 35.9463 kJ/mol.
C p , C 9 H 12

= 0.13902 + 53.7610-5T
350

^
H

0.13902+53.76 105 T
25

dT

=77.9415 kJ/mol.
C p , DISB

= -0.0675 + 110-3T
350

^
H

0.0675+1 103 T
25

dT

=39.0005 kJ/mol.

C pg , C 6 H 6 = 126.5 103 +23.4 105 T

C pl , C 6 H 6 = 74.06 103 +32.95 105 T

80.1

^
H

25

90

126.5 103 +23.4 105 T dT+ 30.765 +

=39.4233 kJ/mol.

Cp, C 3H 6

3
5
= 59.58 x 10 +17.71 x 10
T

90

^
H

59.58 x 103 +17.71 x 105 T

25

=4.5346 kJ/mol.

dT

74.06 103 +32.95 105 T

80.1

Cp, C 3H 8

5
= 0.068032+22.59 x 10 T

90

^
H

0.068032+22.59 x 105 T

dT

25

= 5.26638 kJ/mol.

C p , C 9 H 12

= 0.13902 + 53.7610-5T
90

^
H

0.13902+53.76 105 T

dT

25

=11.0456 kJ/mol.
C p , DISB

= -0.0675 + 110-3T
90

^
H

0.0675+1 103 T
25

dT

=-0.66625 kJ/mol.

n ( out ) H (out)

n ( ) H ()

= kJ/s

Q + Ws= H + Ek + Ep
Where Ws, Ek, Epis zero
Therefore Q = H = - 11,048.62 KJ/h