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Process 13 Heng Sun
Process 13 Heng Sun
control problem of a MRC plant. Arjun and Ment [7] developed a simplified model which is applicable for
control structure design without compromising. Wilco etc. [8] discussed the potential application of modern
control technology in LNG production.
Some nearest literatures [9-11] have involved the optimization of operations. Prue Hatcher etc. [12] compared
the difference between the optimizations considering operation and design objects. The work focused on the
heat exchanger area and showed that the optimization with different objects leads to obviously different
results. Hasan etc. [13] presented a generalized model for the running of the compressors network in
large-scale AP-XTM LNG process. During operation, the efficiency of the SMR plant depends on the
performance of centrifugal MR compressors, which changes when inlet gas parameters are changed during
operation. However, this has not been considered precisely. The goal of the work here is to establish an
operation optimization model which includes this key factor and study the performance of a SMR plant under
changed working conditions.
2. OPERATION OPTIMIZATION MODEL OF SMR PLANT
The essential difference between the operation optimization and design optimization is the device
performances of the LNG plant. The device is fixed for operation optimization while the device is selectable
and their performances are free variables in design optimization. Therefore, the operation optimization model
could be setup on the basis of the process simulation. Here, the simulation is also carried out by HYSYS
software. The SRK EOS was used to calculate both the phase-equilibrium and the thermal properties. The
key of operation optimization is to establish models of the devices in LNG refrigeration cycles. Since the
variation of main cryogenic heat exchanger (MCHE) is minor, its performance is treated as constant.
Therefore, the constraints of the MCHE could be described as equations (1) and (2).
Tmin 2C
DTLMTD 4C
(1)
(2)
Here, min denotes the minimum approach of temperature inside the main cryogenic heat exchanger and
LMTD means logarithmic mean temperature difference. The fixing of compressor's performance is important
for the optimization results. The Q-P and Q- curves of the first and the second process stages of the
compressor could be fitted using equations (3) and (4):
2
n
n
p
= 1 = A1 + A2 QV + A3QV 2
p0
n0
n0
2
Q n
Q n
Q n
= B1 V 0 + B2 V 0 + B3 V 0
n
n
n
(3)
3
(4)
Here, p0 is suction pressure, p1 is outlet pressure, is the pressure ratio, Qv is volume flow rate, n is rotational
speed. Since n is equal to the rated speed n0, n/n0 is equal to 1. A1, A2, A3, B1, B2, B3 are the fitting coefficients.
A typical compressor is selected and the fixed coefficients are listed in Tables 1~2, where the mean variances
are in the last column. During actual operation, the working condition of the compressors changes obviously.
Based on similarity theory, equation (3) could be used to predict the performance of the compressor under
different working conditions [9]
RTa
= n
(5)
R Ta
Table 1. Fitted coefficients of Q-p curves of 1st and 2nd stages of compressor
A1
A2
A3
First-stage
-23.862
3.0719
-0.076537
0.15059
Second-stage
1.7931
1.1011
-0.25263
0.29789
B2
B3
First-stage
1.0012
0.42213
-0.013329
0.21897
Second-stage
52.575
-11.91
0.7649
0.07986
PRICO@ process which has been the mostly applied in small-scale LNG plant are selected to conduct the
simulation study. The PFD of the PRICO@ process is shown in Fig. 1.
Purifying unit
Cooler
Cooler
Cryogenic heat
exchanger
Separator
Suction vessel
Separator
LNG Tank
Refrigerant pump
Refrigerant pump
J-T valve
Production valve
Component [%]
Gas 1
Gas 2
Gas 3
CH4
92.67
96.63
93.46
C2H6
3.9
1.54
2.03
C3H8
1.95
0.85
1.13
C4H10
0.98
0.43
0.74
N2
0.5
0.55
2.64
Component
CH4
20.79
C2H4
36.21
C3H8
12.62
C5H12
19.58
N2
10.8
The MR composition for design optimization is already known. However, it may not be available for changed
conditions including different environmental temperature, changed feed gas conditions and partial load.
Therefore, an operation optimization model is necessary to be established to obtain the best operating
parameters under actual conditions. Here, the optimized variables are pthroat and coi i = 1,2 n .
Here, co means the molar fraction of i-component. The constraint involves that the pressure of suction gas of
the compressor could not be too low. The constraint conditions could be expressed as:
n
co
i =1
=1
(6)
p suction 130
(7)
(8)
26
24
22
20
18
3
3.5
4.5
5
5.5
Feed Gas Pressure (MPa)
6.5
Figure 2. Variations of unit energy consumption vs. the pressure of feed gas
30
20
10
0
1
Figure 3. Unit energy consumption of the SMR plant under different gas compositions
However, the reduction of energy consumption becomes inapparent when the environmental temperature
decreases further. This could be explained by the working condition is far away from the design condition
when temperature is lower than -20. The main process parameters and MR compositions of the operation
optimization are listed in Tab. 5 and Tab. 6, respectively. An available adjustment strategy could be drawn
from the process parameters achieved. The adjustment strategy is to ensure the high efficiency of the first
stage compressor primarily since it is the key factor effecting the energy consumption. After that, the LMTD of
MCHE increased rapidly when the temperature is lower than -20. This causes the efficiency of the total
cycle decreased correspondingly.
Table 5 Process parameters and simulation results under different loads for throttle adjustment
Temperature ()
40
20
10
-10
-20
-30
-40
2615.9
2587.0
2338.8
2165.3
2157.3
2155.2
2152.1
2155.0
1549.8
1435.2
1535.8
1500.9
1426.6
1327.2
1256.9
1251.1
3411.7
3115.6
3693.6
3765.7
3542.2
3265.9
3102.6
3090.7
st
4.44
6.00
5.32
4.76
5.61
5.56
7.74
7.81
82.474
82.867
84.332
82.454
82.452
82.467
82.454
82.505
70.742
70.796
70.768
69.555
69.557
70.193
70.504
70.614
6339.1
5948.6
5646.8
5330.3
5136.7
4909.7
4760.8
4756.9
25
20
15
10
5
0
-40
-20
0
20
Temperature ()
40
60
Figure 4. Unit energy consumption of the SMR plant under different environmental temperature
Table 6. Optimized composition of MR for plants with throttle facility
under different loads (molar fraction)
Temperature ()
40
20
10
-10
-20
-30
40
Methane
0.229
0.252
0.333
0.345
0.373
0.420
0.425
0.425
Ethylene
0.334
0.367
0.271
0.260
0.267
0.240
0.281
0.279
Porpane
0.143
0.143
0.194
0.247
0.223
0.238
0.206
0.215
i-Pentane
0.192
0.144
0.107
0.063
0.056
0.028
0.013
0.008
Nitrogen
0.101
0.094
0.094
0.085
0.082
0.074
0.075
0.073
Molecular weight
36.05
33.66
31.89
30.65
29.62
28.05
26.85
26.75
includes MR composition, throttle pressure and MR flowrate. "Th" means fixed MR composition case in which
only MR flowrate and throttle pressure are optimized variables.
100
Th
Op
80
60
40
0
20
40
60
80
100
120
Unit power(kJ/mol)
40
Th
Op
35
30
25
20
0
20
40
60
80
Load percentage(%)
100
120
100
90
80
70
60
50
40
30
1050
945
840
735
630
525
420
315
2623.4
2365.6
2093.1
1828.6
1571.4
1494.6
1292.7
1013.7
280
251
228.5
206.9
189.9
166.9
147.1
130
82.33
82.95
83.8
84.39
84.02
84.09
83.60
83.47
70.70
71.11
71.35
71.02
69.85
71.28
70.71
70.70
6363.2
5905.1
5429.7
4939.9
4451.1
4074.3
3594.1
3080.9
Some small-scale SMR plants which have not been designed for operations under part-loads have no load
adjustment facilities such as throttle valves. Since such plants do may occasionally work under part-loads, it is
also significant to study how to save the energy consumptions for such SMR plants. The adjustment of the
composition of MR is a potential method. The simulation study of this method is also conducted. The methods
are the same to the above except for the throttle pressure is set to be always zero. The energy consumption is
obviously decreased by changing the composition of MR, which is illustrated in Fig. 7. A more than 10%
energy save under 70% load and a more than 16% energy save could be obtained using this method. The
results also indicate the possibility of extend the load adjustment range of throttle by using composition
optimization exists.
50
Component Op
Throat
No Adjust
40
30
20
10
0
0
20
40
60
80
Load percentage (%)
100
120
Figure 7. Comparison between the unit power with and without throttle facility
6. CONCLUSIONS
A model of operation optimization is established based on the consideration of performance variations of the
devices in SMR plant under changed conditions. The operation optimization model is established by
combination of performance simulation of main devices with the process simulation using HYSYS software.
The performance of centrifugal compressor is calculated using fitting method. The model can be used to
study the performance of SMR plant under different conditions, such as variations of feed gas parameters,
environmental temperature and part-load conditions. The optimized operation strategy could also be achieved
based on the model. The available adjustment strategy is that the high efficiency of the first stage compressor
must be primarily ensured. Since the efficiency of compressor is a key factor for energy consumption, this is
suitable for almost every changed working condition.
The simulations and operation optimizations of the SMR plant working under changed gas parameters and
environmental temperature was carried out. The results show that the operation optimization can provide a
good adaptation capacity for SMR plant when the working condition slightly deviated from the design point. If
the deviation is large, the efficiency of the plant will decrease. Besides, the satisfactory energy consumption
8
could be achieved when the fraction of ethane increases while the unit energy consumption is obviously
increased for rich-nitrogen feed gas.
The simulation of a LNG plant of PRICO process with throttle facility of load-adjustment was implemented.
The results show that throttle method could get a relative good adjustment effect in the load range of
60%~100%. The unit power for 30% load is about 60% more than that under design condition. The
composition optimization of MR can slightly decrease the power further. The composition optimization can
adjust the load effectively for the simply SMR plant without any load adjustment facility. A more than 10%
energy save under 70% load and a more than 16% energy save could be obtained using this method.
ACKNOWLEDGEMENTS
The authors are grateful for funding by National Natural Science Foundation of China (No. 51004111:
Research on the mechanism and regulation of the liquefaction process of nature gas in a supersonic swirling
separator) and Special Foundation of Young Teacher of CUPB, China (Research on cryogenic power cycle to
recovery LNG cold energy and waste heat and optimization study)
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