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  • 015-Ionization Energy II

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    林彥瑜
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    The first ionization energies (I1) for beryllium, magnesium, and calcium are slightly enlarged compared to their positions in the periodic table due to shielding of the 2p electrons by the filled 2s orbital. This causes the 2s electron to spend more time closer to the nucleus than the 2p electron. For oxygen and sulfur, the I1 values are slightly reduced because of extra electron repulsions within the doubly occupied 2p orbital.

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    015-Ionization Energy II

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    The first ionization energies (I1) for beryllium, magnesium, and calcium are slightly enlarged compared to their positions in the periodic table due to shielding of the 2p electrons by the filled 2s orbital. This causes the 2s electron to spend more time closer to the nucleus than the 2p electron. For oxygen and sulfur, the I1 values are slightly reduced because of extra electron repulsions within the doubly occupied 2p orbital.

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    24 views7 pages

    015-Ionization Energy II

    Uploaded by

    林彥瑜
    The first ionization energies (I1) for beryllium, magnesium, and calcium are slightly enlarged compared to their positions in the periodic table due to shielding of the 2p electrons by the filled 2s orbital. This causes the 2s electron to spend more time closer to the nucleus than the 2p electron. For oxygen and sulfur, the I1 values are slightly reduced because of extra electron repulsions within the doubly occupied 2p orbital.

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    Slightly Enlarged I1 for Be, Mg, and Ca

    Slightly Enlarged I1 for Be, Mg, and Ca

    The electrons in the filled 2s orbital provide


    some shielding for electrons in the 2p orbital
    from the nuclear charge. (p93, 2)
    A 2s electron spends more time closer to the nucleus
    than a 2p electron.

    Slightly Reduce I1 for O and S

    Slightly Reduce I1 for O and S

    The extra electron repulsions in the doubly


    occupied oxygen 2p orbital. (p93, 2)

    2A Configuration: Larger I

    6A Configuration: Smaller I ?!

    Trends in the 1st Ionization Energies


    for the Representative Elements
    p93, Figure 2.33

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