Professional Documents
Culture Documents
Thermodynamics Summary
Thermodynamics Summary
Humberto Gilmer
Thermodynamics Summary
The fundamental relation for thermo is the first law of thermodynamics
U = Q W
where Q is heat energy ADDED to the system while W is work done BY the system. The work done BY
a system undergoing expansion is
Z
W = P dV
note that P may be volume-dependent! Below is a PV diagram:
Constant
P
V
Relations
P1 V1
P 2 V2
T1 = T2
Q
nCP T
nCV T
Isothermal
P1 V1 = P2 V2
Adiabatic
T otal
None
P1 V1 = P2 V2
0
Q
W
P V
0
V
W = nRT log Vfi
W =
P2 V2 P1 V1
1
U
U = nCV T
U = nCV T
0
U = nCV T
0