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PHYS1250 AU2015

Humberto Gilmer

Thermodynamics Summary
The fundamental relation for thermo is the first law of thermodynamics
U = Q W
where Q is heat energy ADDED to the system while W is work done BY the system. The work done BY
a system undergoing expansion is
Z
W = P dV
note that P may be volume-dependent! Below is a PV diagram:

In order, the processes are


A B: Isobaric - Constant pressure
B C: Adiabatic - No heat exchange
C D: Isothermal - Constant temperature
D A: Isochoric - Constant volume
The table below provides a handy summary of (most) thermo relations.
Process
Isobaric
Isochoric

Constant
P
V

Relations

P1 V1
P 2 V2
T1 = T2

Q
nCP T
nCV T

Isothermal

P1 V1 = P2 V2

Adiabatic
T otal

None

P1 V1 = P2 V2

0
Q

W
P V
0
 
V
W = nRT log Vfi
W =

P2 V2 P1 V1
1

U
U = nCV T
U = nCV T
0
U = nCV T
0

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