Professional Documents
Culture Documents
3.fiber Reinforced Plastics
3.fiber Reinforced Plastics
Statement of Purpose:
Related Literature:
Portland Cement Concrete is considered to be a relatively brittle material.
When subjected to tensile stress, unreinforced concrete will crack and fail. Since
the mid 1800’s steel reinforcing has been used to overcome this problem. As a
composite system , the reinforcing steel is assumed to carry all tensile loads.
Placing an external reinforcement on a structure is a common practice
either to improve its performance during an earthquake or to repair it after an
earthquake. This can be used also for under-designed structure. The materials
can be of reinforcement consisted either of concrete materials placed by
spraying or coating and/or steel plate or jackets bounded. However, the
materials needed to develop is a lightweight, high strength materials with
superior durability and corrosion resistance that can also be applied with relative
case to take place in. The use of fiber-reinforced polymers (FRP’s) fulfills that
need. Polymers and fibers can be combined in a material to suit the specific
needs of a structure.
FRP carrying continuous fiber is that they are highly anisotropic.
Properties in the direction of fiber alignment , such as tensile strength, elastic
modulus and the thermal stability are far superior to those in the direction
perpendicular to fiber alignment. In addition, continuous fiber composite are
essentially brittle and show poor toughness both in the direction of the fiber and
perpendicular to it.
Vinyl Ester Resins are known for their chemical resistance, excellent
wetting, toughness and high temperature properties for composite parts. It is a
resin consisting of an epoxy backbone, for chemical resistance and high strength,
combined with vinyl groups, for high reactivity, and styrene monomer, for low
viscosity. The vinyl groups (carbon to carbon double bonds) and ester linkages
are only at the ends of the resin molecule. This controls the cross linking density,
providing flexibility to the resin matrix. Also these groups are less likely to remain
unreacted in the composite, providing less sites for chemical attack. The ester
linkages are adjacent to methyl groups, making them less susceptible to
breakdown through hydrolysis. These resins are used in composites for
corrosion resistant applications.
Fiber Reinforced Plastics are low weight, high strength, ease of erection,
and corrosion resistance. These factors combined lead to lower installation costs
and lower maintenance costs. When the manufacturing process is perfect and
the standards have been developed, the initial costs may be lower as well. All of
these factors could lead to lower-life cycle costs than using traditional materials.
Nowadays, strengthening by post casting concrete, steel plate jacketing,
fiber reinforcement such as carbon, aramid, and glass are utilized as seismic
strengthening methods for concrete structures. Recently, a seismic
strengthening method by wrapping continuous fiber sheets has often been used,
since the constructibility and durability is superior. However, materials using
continuous fiber are expensive. On the spread of seismic strengthening for
buildings and infrastructures in the future, simple methods of strengthening with
low cost should not only be suggested, but also seismic behaviors should be
cleared.
Definition of Terms:
Glass Fiber – is manufactured by Owens Corning, has a diameter of 11 microns,
a tensile strength of 3400 Mpa, an elastic modulus of 81 Gpa, and
elongation at break of 4.6%. It has a high performance , silane-based
sizing that is applied to fiber filaments to improve handling and optimize
the fiber-resin bond in the composite.
Vinyl Ester Resin(R802)- consisting of an epoxy backbone, for
chemical resistance and high strength, combined with vinyl groups, for high
reactivity, and styrene monomer, for low viscosity. The vinyl groups (carbon to
carbon double bonds) and ester linkages are only at the ends of the resin
molecule. This controls the cross-linking density, providing flexibility to the resin
matrix. Also these groups are less likely to remain unreacted in the composite,
providing less sites for chemical attack. The ester linkages are adjacent to
methyl groups, making them less susceptible to breakdown through hydrolysis.
These resins are used in the composites for corrosion resistant applications.
Vinyl Ester Resin R806- a special type of Vinyl ester resin and they
have the same purpose of R802 as a polymer.
Polyester Resins- are homopolymers based on p-oxybenzol repeat
units and are linear thermoplastics. They are highly crystalline polymers but
have no observed melting point even at up to 900 to 1000 degrees Farenheit.
Flow and creep are virtually non-existant below their crystal translation
temperature of 625 degrees. Polyester has a density of 1.44 gm/cc. Polyester
possess a compressive strength of 15,000 psi. The high strength results is an
excellent load bearing capacity. Polyester has a thermal conductivity of 3.9
BTU/hr./ft2/degrees ft/in. Its coefficient of thermal expansion (3.3x10-5
in/in/degrees F) is approximately linear from room temperature to 575 degrees F.
Polyester is a very thermally stable wholly aromatic polymers.
Methodology:
Spraying of fiber reinforced concrete plastics (SFRP) is conducted by
the Vantec Laboratory through the help of Fuji P.S. Testing is done at Tokyo
Institute of Technology. The tensile strength, bending capacity, shearing capacity
and the bond stress are done using samples of concrete with and without SFRP.
The key element of the spray equipment is the nozzle unit that injects the
catalyzed polymer of the spray stream. Attached to the nozzle is a fiber chopper
unit that cuts the incoming fiber strand to various length (13,26,52 mm.) and
injects it in the spray stream along with the catalyzed polymers(see Fig. 1 to 4).
Before applying the spray, the surfaced concrete is coated with a layer of
bonding agent (vinyl ester resin combined with catalyst methyl ethyl keytone
peroxide (MEKP). The polymetric matrix and the fiber are simultaneously
sprayed at a high speed on the surface of a concrete structured to be repaired
(see Fig.5 to 6). The sprayed composite is compacted pneumatically on the
application surface, and is then finish with a roller (see Fig. 7 to 8) The length of
the fiber can be adjusted in the process along with the type of polymer and the
sprayed thickness. In this study, we use three (3) types of polymers namely,
Vinyl ester resin, Vinyl ester resin (R806), 50% Vinyl ester resin (R806) and 50%
polyester resin (bb 100) and the polyester resin (bb 100).
To spraying gun
Spray machine
Conpression air
Resin tank
Rolling cutter
1/4inch(6mm)
Cutting and
spraying part
Resin gun
From figure 9 and 10, it shows that the ordinate indicates strength and
the abcissa is the strain (extensibility). The following were observed:
y The vinyl ester resin R806 gives a high strength but low in strain, peeling off
from the specimen were observed
y The vinyl ester resin R802 has a high strength and high value in strain, but
peeling off was observed in the sample.
y The combination of 50% of polyester resin bb100 and 50% of R806 has low in
strength and strain.
y The Polyester resin (bb-100)- low in strength but high in strain and no peeling
off.
From the result, polyester resin bb100 can be sprayed in the
specimen due to its low value of Young’s Modulus of Elasticity and high value
of strain.
200
3
150
10 10 12 S tr a in g a g e
0 0 5 CL
L a s t t im e T h is t im e
R e s in None V in y l e s t e r P o ly e s t e r B B - r e s in
S p r a y in g N o t h in g W ir e b r u s h in g C h ip p in g re ta rd e r W ir e b r u s h in g
s u rfa c e & s p ik in g
P e a l o ff ○ − −
c type
thickness 3mm Failure mode Flexural tension Flexural tension Flexural tension
Note: The dimension of specimen sprayed is 100 square mm. with a length of
450 mm. and a reinforced with no. 23 bars
This 3.5 mm. thickness is recommendable. There is no peeling occurs on
the surface.
Note: From Figure 19, you will notice the peel-off of the sprayed fiber from the
specimen.
stress-strain curve of bb 13
80
70
60
stress(MPa)
50
bb13
40 bb132
30 bb133
20 bb134
bb135
10
0
0 5000 10000 15000 20000 25000
strain(μ)
stress-strain curve of bb 26
80
70
60
stress(MPa)
50 bb26
40 bb262
30 bb263
bb264
20
bb265
10
0
0 5000 10000 15000 20000 25000
strain(μ)
stress-strain curve of bb 52
80
70
60
stress(MPa)
50 bb52
40 bb522
30 bb523
bb524
20
bb525
10
0
0 5000 10000 15000 20000 25000
strain(μ)
stress-strain curve
80
70
60
stress(MPa)
50
40 bb13
30 bb26
bb52
20
10
0
0 5000 10000 15000 20000 25000
strain(μ)
Note that from figure 17, polyester (bb) with a length of 26 mm will give better
result of stress-strain curve.
shearing test
60
Peeling
50 Peeling
Maximum load(kN)
40
30
20
10
0
0 1 2 3 4 5 6
Actual spraying thickness(mm)
10000 10000
8000 8000
Strain
ひずみ(μ)
ひずみ(μ)
Strain
6000 6000
0% 0%
20% 20%
4000 40% 4000 40%
80% 60%
2000
60% 2000
80%
Peak Peak
破断or剥離 破断or剥離
0 0
-100 -50 0 50 100 -100 -50 0 50 100
中央からの距離(mm)
Distance from center 中央からの距離(mm)
Distance from center
2mm① 2mm②
2mm①
2mm②
12000 12000
10000 10000
8000 8000
Strain
ひずみ(μ)
ひずみ(μ)
Strain
6000 6000
0% 0%
20% 20%
4000 40% 4000 40%
60% 60%
2000
80% 2000
80%
Peak Peak
破断or剥離 破断or剥離
0 0
-100 -50 0 50 100 -100 -50 0 50 100
中央からの距離(mm) 中央からの距離(mm)
Distance from center Distance from center
3.5mm① 3.5mm②
3.5mm① 3.5mm②
12000 12000
10000 10000
8000 8000
Strain
ひずみ(μ)
ひずみ(μ)
Strain
6000 6000
0% 0%
20% 20%
4000 40% 4000 40%
60% 60%
2000
80% 2000
80%
Peak Peak
破断or剥離 破断or剥離
0 0
-100 -50 0 50 100 -100 -50 0 50 100
中央からの距離(mm) 中央からの距離(mm)
Distance5mm①
from center Distance from center
5mm②
5mm① 5mm②
12000
10000
8000
Strain
ひずみ(μ)
5mm③
1. Calculation of bond shearing strength
Then, we try to calculate the bond shearing strength from the strain distribution of the
specimen which was destroyed by peeling.
Table 4
5mm① 5mm③ Average
Maximum stress
slope
dσ SFRP 1.495 1.475 −
(MPa/mm)
dx
Cross section of
SFRP 420 380 −
ASFRP (mm2)
Width of SFRP
100 100 −
b (mm)
Bond shearing
strength 6.28 5.61 5.95
τ max (MPa)
Figure 28-Load Displacement Curve of type A
120
100
80
Load (KN)
60 Type A-a5mm
TypeA-a3mm
40
TypeA(w/oSFRP)
20 Type Ac-3mm
0
0 10 20 30 40 50
Displacement (mm.)
250 TypeB(w/oSFRP)
TypeBb3mm
200 TypeBa3mm
TypeBc3mm
Load (KN)
150
100
50
0
0 10 20 30 40
Di spl acement ( mm. )
Figure 30-Load Displacement Curve of Type C
250
200 TypeC(w/oSFRP)
TypeC-b3mm
Load (KN)
150 TypeC-c3mm
100
50
0
0 10 20 30 40
Di spl acement ( mm. )
Type A under Compressive Stress
Based from Figure 28,29 and 30, the Load Displacement Curve with SFRP
gives better displacement results than without SFRP, it appears that
specimen with SFRP gives more strength than without Spraying which
shows in the said graph. Comparison of using finite element analysis of
Diana software and the actual experimental value in Figure 31, shows that
the finite element analysis and the experimental values will give almost the
same result.
Conclusions:
1. SFRP spray process of strengthening and rehabilitation is a very promising
technique, and continued research will undoubtedly lead to its use in reality.
2. It appears that SFRP have the potential to significantly increase the strength
of existing concrete structures, while at the same time dramatically improving
their fracture energy characteristics.
3. The results indicate that while a number of issues still remain to be
addressed, the use of SFRP for repair and retrofit has advantages over the
traditional wraps on the basis on ease of placement, labor cost and
workmanship requirements.
4. It is highly recommended for highway concrete bridge repair as a form of
retrofitting.
5. The thickness of spraying is 3.5 mm and the length of fiber is 26 mm. To
avoid peel-off.
Recommendations:
The following are the recommendations for future studies:
1. To investigate the actual cost of the SFRP if it is more economical to use.
2. To investigate its durability characteristics under the Philippine weather.
. Try to make another mixing type of SFRP using another resin or combination of
resins.
3. To determine the ability to withstand elements and other detrimental
influences out there in field.
References:
1. N. Banthia, A. Bentur, A. Mufti, “Fiber Reinforced Concrete”, The Canadian
Society for Civil Engineers, 1998
2. N. Banthia and S. Mindess, “Fiber Reinforced Concrete (Modern
Developments)”, The University of British Columbia, Vancouver,
Canada,1995
3. Thomas W. Berg “Fiber Reinforced Concrete”, http://www.retail
source.com/information
4. “Sprayed-Up FRP Strengthening for Reinforced Concrete Beams”,
http://www.tsukuba.ac.com
5. “Fiber Reinforced Concrete”, http://www.fibermesh.com
6. “Stone Solutions – Custom Concrete Countertops”,
http://www.stone-solutions.com
7. “Cary Concrete Products, Inc. Materials”, http://www.caryconcrete.com
8. “Durastone”, http://www.durastone.com
9. “Superior Polymer Products Vinyl Ester Resin Technical Data”,
http://www.superiorpolymer.com
10. “Composites-What is a Vinyl Ester Resin?”, http://www.cabot.corp.com
11. http://www.bouyer.net/digests/2000
12. “Polyester Resin”, http://www.deq.state.la.us/assistance
13. “Polyester Resin”, http://www.sculpt.com/catalog_98
14. “Rule 1162- Polyester Resin Operations”, http://www.aqnd.gov/rules/htm
15. “Polyester Resin Plastics Products Fabrication”,
http://www.dep.state.fl.u/air/permitting/plastics.htm
16. “4684-1 Rule 4684 Polyester Resin Operations (Adopted May 19,….)”,
http://www.valleyair.org/rules/currentrules
“Diana Finite Element Analysis”, TNO Building and Construction Research, 2000
ABOUT THE AUTHOR
Engr. Cristina Tanhueco-Coquilla is at present the Chairperson of the Civil
Engineering Department of Adamson University. She earned her Master of
Engineering, major in Civil Engineering from Technological University of the
Philippines and her B.S. Degree in Civil Engineering from the University of the
East. She was at one time also the Chairperson of the Civil Engineering
Department of the University of the East. At present she is taking up Ph.D. in
Technology Management at the Technological University of the Philippines. She
may be contacted at 14 Rd. 7 G.S.I.S. Hills Talipapa, Novaliches, Tel. No.
(02)983-11-41, Cell/Text No. 0917-240-6529, E-mail Address:
ccoquilla@adamson.edu.ph, cristinacoquilla@yahoo.com.