1.

The data for a reaction done at a fixed temperature is as follows :

Molar concentrations rate of reaction
A B
i) 6 x 10–3 1 x 103 0.012
ii) 6x 10–3 2 x 10–3 0.024
iii) 12 x10–3 1x10–3 0.048
a) What is the order of the reaction
b) Write the rate equation.
2. In a reaction 0.2 mole of a reactant got reacted in 10 seconds. In the same reaction
0.5 mole got reacted in 25 seconds. What is the order of the reaction?
3. In the case of a gaseous reaction, half-life period for initial concntrations of 1 mole
and 3 moles are 40 minutes and 13.2 minutes respectively. Calculate the order of the
reaction. (
4. At an initial concentration of 0.2 mole rate of decomposition was found to be 0.7 mol
dm–3 min–1. At an initial concentration of 0.3 mole, the rate of decomposition was
1.572 mol dm–3 min–1. Calculate the order of the reaction.
5. In a first order reaction the amount of a reactant left behind was estimated
volumetrically at certain time intervals. The readings obtained are given below.
Time in minutes 0 5 10 15 20
(a – x) 37 30 24 19.8 16
6. When a reaction was performed with 0.3 mol dm –3 and 0.6 mol dm –3 reactants
respectively the rates of decomposition were 0.5 mol dm –3 hr and 4 mol dm–3 hr–
–1
1. Determine the order of the reaction.
7. In a reaction when initial concentration doubles, the half-life is reduced to half. What
is the order of reaction?
8. The rate of decomposition of a substance was 14.5 when it reacted 5% while the rate
of decomposition in same unit was 10.25 when it reacted 20%. Find the order of
reaction.